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Spring 2021 EN

The German Biogas Association presents its English spring 2021 issue of the BIOGAS journal.

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www.biogas.org<br />

German Biogas Association | ZKZ 50073<br />

<strong>Spring</strong>_<strong>2021</strong><br />

Bi<br />

The trade magazine of the biogas sector<br />

GaS Journal<br />

english issue<br />

Humus farming: from a sceptic<br />

to a pioneer P. 6<br />

The VOA / TIC value put<br />

to the test P. 28<br />

Denmark totally committed to<br />

organic residues P. 42<br />

Humus:<br />

keep the<br />

edaphon<br />

alive!<br />

Including Country Reports from Denmark,<br />

South Korea and the Philippines


English Issue<br />

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Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

Editorial<br />

Keep the<br />

edaphon alive!<br />

Dear Readers,<br />

In this issue of the Biogas Journal, among other topics,<br />

we address the subject of humus management in agriculture.<br />

The farm businesses with biogas plants introduced<br />

here are trying out management methods, some<br />

of which are unconventional, to increase humus content<br />

and thereby enhance overall soil fertility. Why deal with<br />

this topic? Well, in Europe, recent years have shown that<br />

when long periods without precipitation occur together<br />

with high temperatures, soil moisture levels are quickly<br />

depleted – depending on the type of soil and its humus<br />

content. On the other hand, plants grown in soil with a<br />

humus content of two percent or more or plants growing<br />

in plaggen soil reach a ripened or prematurely ripened<br />

stage later.<br />

One percent more humus in the soil means an additional<br />

saving of about 400,000 litres of water per hectare. Humus<br />

particles store twenty times their weight in water<br />

and up to 95 percent of soil nitrogen. This means that<br />

building up humus is worthwhile in order to increase<br />

the usable water holding capacity with regard to the water<br />

available in the soil. Also significant, though, is that<br />

with each additional tonne of carbon in the soil biomass,<br />

which is equivalent to about two tonnes of humus, 3.67<br />

tonnes of CO 2<br />

are removed from the atmosphere. We<br />

don’t have enough space here to list all of the many other<br />

benefits. This is why we should pay more attention to<br />

humus formation because, in the future, not only must<br />

our business activities be CO 2<br />

neutral, but we must also<br />

remove a considerable portion of the previously emitted<br />

CO 2<br />

from the atmosphere.<br />

From a purely scientific perspective, humus is made up<br />

of the total dead organic substance of the soil mixed<br />

together with the mineral soil. A central component is<br />

the so-called edaphon, which Raoul H. Francé was already<br />

investigating 100 years ago. Edaphon refers to the<br />

totality of living organisms, such as bacteria, archaea,<br />

fungi, viruses, protozoans, nematodes, spiders, insects<br />

and earthworms. The greater the amount of species and<br />

the amount of individuals per species, the more active<br />

and fertile the soil. This activity depends on soil temperature<br />

and soil water content, and therefore, also on<br />

the seasons.<br />

According to Australian soil scientist Dr. Christine Jones,<br />

however, it is even more important for plants that perform<br />

photosynthesis to be growing at the soil’s surface<br />

for as much of the year as possible. The edaphon, just<br />

as humus, is not produced by organic fertilisation alone,<br />

but instead due to root excretions (exudate). Among<br />

other items, these include amino acids and easily degradable<br />

sugars, which feed bacteria and fungi. In this way,<br />

the living plants pump large quantities of liquid carbon<br />

into the soil, which feeds the edaphon organisms.<br />

In a process akin to bartering, the microorganisms give<br />

the plants the nutrients they need from the soil. The<br />

so-called mycorrhizal fungi are particularly important in<br />

this interaction. U.S. soil scientist Dr. Elaine Ingham<br />

also talks about the “soil food web”, which refers to the<br />

process by which the edaphon organisms provide each<br />

other with nutrients; but they also form a nutrient chain<br />

based on the principle of “eat and be eaten” in which<br />

every dead organic substance is always recycled.<br />

We must become aware of natural connections and interactions<br />

and align our agricultural practices accordingly.<br />

Essentially, our lives depend on just the top few centimetres<br />

of topsoil. Everything that debilitates humus and<br />

inhibits the edaphon should be reduced to a minimum.<br />

I wish everyone success in increasing humus, boosting<br />

soil fertility and developing “ripe” soil.<br />

Best regards,<br />

Martin Bensmann,<br />

Editor, Biogas Journal<br />

German Biogas Association<br />

3


English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

Optimum agitator technology for every substrate<br />

IMPRint<br />

– All types of agitators<br />

– Over 25 years of biogas expertise<br />

– Repowering & optimisation<br />

Tel. +49.7522.707.965.0 www.streisal.de/en<br />

better performance<br />

Publisher:<br />

German Biogas Association<br />

General Manager Dr. Claudius da Costa Gomez<br />

(Person responsible according to German press law)<br />

Andrea Horbelt (editorial support)<br />

Angerbrunnenstraße 12<br />

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Phone: +49 81 61 98 46 60<br />

Fax: +49 81 61 98 46 70<br />

e-mail: info@biogas.org<br />

Internet: www.biogas.org<br />

Editor:<br />

Martin Bensmann<br />

German Biogas Association<br />

Phone: +49 54 09 9 06 94 26<br />

e-mail: martin.bensmann@biogas.org<br />

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Printing:<br />

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The newspaper, and all articles contained within<br />

it, are protected by copyright.<br />

Articles with named authors represent the opinion<br />

of the author, which does not necessarily coincide<br />

with the position of the German Biogas Association.<br />

Reprinting, recording in databases, online<br />

services and the Internet, reproduction on data<br />

carriers such as CD-ROMs is only permitted after<br />

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4


Biogas Journal | <strong>Spring</strong>_<strong>2021</strong> English Issue<br />

Editorial<br />

3 Keep the edaphon alive!<br />

By Martin Bensmann, Editor, Biogas Journal<br />

German Biogas Association<br />

4 Imprint<br />

Germany<br />

6 From a sceptic to a pioneer<br />

By Christian Dany<br />

14 Feeding soil life with organic matter<br />

By Dipl.-Journ. Wolfgang Rudolph<br />

22 Biogas can improve the soil<br />

By Dierk Jensen<br />

28 The VOA / TIC value put to the test<br />

By Prof. Dr. Paul Scherer, Martin Pydde, Dipl.-Ing. Sebastian<br />

Antonczyk and Dr. Niclas Krakat<br />

6<br />

34 NuTriSep: Nutrient extraction and peat substitute<br />

from digestates<br />

By Dipl.-Ing. Heinz Wraneschitz<br />

38 Seven biogas plants supply one gas feed-in plant<br />

By Marie-Luise Schaller, EUR ING<br />

Country reports<br />

42 Denmark<br />

Denmark totally committed to organic residues<br />

By Thomas Gaul<br />

46 South Korea<br />

Mandarin orange juice production – residues<br />

used to produce biogas<br />

By Achim Kaiser<br />

48 Philippines<br />

Converting pineapple waste into biogas<br />

By Medina Berbic<br />

coverphoto: Silke Goes photos: Christian Dany, Dierk Jensen, LIPP GMBH<br />

22<br />

48<br />

5


English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

From a sceptic to a pioneer<br />

Hans Grötzinger is a passionate crop, biogas and organic farmer. He discovered renewable<br />

agriculture while searching for better soil fertility and stability in view of the climate<br />

change. He applies some of the measures mentioned under this term, but not all of them.<br />

He focuses on humification, a well-balanced supply of nutrients and organic fertilization.<br />

By Christian Dany<br />

Hilling in the Lower Bavarian district of<br />

Landshut: Hans Grötzinger sticks a spade<br />

into the soil of his field. “The chunks in the<br />

soil are good,” he explained. “They maintain<br />

the soil structure so that the soil won’t<br />

become too muddy when it rains. Below the chunks is<br />

the fine soil.” He then digs more than 30 centimeters<br />

below the surface. There is no visible cultivated layer,<br />

which is no wonder, as the organic farmer Grötzinger<br />

stopped using a plough three years ago.<br />

Another interesting factor is the test with a one meter<br />

long soil probe: It can easily be pushed into the soil as<br />

far as it will go. 37-year old Grötzinger then inspects a<br />

field of five-week-old oat plants dispersed with buckwheat<br />

and goosegrass. “The buckwheat is from the<br />

previous catch crop and the goosegrass shows there is<br />

good nutrient availability,” he explains. We then see a<br />

demonstration of renewable agriculture live when his<br />

brother, Josef, works the remnants of a catch crop blend<br />

into the soil with a seedbed cultivator.<br />

Grötzinger’s father Josef switched to organic farming in<br />

the Naturland Association as early as 1989. “We were<br />

a mixed farm, with dairy cattle and bullock fattening,”<br />

said Grötzinger. The quadrangle-shaped farmhouse lies<br />

on the main street of the village, just like some of the<br />

other farms. But most of the approximately 500 inhabitants<br />

live in the adjacent residential area. There are<br />

some large industrial companies nearby. Employment<br />

opportunities have accelerated structural change.<br />

“The smaller farms closed down about 30 or 40 years<br />

ago.” Grötzinger himself also did not follow a predestined<br />

course of life. After his apprenticeship in agriculture,<br />

he no longer enjoyed working in that profession.<br />

“For five years, I worked as a paramedic. I wasn’t really<br />

interested in dairy cattle,” he said.<br />

But when the special permit for livestock breeding expired,<br />

he experienced a turnaround: “We would have<br />

needed more pasture, but were a little too penned between<br />

the road and the Bina River,” said Grötzinger. He<br />

enrolled in the organic agricultural college in Landshut-<br />

Schönbrunn and graduated as a master of agriculture.<br />

He later gave up livestock breeding and revolutionized<br />

the business: “We have a lot of clover grass in the crop<br />

rotation. That can be optimally utilized in the biogas<br />

photos: Christian Dany<br />

Josef Grötzinger, who is the operations<br />

manager’s brother, removes the<br />

stubbles with a seedbed cultivator. The<br />

picture also shows the tire pressure<br />

regulation system with the equalizing<br />

tank at the front.<br />

6


Biogas Journal | <strong>Spring</strong>_<strong>2021</strong> English Issue<br />

plant. I have good technical skills, which is<br />

just what we needed,” said Grötzinger, who<br />

has two sons.<br />

The biogas plant, which has an electric capacity<br />

of 210 kilowatts (kWel) was set up<br />

along the lines of the build-owner model<br />

in 2010 with connected load. A 100 kW el<br />

CHP unit for flexible operation was added<br />

in 2016. Grötzinger: “We operate a little<br />

according to the temperature.” That means<br />

full power, particularly in October<br />

“We have a lot of clover grass<br />

in the crop rotation. That can<br />

be optimally utilized in the<br />

biogas plant”<br />

Hans Grötzinger<br />

Grötzinger checks<br />

the soil moisture<br />

before continuing<br />

the processing.<br />

7


English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

and November, when grain maize is being dried, and<br />

in winter to ensure a guaranteed supply of heat for the<br />

seven households connected to the heating grid. In<br />

return, power is reduced in mid-summer. Grötzinger<br />

wants his plant to run as much as possible on residues<br />

Picture of the farm of Hans Grötzinger<br />

Geographic location:<br />

Operational setup:<br />

Size of the farm:<br />

Soil type:<br />

Land use:<br />

Individual operating units:<br />

Bavarian Molasse Hills, height above sea level: 470 meters<br />

crop cultivation, renewable energies<br />

150 hectares<br />

+/– sandy loam, 47 to 75 ground points<br />

130 hectares , 20 ha Grassland<br />

Crop cultivation: cash crops and fodder as biogas feedstock<br />

Renewable energies: biogas and photovoltaics<br />

Biogas plant: 210 kW el<br />

rated output, 310 kW el<br />

installed capacity (100 kW el<br />

for flexible operation),<br />

Substrates: silage grass, deep sloped floor litter,<br />

small silage grass residues<br />

Family: Operations Manager Hans Grötzinger (37),<br />

wife Katrin, sons Julian and Johannes<br />

Employees:<br />

1 full-time Operations Manager, 80 % part-time employee<br />

Josef Sen., 20 % part-time employee wife, 20% part-time<br />

employee Josef (brother), one minor employee for the<br />

biogas plant<br />

which it does: The main component of the feedstock is<br />

grass silage made of grass clover and catch crops, 32<br />

to 35 percent of it consists of sloped floor deep litter<br />

manure, which he buys in addition. Only 15 percent of<br />

it is maize silage.<br />

Biogas plant as a nutrient supplier<br />

On the organic farm, the biogas plant fulfills the important<br />

function of a “nutrient plant”. In return for the<br />

manure he buys, Grötzinger partly returns digestate<br />

as fertilizer and partly receives a nutrient input. He<br />

also cooperates with other biogas plants, from which<br />

he gets grass clover in exchange for the digestate. The<br />

Lower Bavarian considers cooperation an important<br />

aspect at many levels: In a community of five farmers,<br />

he tests and develops the cultivation of linseed: “If it<br />

works, we’ll expand it.” He ventures into unusual farming<br />

methods in other ways, too: He cultivates spelt,<br />

oats, grain maize and even sweet maize, of which the<br />

cobs are picked and sold as barbecue maize.<br />

Grötzinger sells around two thirds of the field crops as<br />

cash crop, one third goes into the biogas plant. “Reallocation<br />

and consolidation of the farm holdings resulted<br />

in a great infrastructure,” he says. Most of the<br />

farm boundaries have been readjusted and 80 percent<br />

photo: Grötzinger<br />

Operating the rotary cultivator, viewed<br />

beyond the tip of the tractor: Here<br />

showing clover grass being milled<br />

before the winter crop.<br />

8


Biogas Journal | <strong>Spring</strong>_<strong>2021</strong> English Issue<br />

of the fields are less than 2.5 kilometers<br />

away. They have an average size of about 4<br />

hectares. And besides that, crop production<br />

benefits from the loess soils in this<br />

area. Crop and energy farmers also have<br />

about 20 hectares of grassland, many of<br />

which are wildflower meadows along the<br />

Bina River. Grötzinger farms a total of 150<br />

hectares, a large part of which is leased<br />

land.<br />

The basis of Grötzinger’s crop rotation is<br />

clover grass. He says that well-planned<br />

crop rotation will ensure a clean, healthy<br />

plant stock; for example, as a prevention<br />

against stone blight in wheat. Catch crops<br />

are planted after each primary crop to ensure<br />

that the soil is always covered. For example,<br />

he grows vetch rye or Landsberger<br />

mixture, which generally consists of vetches,<br />

scarlet clover and Italian ryegrass.<br />

This mixture regularly brings the organic<br />

farmer a harvest of more than 30 tons of<br />

fresh matter per hectare with about 28 percent<br />

of dry substance. “That’s about half a<br />

maize harvest and there is also a cash crop<br />

on top of that.” The additional<br />

revenue and the humification<br />

more than make up for all the<br />

work and the hours spent on<br />

the tractor. Grötzinger has his<br />

own seed blending unit with<br />

which he can also make individual<br />

mixtures. Besides that,<br />

he also puts in more undersown<br />

crops when he plants<br />

grain and maize: for example,<br />

white clover, rye-grass or grain<br />

legumes.<br />

Retting instead of<br />

ploughing<br />

So far, not so good. “Even<br />

with good yields and good agricultural<br />

practice, the problems<br />

did not decrease, they<br />

rather tended to increase,”<br />

said Grötzinger. The yields<br />

were not stable enough, especially<br />

during dry periods.<br />

So he took a closer look at<br />

new forms of agriculture and<br />

how to brace himself for the<br />

climate change. He considers<br />

the enrichment of humus<br />

as the most important task<br />

for the future because of its<br />

capability to retain water and<br />

nutrients. “We have been planting catch<br />

crops for a long time now. We also used<br />

to have solid manure. We had 2.8 to 3.5<br />

percent of humus, but did not manage<br />

to get more than that,” he said, looking<br />

back. He found solutions in principles that<br />

today are summed up as “renewable agriculture”.<br />

He changed the inversion and<br />

soil sampling methods and also organic<br />

fertilization.<br />

He has been tilling the soil without a<br />

plough for about 4 years now, as it did<br />

more to destroy the life and structure of the<br />

soil than enhance it: “Ploughing interferes<br />

with the development of bacteria. Further<br />

down, there are anaerobic bacteria that<br />

are brought to the surface, which you can<br />

smell.” Instead of doing that, Grötzinger<br />

removes the crop residue and puts it into<br />

the surface retting. Later, he stirs the soil<br />

with a cultivator at a depth of about 15<br />

centimeters and then compacts it with a<br />

Cambridge-type roller.<br />

“Anything that has a thick sward, like clover<br />

grass and Landsberger mixture, is cut<br />

right down to the roots,” he explained. The<br />

rotary tiller, that he leases, cuts to a depth<br />

of 3 to 5 centimeters. “If there are straw<br />

and maize stubbles, green rye and whole<br />

crop silage, we use a blade cultivator because<br />

it consumes less diesel.” The special<br />

hydraulic cultivator with adjustable<br />

depth can also cut plants to that depth.<br />

“That’s how I put organic material into the<br />

soil with maximum soil conservation,” said<br />

Grötzinger. He refrains from using retting<br />

control, like enzymes or the like: “It needs<br />

time. The material stays in there for three<br />

to ten days. The more there is, the longer<br />

it takes for the organic matter to be converted.”<br />

The chisel ploughing is followed<br />

by rolling. He says that is important to<br />

ensure that the CO 2<br />

is retained in the soil<br />

rather than being outgassed. And besides<br />

that, the soil retains its resistance to heavy<br />

loads much faster.<br />

“If left for a few weeks, the soil becomes<br />

porous and compaction is reduced. We<br />

hardly ever need a rotary harrow, even<br />

though our soil is heavy.” Although this<br />

kind of tillage requires several cycles, it<br />

uses up less diesel: “We only use between<br />

2 and 4 liters of diesel per hectare for each<br />

flat cultivating and rolling cycle.” The annual<br />

consumption is 28,000 liters, which<br />

is about 2,000 liters less than when he was<br />

still using a plough.<br />

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English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

“There’s no point fertilizing<br />

according to a pH level”<br />

Hans Grötzinger<br />

Round crumbly soil<br />

with good root density<br />

in a field of oats.<br />

Fertilization according to Albrecht/Kinsey<br />

The changing tillage methods go hand in hand with<br />

soil analyses according to the Albrecht/Kinsey method,<br />

which is applied to create a balanced proportion of nutrients<br />

in the soil and adequate levels of trace elements.<br />

Grötzinger explained the theory of “scarcity despite<br />

abundance”: “Today, you have to eat ten times more<br />

salad than after World War II to absorb the same amount<br />

of trace elements. This method will provide us with food<br />

items that are simply more nutritious.” The farmer, who<br />

comes from Hilling, works with the agricultural retailer<br />

Josef Hägler and with Geobüro Christophel, and supervises<br />

the soil samples of other operating farms in the<br />

region.<br />

The Albrecht/Kinsey method primarily focuses on the<br />

cation exchange capacity, which is a measure of the<br />

quantity of nutrient cations that occurs in interchangeable<br />

form and that is thus accessible to plants (for example<br />

C a2+ , Mg 2+ , K + ). It also used to examine the interaction<br />

of nutrient contents, for which there are special<br />

ratios, such as the carbon:nitrogen ratio: “Within two<br />

years, we adjusted the C:N ratio to 9:1 (10:1 would be<br />

ideal). We started off at 5:1,” said Grötzinger, “That’s<br />

too tight for most of the farms, no matter whether they<br />

have dairy cattle or biogas.” According to Grötzinger,<br />

another indication is the calcium:magnesium ratio:<br />

“Ideally, it would be 68:12. We had 75:11. Too much<br />

calcium prevents other nutrients from being absorbed.”<br />

Grötzinger also found that the pH level is not a decisive<br />

criteria: “There’s no point fertilizing according to a pH<br />

level.” In the past, too much calcium was often used in<br />

fertilization if the pH level was low. But he believes that<br />

if the nutrients are well-balanced, there will automatically<br />

be a good pH level of around 6.5. His farm was<br />

discovered to have a shortage of boron and sulphur. Sulphur<br />

deficiency is a widespread phenomenon, he said,<br />

but you need enough sulfur for nitrogen availability and<br />

to build up humus.<br />

Grötzinger recommends having soil analyses made during<br />

the soil dormancy period before the soil is fertilized –<br />

ideally in November. Repeated analyses should then<br />

be made on the same date after two or three years. He<br />

recommends taking samples from a very good and a<br />

very bad area and from two or three average areas. A<br />

standard analysis costs around 100 Euros.<br />

photo: Grötzinger<br />

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Biogas Journal | <strong>Spring</strong>_<strong>2021</strong> English Issue<br />

photo: Christian Dany<br />

Digestate treatment with Leonardite<br />

and In-wa Quartz<br />

Organic fertilization with organic manure from the biogas<br />

plant is of prime important on Grötzinger’s farm.<br />

He separates the thick part of the digestate and in that<br />

way, extracts around 500 tons of solid phase per year.<br />

Grötzinger processes the liquid phase with Leonardite<br />

and In-Wa Quartz, which are both approved in organic<br />

farming. “The high proportion of grass clover produces<br />

7 kilograms of nitrogen per cubic meter in the<br />

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English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

Julian Grötzinger with<br />

a whole crop silage<br />

mixture of winter peas,<br />

barley, rye and Landsberger<br />

mixture.<br />

manure. Despite the high protein content, the digestate<br />

no longer smells after it has been processed. That<br />

works one hundred percent,” he says. The In-Wa Quartz<br />

makes the manure black, although only 0.5 liter of it is<br />

needed for every 100 cubic meters. The digestate goes<br />

into a rotting phase and that brings about a stimulating<br />

effect for self-protection.<br />

“In an experimental field, we treated organic rapeseed<br />

with In-Wa Quartz and lime,” said Grötzinger when talking<br />

about a particular incident. “The rapeseed had been<br />

completely infested with the rapeseed gloss beetle. The<br />

next day, there wasn’t a single beetle to be seen.” He<br />

says that Leonardite is a lignite precursor that results<br />

from the humification of plant matter. That makes it<br />

rich in humic acids (up to 90 percent). “The Leonardite<br />

binds the nitrogen and the plant gets it little by little,<br />

whenever it needs it, which means that there is no free<br />

nitrogen present in the soil.” This conditioning prevents<br />

nitrate from being leached out. “I have two digestate<br />

storages,” he said when explaining his nutrient management<br />

methods. “The digestate from the farms that<br />

supply me with clover grass is not treated, unless this<br />

is expressly requested. The treatment costs 1 Euro per<br />

cubic meter.”<br />

Composting digested, separated solids<br />

Grötzinger spreads liquid digestate with the trailing<br />

shoe method and makes sure it is distributed over cultivated<br />

fields. That can be achieved by cultivating catch<br />

crops and by splitting the individual applications. “We<br />

no longer have any fertilizer burn. Spreading manure<br />

over open soil would cause rotting,” he said. “You would<br />

‚encourage‘ weeds to grow.” Grötzinger has also produced<br />

“MC compost” from the solid phase. “To do that,<br />

the material is spread on a storage clamp and compacted.<br />

The nitrate and moisture content must be well-balanced.<br />

It takes eight weeks for compost that is rich in<br />

humic acid to form and that way there is less carbon<br />

loss than in usual compost,” he explains. According to<br />

the current fertilizer ordinance, MC compost may no<br />

longer be produced on open fields, although as it turns<br />

out, it is completely dry beneath the storage clamp and<br />

Nmin sampling has not shown considerable amounts of<br />

nitrogen. That is why Grötzinger stores the solid phase<br />

in a covered horizontal clamp and then distributes it<br />

like that.<br />

“The system needs time to warm up,” Grötzinger summarizes.<br />

He maintains that you cannot expect any<br />

miracles overnight. But the trend in the right direction<br />

became clear quite quickly. “We managed to produce<br />

between 0.2 and 0.5 percent of humus within three<br />

years – depending on the location,” he said. But he<br />

spends a lot of time on the plant production system,<br />

criticizing that the biggest problem of some of the farms<br />

nowadays is the lack of time. “Everyone is in a hurry,<br />

nobody wants to wait.”<br />

He criticizes the lack of patience and the fact that liquid<br />

manure or digestate is then spread on the fields in<br />

as early as March. “If you see how wet the soil is, you<br />

shouldn’t be driving over it with a total weight of 25<br />

tons.” He said that last year, he sowed maize as late as<br />

June 2 nd and then managed to shred 60 tons of fresh<br />

matter; and that is all grown organically with a supply of<br />

15 cubic meters of digestate. “I’ve never known anyone<br />

not to succeed because they did something too late, but<br />

rather because they did it too early. Just wait and keep<br />

cool,” he says. “If you take pleasure in the method and<br />

the soil, the rest will practically work by itself.”<br />

photo: Christian Dany<br />

Author<br />

Christian Dany<br />

Freelance Journalist<br />

Gablonzer Str. 21 · 86807 Buchloe<br />

00 49 82 41/911 403<br />

christian.dany@web.de<br />

12


Biogas Journal | <strong>Spring</strong>_<strong>2021</strong> English Issue<br />

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English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

Rolf Schneider examines the<br />

crop development in a mixed<br />

crop of rapeseed and peas. He<br />

is one of the pioneers of no-till<br />

farming in Germany.<br />

Feeding soil life<br />

with organic matter<br />

Rolf Schneider, who is a farmer, has been cultivating<br />

his land with the no-till farming method for 30 years and<br />

builds up humus in the soil with fermented products.<br />

By Dipl.-Journ. Wolfgang Rudolph<br />

This year’s crop of rapeseed in Rolf Schneider`s<br />

field in Apolda, Thuringia, has bright yellow<br />

flowers and good branching. He sowed the crop<br />

with the no-tilling method in wheat stubble on<br />

September 8 th 2019 together with peas as a corollary<br />

plant. The legumes in the mixed crop collected nitrogen<br />

with their nodule bacteria until late fall. Once the peas<br />

were winter-killed, the rapeseed had sufficient nutrients<br />

in the spring.<br />

Schneider considers the no-till farming method which<br />

he also applies to all the other fields on his 300-hectare<br />

farm as the most natural form of agriculture. The concept<br />

of this system of cultivation has formed the basis<br />

of his farming strategy for the past 30 years. That makes<br />

Rolf Schneider one of the pioneers of no-till farming in<br />

Germany to which he is making a crucial contribution.<br />

He is more surprised than annoyed at the fact that the<br />

whole scene is relatively limited, as so many of the facts<br />

become obvious when you take a close look at them.<br />

And the generally good harvests he gets from his fields<br />

in such a dry area of the Weimar district would justify<br />

the results, as would the relatively low crop losses in the<br />

past two, very hot summers. The precipitation amounts<br />

in that period were considerably below the annual average<br />

of just under 500 mm. Only a few interested visitors<br />

came to inspect his fields and those of other notill<br />

farming enthusiasts in Germany from the vicinity.<br />

Instead, farmers from New Zealand or Australia came<br />

to exchange experience. Many of them were making<br />

repeated visits.<br />

“In any case, you can no longer rely on the experience<br />

you have in the area on weather development, not even<br />

if you take the wide fluctuation margin into account,”<br />

said Schneider. He added that only the relatively good<br />

water retention capacity is still as it was before.<br />

More than just non-inversion tillage<br />

“But the term no-till farming is a little unfortunate,”<br />

says 53-year-old Schneider. He says that it is more than<br />

just a matter of merely skipping some of the field work,<br />

particularly what he refers to as “continually rummaging<br />

through the field” to save machine power. He claims<br />

that is more the result of a strategy that focuses on field<br />

soil and soil life, meaning micro-organisms, bacteria<br />

and fungi. “The overall goal is to attain consistently<br />

loose, fertile soil that regenerates, forms humus and<br />

stores carbon in a cycle. To achieve that, the soil must<br />

be allowed to rest. This idea has inspired me back when<br />

I was still a young farmer,” says Schneider.<br />

He says you can see that, for example, in the forest or in<br />

permanent grassland. But in cultivated fields, the soil<br />

life has to be preserved and provided with organic material<br />

by doing without tillage, either through the root<br />

excretions of living plants or decomposition products<br />

of dead plant particles. “This is exactly what is best<br />

achieved by sowing the main crop into an established<br />

cover crop or stubble, intercropping and mixed seedphotos:<br />

Carmen Rudolph<br />

14


Biogas Journal | <strong>Spring</strong>_<strong>2021</strong> English Issue<br />

ing,” said the farmer when describing the basic idea of<br />

the cultivation system. He continued saying that applying<br />

the organic manure directly in the soil also promotes<br />

the formation of humus.<br />

The peas sown as corollary plants with the rapeseed<br />

show that this not only provides additional nitrogen, but<br />

a whole row of other effects achieved by non-inversion<br />

tillage. That includes better root penetration in the soil,<br />

suppression of flea beetles and other harmful insects<br />

with odors that are not typical for rapeseed, reducing<br />

the use of herbicides by ensuring faster soil coverage<br />

and, last but not least, the provision of food for soil<br />

organisms.<br />

In order to keep track of the effects of horticultural<br />

measures like that, Schneider inspects the nutrient<br />

status on each of his 18 fields in five-year intervals in<br />

addition to the legally prescribed soil samples by making<br />

a full soil analysis according to the Kinsey method.<br />

With this approach, the percentages of 13 nutrient elements<br />

are examined in a laboratory in the USA. “The<br />

balance of the individual micronutrients in relation to<br />

each other is decisive for the evaluation of the soil fertility<br />

derived from that,” Schneider explained. So, he<br />

injected the rapeseed field with a nutrient solution prepared<br />

according to the Kinsey recommendation.<br />

Before the farmer, who comes from the Westerwald in<br />

Hessen, acquired the former “Volkseigenes Gut” (German<br />

for People-Owned Property; abbreviated VEG) in<br />

Apolda in 1992, he had already gained experience<br />

with minimum tillage methods on his family’s farm. “It<br />

bothered me that vast quantities of energy were being<br />

consumed just to bring the field to heel with technology<br />

The dense population of earthworms in<br />

the field indicates diverse soil life.<br />

use,” said Schneider, thinking back. He also received<br />

fresh impulse from the ideas of the agricultural machinery<br />

manufacturer Horsch in the 1980`s. Schneider had<br />

bought one of the tillers with a sowing bar for broad<br />

seeding, the “sowing actuator”, which then was still<br />

mounted in the barn on the Sitzenhof farm in Schwandorf<br />

and used it for many years. The Horsch com-<br />

The digestates that<br />

come from the small<br />

liquid manure system are<br />

completely spread on the<br />

fields as fertilizer with a<br />

strip-tilling machine or a<br />

slurry injector.<br />

“It bothered me that vast quantities of<br />

energy were being consumed just to bring<br />

the field to heel with technology use”<br />

Rolf Schneider<br />

15


English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

Rolf Schneider uses the Primera seed drill made<br />

by Amazone on his farm for the sowing.<br />

The equipment<br />

of the Primera<br />

seed drill made by<br />

Amazone includes<br />

coulter units for<br />

no-till farming.<br />

Digestate to supply nutrients and improve<br />

the soil is applied directly in the soil, for<br />

example with slurry injectors.<br />

The strip-till machine is often used before the<br />

corn is sown to deposit digestate as fertilizer.<br />

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English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

The pea seeds added to the main crop of rapeseed assume a<br />

whole series of other tasks besides supplying nitrogen.<br />

The little nodules on<br />

the network of roots of<br />

the corollary plants of<br />

peas collect nitrogen<br />

for the main crop,<br />

which is rapeseed.<br />

The root crowns of the rapeseed plants had<br />

a diameter of almost 3 centimeters in just<br />

under eight weeks after the sowing.<br />

The mixed crops consisting of rapeseed and peas had already<br />

developed well by the end of October last year.<br />

pany then changed its approach and was no doubt very<br />

successful. But for Schneider, that meant too many<br />

compromises that he does not want to make.<br />

The aversion to soil-working power tractors met with<br />

economic constraints during the expansion of the farm<br />

in Apolda, where the staff includes his partner, Petra<br />

Stoll, and an employee. “We couldn’t afford a large<br />

fleet of machines to farm in the traditional way it’s done<br />

in this region,” Schneider remembered. Moreover,<br />

there were problems with erosion in the rugged terrain.<br />

So, he made a virtue out of necessity and adapted the<br />

technology to the fields, not the other way round.<br />

Digestates improve soil fertility<br />

Today, the machinery at the farm in Apolda includes<br />

the robust Brazilian airseeder Semeato and the Ama-<br />

18


Biogas Journal | <strong>Spring</strong>_<strong>2021</strong> English Issue<br />

zone Primera equipped<br />

with coulter units for<br />

no-till farming with a<br />

working width of 6 meters<br />

for sowing in drills.<br />

The Semeato has a dead<br />

weight of 3.5 tons. That<br />

enables the twin discs<br />

to penetrate the ground<br />

in order to sow the seed<br />

because the soil is partly<br />

clayey and is hard during<br />

the dry periods.<br />

Schneider is planning to<br />

technically upgrade the<br />

seeders to plant the crop<br />

in specific areas. All the<br />

machines are equipped<br />

with an automatic tire<br />

pressure control system<br />

to protect the soil.<br />

The fertilizer spreader is only used selectively,<br />

for example, for targeted application<br />

of nutrients based on the Kinsey recommendations.<br />

Otherwise, nitrogen fertilization,<br />

apart from farm manure, is only performed<br />

based on ammonium, mainly by<br />

injection using the Cultan method. Schneider<br />

gave up milk production with the<br />

400 cows that were initially part of the<br />

farm in 2018. Instead of that, he now has<br />

an average of 700 heifers that are reared<br />

for a large dairy farm in a region otherwise<br />

dominated by arable farming.<br />

Manure and dung out of the livestock production<br />

are fermented in 900 cubic meter<br />

(m³) fermenters in the small 75 kW liquid<br />

manure system that was put into operation<br />

in 2012. The annual yield of 8,000<br />

to 9,000 m³ of digestate is applied to the<br />

fields as grain top fertilization by slurry<br />

injectors in the spring, or by means of a<br />

strip-tilling unit, which creates a nutrient<br />

depot under the subsequently sown row of<br />

corn. This work is done by contractors. “I’m<br />

currently looking for a service provider who<br />

can apply liquid manure with a tube wagon,<br />

that is, by means of pipes from the biogas<br />

plant to the field. That would be feasible<br />

on the fields near the farm, which take up<br />

about half of the farm surface, and would<br />

also be another way of reducing soil pollution,”<br />

he says.<br />

A sensitive issue of no-till farming is the use<br />

of total herbicides. “The problem is not so<br />

much the weeds,” says Schneider. He says<br />

that he can handle that, as the absence of<br />

tillage would significantly reduce the activation<br />

of weed seeds. And a few things<br />

could be done about the crop rotation. But<br />

in order to plant cereals or maize in catch<br />

crops, which are typical for no-till farming,<br />

Glyphosate is indispensable for killing the<br />

plant cover. He sees neither other means<br />

that have a comparable effect, nor a practical<br />

alternative procedure.<br />

Crop rotation adapted to weather<br />

conditions and the market<br />

Schneider says that since he took over the<br />

farm, he has been focusing on “returning<br />

the soils to their natural balanced states<br />

with the no-tilling farming system and restoring<br />

the original biology”. His target is<br />

to attain a permanent humus content of<br />

5 percent. Although he has only achieved<br />

this on part of his cultivated area, soil life<br />

has considerably increased everywhere.<br />

The now more biologically active limestone<br />

weathered soils with loess overlays, that<br />

have an average acreage of 50 but a range<br />

of 20 to 100, would show more stress tolerance<br />

and the yield variability would be<br />

lower. On average, he gets 92 decitonnes<br />

per hectare of wheat, 38 dt/ha of rapeseed,<br />

90 dt/ha of winter barley and 45 tonnes<br />

of fresh matter per hectare of silage maize<br />

from the field. Compared with the harvests<br />

in the region, that is in the upper fifth, with<br />

lower operating costs.<br />

“At any rate, you can`t rely on experience<br />

gained in the area on weather development<br />

anymore, not even if you take the large variations<br />

into account,” says Schneider. He<br />

says that only the capacity of the soil to<br />

retain water is still effective, though this<br />

is only of limited use during lengthy dry<br />

periods.<br />

Since no-till farming eliminates the need<br />

for preparatory soil cultivation and the arable<br />

land can often be driven over, even<br />

in wet weather, Schneider can adapt the<br />

crop rotation system to the weather and<br />

the expected feeding requirements. He describes<br />

the possible variations, using vetch<br />

grown with rye –which is a mixture of winter<br />

rye and fodder vetch – as an example: “If<br />

the spring is very dry, I don’t harvest the<br />

vetch grown with rye when it’s green before<br />

the ears emerge in early May as is usually<br />

done. I leave it untouched until June. The<br />

established plants absorb the little water<br />

that is available very effectively with their<br />

extensive root systems and then<br />

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English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

The farmer Rolf Schneider has been farming his land with the no-till farming method for thirty years.<br />

His particularly focuses his crop management on improving the fertility of the soil.<br />

There is an abundance of earthworm castles like<br />

that in the arable land tilled with no-till farming<br />

methods.<br />

yield plenty of fresh matter, even as whole crop silage”.<br />

Sorghum, which worked well last year, or leguminous<br />

grain mixtures could be considered as drought stresstolerant<br />

fodder plants for possible successive crops. If<br />

the weather changes and a wet period is expected, Schneider<br />

says he could sow clover grass. The harvest in the<br />

fall is then followed by winter grain. Corn only grows in<br />

a two-crop system after vetch grown with rye or Landsberg<br />

mix is harvested while it is still green. Instead of<br />

corn, these crops can be followed by a summer crop<br />

as an alternative, such as a mixture of oats and peas.<br />

Current example: In late May this year, Schneider used<br />

the Amazone direct seeding machine to sow Landsberg<br />

mix on a 50-hectare field. After it was cut and taken to<br />

the silo, Schneider planted corn on the field over the<br />

next few days without cultivating the field any further.<br />

Stop destroying the dwellings of the<br />

diligent little helpers<br />

In a field of small young wheat plants, Schneider points<br />

to numerous mounds on ducts leading downwards, the<br />

so-called earthworm castles. “That’s were my most important<br />

workers operate,” he says. The earthworms are<br />

a true indicator of life as they work tirelessly to loosen<br />

and vent the earth beneath our feet and draw organic<br />

materials and thus nutrients into lower soil layers. “We<br />

should stop continually using applicator tools that destroy<br />

the dwellings of diligent little helpers like that, who<br />

reinforce the soil against adverse weather and make it fit<br />

for the climate change,” says Schneider.<br />

On his farm, Rolf Schneider breeds young cattle for a dairy farm. The dung and manure he gets<br />

from the heifers is fermented in the biogas plant and the digestate is applied to the fields as<br />

fertilizer to improve the soil.<br />

Author<br />

Dipl.-Journ. Wolfgang Rudolph<br />

Freelance Specialized Journalist<br />

Rudolph Reportagen – Agriculture,<br />

Environment, Renewable Energies<br />

Kirchweg 10 · 04651 Bad Lausick<br />

00 49 3 43 45/26 90 40<br />

info@rudolph-reportagen.de<br />

www.rudolph-reportagen.de<br />

20


Biogas Journal | <strong>Spring</strong>_<strong>2021</strong> English Issue<br />

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21


English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

Biogas can improve the soil<br />

Healthy soil can be a guarantee for a good harvest. But impoverished soil causes major<br />

problems: Nutrients are thrown out of balance, water retention capacity will decrease and<br />

the share of humus will diminish. New considerations when confronted with “the soil<br />

factor” in times of climate change.<br />

By Dierk Jensen<br />

The earthworm is one<br />

of the most important<br />

living organisms of<br />

soil life.<br />

The world is small. Of course, he is familiar<br />

with Johann Düker, said Uwe Schmidt.<br />

“Anyone who deals with agricultural issues<br />

in the Elbe-Weser region is familiar<br />

with the biogas pioneer from Basdahl,” he<br />

said on the phone. And as chance would have it, the<br />

dairy cattle consultant Uwe Schmidt has a current<br />

newspaper with a reader’s letter by Düker lying on<br />

the desk at his office in Hipstedt on the very day of<br />

our visit.<br />

“We have always known that plants can only subsist<br />

on their haustoria. I found practical examples of that<br />

in as early as 1952/52: My father fertilized the fields<br />

every few years with compost; nitrogen was not used<br />

as a fertilizer. If there was not enough compost, a few<br />

barrels of liquid manure were spread on the fields.<br />

What interesting is that the fields fertilized with liquid<br />

manure were greener than the composted fields after<br />

just a couple of weeks,” said Düker in his reports in the<br />

Bremervörder newspaper.<br />

Furthermore: “In the second harvest at the end of<br />

August, it was the other way round. In the years that<br />

followed, the crop on the composted fields improved<br />

more and more.” And at the end of his extensive plea<br />

for greater sustainability in agriculture and society,<br />

Düker wrote that “We need to be aware that all life in<br />

God’s creation is absorbed into our food cycle through<br />

the fine roots of our plants.”<br />

photo: Silke Goes<br />

22


Biogas Journal | <strong>Spring</strong>_<strong>2021</strong> English Issue<br />

Paying more attention to the soil<br />

That brings us to the center of the issue. “Unfortunately,<br />

a lot of farmers don’t realize the consequences of<br />

their methods of cultivation and the damage they do to<br />

the soil until a lot later,” Schmidt complains. “The situation<br />

on some of the farms is deteriorating year by year,<br />

the crop yields are declining and cows in the stables<br />

are becoming increasingly ill.” Often, by the time he is<br />

consulted as an expert on animal health and nutrition<br />

at the consultancy firm “mmb”, it is too late.<br />

Uwe Schmidt and his employees have been traveling<br />

to dairy farms throughout Germany, the Baltic states<br />

and other places for the last twenty years to revitalize<br />

the performance and health of farm animals. Schmidt<br />

feels noticeably enthusiastic about healthy livestock;<br />

he himself kept a small herd of suckler cows on his own<br />

land for many years. He feels that the vitality of the cattle<br />

essentially shows whether the agricultural system on<br />

the farms is still working.<br />

That is why a holistic approach to animals, health,<br />

nutrition, excretions, dung, liquid manure, fermented<br />

manure and ultimately soil and plant growth are so extremely<br />

important to sixty-five year old Schmidt. “I’ve<br />

seen so many stables in my consultancy work. I usually<br />

see at first glance what is going wrong,” said Schmidt.<br />

“I can even smell it. If it smells bad, something is out<br />

of balance.”<br />

He has no doubt that humification is important for soil<br />

life and soil structure – not to mention the integration<br />

of climate-friendly carbon. That is why he regrets that<br />

a large percentage of farmers still do not care enough<br />

about it. “They still regard liquid manure as something<br />

like waste. They are not aware of the fact that their liquid<br />

manure is very valuable,” he emphasized. “In the<br />

end, we could fertilize our fields adequately with farm<br />

manure without using any mineral fertilizers.”<br />

He continued by saying that this can only be done<br />

through biological diversity on the fields and in the<br />

soil. Which is why he uses a special herb biology to<br />

“In the end, we could fertilize our fields<br />

adequately with farm manure without<br />

using any mineral fertilizers”<br />

Uwe Schmidt<br />

reactivate the biology in dairy feed that has a favorable<br />

impact on the health of the cows’ liver, on their hooves<br />

and ultimately on the (rotting) liquid manure. “But if<br />

everything is biologically dead, we shouldn’t be surprised<br />

if the soil is ultimately dead, too,” says Schmidt,<br />

with a warning against the stubborn continuation of<br />

conventional agriculture that always lags too much behind<br />

quantitative reasoning.<br />

It is not surprising that Uwe Schmidt works with Dr.<br />

Sonja Dreymann. The soil expert, who lives in Kiel,<br />

pursues similar approaches as those of Schmidt.<br />

Maize treated with plant<br />

biology compared with<br />

untreated crop.<br />

23


English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

Dr. Sonja Dreymann making a pH test (a rapid test using a Hellige<br />

model pH meter) to determine the pH level and to find out if the silted<br />

topsoil is caused by acidification or whether acidification can be ruled out.<br />

Dr. Sonja Dreymann using a pipette<br />

to trickle hydrochloric acid onto a soil<br />

sample for the so-called carbonate test.<br />

Dr. Sonja Dreymann<br />

during advisory work<br />

on the Szarvasi and<br />

grain stock. <br />

She thinks in terms of cycles, analyzes agriculture<br />

as a whole, with special focus on<br />

the soil and on soil life. Her customers are<br />

farmers seeking advice on how to breathe<br />

more life and more humus into their arable<br />

land once more.<br />

“If the yield isn´t good, then it was the<br />

weather,” remarked Dreymann about the<br />

Szarvasi stock produced by the biogas producer<br />

Kalle Rave in Ausacker in Schleswig-<br />

Holstein south of Flensburg. A dozen farmers<br />

and biogas producers stand around her,<br />

listening closely to her comments on a soil<br />

sample. “You can see that the root density<br />

in the lower part is quite good, but further<br />

up, right under the surface, there is a narrow<br />

soil horizon that is condensed,” she explains,<br />

breaking the piece of topsoil.<br />

Mentally combining the soil<br />

condition and nutrient supply<br />

“As the panicle likes this compaction, it<br />

gratefully spreads and increasingly forces<br />

out the energy grass.” “Well, under wet conditions<br />

up to the beginning of March and<br />

then only dryness,” a participant interjects.<br />

“How can you change that?” “Yes, sure. The<br />

weather conditions this year most certainly<br />

increased this condition, but the silting up<br />

may be a sign that there is not enough calcium<br />

on the surface because of a high potassium<br />

level, so that not enough oxygen can<br />

get into the upper layer,” Dr. Dreymann answers.<br />

To check her assumption, she makes<br />

the so-called carbonate test, for which she<br />

trickles diluted hydrochloric acid onto the<br />

photos: Dierk Jensen<br />

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Biogas Journal | <strong>Spring</strong>_<strong>2021</strong> English Issue<br />

soil horizon.“There is no formation of vapor<br />

bubbles, so there is obviously not enough<br />

calcium carbonate,” Dreymann states. She<br />

advises the biogas producer Rave to do liming<br />

in the spring and to work the field with a<br />

grass rejuvenator (a kind of harrow) before<br />

the first cut – it will gently slit open the soil<br />

so that air can get in.”<br />

Dr. Dreymann and the farmers speak at eye<br />

level. Her aim is not to discuss the topic in<br />

a monolog, but rather to find constructive<br />

solutions to the dilemma that crop yields<br />

have significantly declined at so many arable<br />

farms in recent years. Maize harvests of<br />

50 tons of fresh matter per hectare are now<br />

a thing of the past in a lot of areas. Many<br />

of the farmers at Dreymann’s practical soil<br />

seminar agree, some of them even mention<br />

up to 20 percent less harvest yields. It<br />

shows that something is going wrong.<br />

The climate change reveals<br />

management errors<br />

“Success in the field ultimately always<br />

depends on the method of cultivation,”<br />

Dreymann notes unmistakable. “The climate<br />

change and extreme weather conditions<br />

in recent years have exacerbated or<br />

confirmed this fact.” But this does not<br />

mean that there are no strategic solutions<br />

to these growing challenges. Quite the contrary.<br />

But Dreymann also said that farmers<br />

have to rethink the way they are treating the<br />

soil and that they have to realize that plants<br />

Uwe Schmidt in<br />

his own laboratory<br />

with fermentation<br />

specimens. <br />

and the soil form a close symbiosis which<br />

must be observed.<br />

For that purpose, what they knew in the<br />

past and what is still generally being circulated<br />

by the chambers of agriculture is<br />

no longer adequate. Classical soil analyses<br />

with mere NPK values do not provide the<br />

answers to important questions. Knowing<br />

more about the soil, about research on<br />

humic substances and about soil microbiology<br />

therefore requires a new transfer of<br />

the knowledge which Dreymann actively<br />

mediates.<br />

Humification plays a key role here, but it<br />

will not work if the nutrients in the soil fall<br />

out of balance. The high phosphate levels<br />

on many farms, for example, prevent the<br />

build-up of humus. According to Dreymann,<br />

if fermented manure is used appropriately,<br />

it could contribute to humification<br />

which has a high level of binding capacity<br />

for nitrogen.<br />

Promoting bacteria that fix<br />

nitrogen in the air<br />

Soil experts assume that about 2,500 kilograms<br />

of nitrogen fixation per hectare are<br />

required to increase humus in the soil by<br />

one percent. Dreymann knows that this<br />

cannot be done merely by fertilizing, but<br />

rather through the fixation of free nitrogen<br />

from the air by micro-organisms that also<br />

live around the roots of non-leguminous<br />

matter.<br />

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with more diversity and greater root<br />

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English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

carbon and nitrogen in the soil for a long<br />

period. Neither carbon nor nitrogen will be<br />

bound in the soil without energy. “The close<br />

relationship that exists between nitrogen<br />

and carbon is often misunderstood in climate<br />

discussions,” Dreymann said.<br />

“My aim is to achieve a five-percent humus<br />

level on my fields in the long term,” says<br />

Kalle Rave to the group of seminar participants.<br />

That is an ambitious goal, as right<br />

now his fields have a humus level of two<br />

percent. But he is confident that he and his<br />

successor Ole Dietz will succeed. They plan<br />

to finance the additional costs required to<br />

store more carbon in the fields with a bonus<br />

from regional commercial enterprises in<br />

which they have their CO 2<br />

emissions compensated<br />

for by targeted humification.<br />

That will give crop plants and mixed crops,<br />

that normally do not achieve sufficient revenues<br />

on the agricultural markets, a new significance,<br />

as they will revive local diversity,<br />

contribute to reducing their share of CO 2<br />

and also help to generate heat, electricity<br />

and fuel. Dreymann and the biogas farmers<br />

Kalle Rave (second from the<br />

right) explains to his colleagues<br />

which characteristics have to be<br />

taken into account when cultivating<br />

the cup plant Silphium<br />

perfoliatum.<br />

Humification on Kalle Rave’s farm<br />

Kalle Rave’s farm comprises pig fattening, 270 hectares of arable land and a<br />

biogas plant with an output of almost one megawatt. Rave wants to achieve<br />

humification with a crop rotation range of wheat, rye, triticale, silage maize,<br />

Szarvasi grass, beets and mixed winter grain consisting of rye, triticale, Welsh<br />

grazing grass, vetches and clover.<br />

Although it is getting increasingly dry in other regions, Rave can hardly complain<br />

about a lack of rainfall in his area. Quite the contrary: Precipitation levels<br />

in Ausacker have even risen from formerly 850 millimeters to 980 millimeters<br />

per square meter and year in the past 30 years.<br />

He fertilizes his crops with manure and fermented manure, if available – the<br />

rest is fertilized “on a mineral basis”. He used the so-called SOBAC system<br />

this year for the first time. He hopes, that will enable him to reduce fertilization<br />

costs in the future. He still uses a plough for the spring crops and only has to<br />

use “relatively small amounts of herbicide”.<br />

The northern latitude makes Schleswig-Holstein a border region for maize; the<br />

soil in that federal state between the seas warms up later and more slowly after<br />

the winter compared to other regions in Germany. Rave knows that this is one<br />

more reason why the maize needs well loosened soil that optimally enhances the<br />

development of the roots. So far, non-inversion tillage has not been an issue in<br />

northern Schleswig-Holstein. “That can only be done from a humus content of<br />

five percent upwards,” said Rave.<br />

Although he does not use any biological supplements like compost tea or enzymes,<br />

he is nevertheless open to these approaches. In the past, he added<br />

sauerkraut juice to the manure and the digestates to improve their treatment.<br />

Meanwhile, venting the manure on his farm has proven to be difficult because<br />

the manure is in a closed container and is only pumped into the open container<br />

shortly before it is distributed on the fields. But Rave consistently uses<br />

vegetable carbon in the fermenter. That binds the nitrogen in the fermented<br />

manure and minimizes both the amount that is leached in the soil and what is<br />

discharged into the atmosphere when it is applied to the fields.<br />

26


Biogas Journal | <strong>Spring</strong>_<strong>2021</strong> English Issue<br />

Pumps- and Agitators<br />

Classical tillage under scrutiny: Can tilling be done without a plough?<br />

from Ausacker agree that that will not work<br />

with classical-conventional arable farming<br />

with classical cash crops, like rapeseed,<br />

wheat and barley.<br />

Rave is not alone in times of climate<br />

change. He is a member of the Boben Op<br />

association that is aiming to promote a local<br />

energy transition and is actively tackling<br />

new approaches to CO 2<br />

sequestration.<br />

By now, about a dozen famers are participating<br />

in Boben Op with the aim of obtaining<br />

revenues of 1,500 euros per hectare<br />

within a period of five years by means of<br />

climate-friendly humification.<br />

There is a comparable project in the<br />

metropolitan area of Munich in southern<br />

Germany, where the participants of the<br />

“Himmelserde” project are pursuing similar<br />

goals. Even if they are still in the early<br />

stages, these concepts encompass new opportunities<br />

that the biogas industry should<br />

definitely take advantage of in times of deteriorating<br />

weather and soil conditions.<br />

Author<br />

Dierk Jensen<br />

Freelance Journalist<br />

Bundestr. 76 · 20144 Hamburg<br />

00 49 40/40 18 68 89<br />

dierk.jensen@gmx.de<br />

www.dierkjensen.de<br />

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English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

The FOS/TAC (VOA/TIC) value<br />

put to the test<br />

Together with the research and development department at MT Energy Service GmbH,<br />

scientists at the HAW Hamburg compared and tested the classical VOA/TIC method of<br />

biogas process monitoring according to Nordmann with an alternative calibrateable<br />

method for the first time over an extensive period of time. The VOA/TIC value describes<br />

the proportion of volatile organic acids to the buffer capacity. The buffer capacity is<br />

measured by total inorganic carbonate.<br />

By Prof. Dr. Paul Scherer, Martin Pydde, Dipl.-Ing. Sebastian Antonczyk and Dr. Niclas Krakat<br />

The VOA/TIC value according to Nordmann,<br />

which is calculated by means of double titration,<br />

has come to play a significant role<br />

in the process monitoring of biogas reactors<br />

since it was published by Weiland and<br />

Rieger in the Biogas Journal 4_2006 (Scherer 2007).<br />

Depending on the balance between the formation of<br />

acid and methane, acid metabolites occur that, at high<br />

concentrations, can inhibit the methane formation or<br />

even completely acidify the anaerobic process of decomposition,<br />

which is why it has to be assessed very<br />

carefully. We want to present an alternative procedure<br />

as a comparison to the VOA/TIC value. It is based on an<br />

Diagram 1: Diagram of the new GC-VOA value that was tested in<br />

recent years by HAW Hamburg and the MT Energy Service GmbH<br />

(MTES) with or without reference to the TIC buffer value<br />

New<br />

combination<br />

Previous<br />

combination<br />

VOA<br />

TIC<br />

TIC<br />

VOA<br />

Is more relevant.<br />

Is more accurate.<br />

Stability rating biogas plant<br />

The new GC-VOA value provides an accurate total value in acetic acid equivalents<br />

to control the process or the acetic acid-propionic acid ratio, the AA/PA ratio.<br />

accurate, calibrateable analysis of short-chained fatty<br />

acid metabolites in the biogas process using gas chromatography<br />

(GC). This accurate analysis of the fatty<br />

acid metabolites alone is sufficient to rate the stability<br />

of biogas plants, but can also refer to the TIC value,<br />

meaning the pH buffer capacity (see diagram 1).<br />

Particular acceptability of the conventional VOA/TIC<br />

method is the result of double titration of a biogas<br />

reactor sample with 50 millimolar (mM) of sulpuric<br />

acid that can be carried out quickly with comparatively<br />

compact equipment. This method that was once<br />

established to monitor sewage sludge digestion, was<br />

published in a paper by Nordmann in the Verbandszeitschrift<br />

Korrespondenz Abwasser journal (KA, 1977)<br />

as a “Staff supplement” with an exact replica of<br />

McGhee from 1968. At that time, there was no modern<br />

analytical equipment available, such as GC or HPLC<br />

(High Pressure Liquid Performance) with operating<br />

routines and PC connection.<br />

In double titration according to Nordmann or McGhee,<br />

the TIC value (“Total Inorganic Carbonate”), the socalled<br />

buffer capacity, is determined in the first phase,<br />

and the “VOA” value, the sum of organic fatty acid<br />

metabolites, is determined in the second. For basic<br />

pH buffers, a weak base or a salt of this weak base,<br />

for example hydrocarbonate/carbonate, should be able<br />

to delay or “buffer” the pH drop in the titration, also<br />

called pH buffer, if small amounts of a strong acid (for<br />

example bivalent sulphuric acid, H 2<br />

SO 4<br />

) are added.<br />

At a pH value of 6.5, the carbonate buffer is 50 percent<br />

hydrocarbonate and 50 percent carbonate (see Diagram<br />

2). This fifty percent value is also called the pK<br />

value and this is the area where buffering is strongest.<br />

This value is 4.8 for short-chain, weak organic acids<br />

(VOA) that are also buffered in a pH range of 3.0 to<br />

6.5. When using manure and renewable raw materials,<br />

a role is also played by the alkaline ammonium buffer<br />

(pK value 9.24) and the phosphate buffer (three pK<br />

values: 2.15, 6.8 and 12.3).<br />

28


Biogas Journal | <strong>Spring</strong>_<strong>2021</strong> English Issue<br />

Diagram 2: Diagram of the two main buffer areas in the microbial biogas<br />

process, the acid buffer of the short-chain organic fatty acid metabolites (VOA)<br />

and the alkalinity/”lime reserve” (TIC) of the hydrocarbonate buffer<br />

VOA I TIC [mg Hac-Equ L -1 ]<br />

VOA buffer<br />

GC-VOA method<br />

VOA / TIC alkalinity<br />

Previous VOA/TIC method<br />

Hydrogen carbonate buffer<br />

buffer<br />

buffer<br />

Unrecorded fatty acids<br />

(previous VOA / TIC method)<br />

Besides the VOA and TIC diagram, there is the phosphate buffer with a pK value of 6.8, the ammonium<br />

buffer with a pK value of 9.24 is more or less outside of that. In the final titration values<br />

of 4.4, 5.0 and 5.75, fatty acids are “cut off” and are not detected, which is something that<br />

cannot happen in the GC-VOA method which is separately calibrated for each fatty acid.<br />

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Digester contents are a mixture of<br />

buffer solutions<br />

Thus, biogas digesters are basically a mixture<br />

of buffer solutions that can normally<br />

be titrated with sulphuric acid in order to<br />

obtain a rough estimate of the buffer quantities<br />

of short-chain organic acids (C 1<br />

-C 6<br />

)<br />

and also of the carbonate buffer (TIC value)<br />

they contain by means of the titration<br />

amount changed in that way (see Diagram<br />

2). Incidentally, the carbonate buffer is<br />

also an essential component of physiologically<br />

important blood buffer.<br />

The titration end points usual for the VOA/<br />

TIC value are shown in Diagram 2. The TIC<br />

value according to Nordmann (titration up<br />

to a pH value of 5.0) is converted and given<br />

as a calcium carbonate equivalent or “calcium<br />

reserve” in CaCO 3<br />

milligrams (mg)<br />

per liter. The VOA value (titration of pH 5.0<br />

to 4.4) states the acetic acid equivalents<br />

in mg/l or ppm (parts per million). Half a<br />

dozen variations can be found in literature,<br />

for example, Ripley 1086 (=APHA 1992)<br />

titrates from pH 5.75 to 5.0 instead of<br />

from pH 5.0 to 4.4 (see Diagram 2).<br />

In the Biogas Journal published in 2006,<br />

Rieger and Weiland were the first to compare<br />

the VOA/TIC values according to Nordmann<br />

(or McGhee) with concentrations of<br />

short-chain organic acid metabolites determined<br />

by titration by using an HPLC<br />

analysis method that could be validated<br />

and they found that the values correlate. At<br />

the same time, GC and HPLC analytics are<br />

of equal value, each fatty acid is calibrated<br />

individually.<br />

The VOA titration values of 500 to 5,000<br />

acidic acid equivalents (mg/kg), however,<br />

were more a point cloud with a mean value<br />

of 2,000 that was not forced to the zero<br />

point, while the values determined very accurately<br />

according to the concentration via<br />

HPLC lay on a straight line that was forced<br />

to the zero point. It is important to keep<br />

in mind that in a titration from an alkaline<br />

range (pH ≈ 8.0) to 5.75 or 5.0, a part of<br />

the TIC and also the VOA buffer is not recorded<br />

(see Diagram 2). Thus, the resulting<br />

TIC value in the second titration from<br />

pH = 5.0 to 4.4 according to Nordmann<br />

(McGhee) or in Ripley from pH = 5.75 to<br />

5.0 is added to the VAO value.<br />

Thus, an excessively high erroneous VOA/<br />

TIC initial value is suggested, particularly<br />

in greatly buffered liquid manure biogas<br />

systems with low fatty acid values, that is<br />

not forced to the zero point, such as in digestion<br />

towers. As a result, it usually only<br />

starts at 0.2 with Nordmann, although the<br />

parallel concentration of fatty acids is still<br />

within an acceptable range.<br />

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29


English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

Diagram 3: Process monitoring at an agricultural large-scale biogas plant (2.5 MW el, install<br />

) over a ten-month period<br />

VOA / TIC Nordm.; VOA Eq-GC/TIC + 0,3<br />

VOA / TIC Nordm.<br />

VOA Eq-GC/TIC<br />

TIC<br />

TIC<br />

Test days<br />

Comparison between the VOA Nordmann/TIC Nordmann (red)<br />

and the new VOA Equ GC value/TIC (green)<br />

and also the TIC value (blue).<br />

Diagram 4: Process monitoring of the agricultural biogas plant in diagram 3 shown over a period of 10 months, the VOA/TIC ratio according<br />

to Nordmann (red) is shown in turn as a reference, and also the acetic acid reference values (VOA Equ GC) shown alone without the TIC value<br />

as a ratio (dotted, grey), moreover the new propionic acid / acetic acid value shown as a ratio (PA/AA, green) in the modified mode<br />

VOA / TIC Nordm.<br />

PA/AA modified<br />

VOA Eq-GC<br />

VOA / TIC; PS/ES mod<br />

VOA Eq-GC [mg/I]<br />

Test days<br />

Handling samples accurately<br />

As recently as 2014, Purser at al. modeled a modified<br />

mathematical correction factor for the VOA/TIC value<br />

according to Nordmann and Ripley, so that it then<br />

forced to the zero point. However, the previous titration<br />

points were still considered feasible for both methods<br />

and were not questioned. In the meantime, there have<br />

been publications by Hinken, Voß, Weichgrebe and<br />

Rosenwinkel about titration according to Nordmann<br />

(for example in Biogas Journal 6_2012) which emphasize<br />

accurate pre-treatment of samples by filtration or<br />

centrifugation. In addition, the measurement result is<br />

greatly affected by the age of the sample (CO 2<br />

outgases<br />

and changes the carbonate buffer) and by representative<br />

sampling from the reactor.<br />

A comparably large variance of the measurement according<br />

to Nordmann that depends on the laboratory<br />

is also reflected in an interlaboratory comparison made<br />

by the Bavarian State Research Center for Agriculture<br />

(Köcker and Henkelsmann, Biogas Journal 1_2011).<br />

Thus, in an extreme case, a measurement of same<br />

sample led to VOA/TIC values of between 0.11 and<br />

0.88, resulting in an averaging range of between 0.3<br />

and 0.45. This disastrous divergence among the laboratories<br />

shows that a comparison between the different<br />

laboratories with VOA/TIC Nordmann can only be done<br />

with great uncertainty.<br />

Rieger and Weiland cautiously write “… Even if a limit<br />

value of ≤ 0.3 is considered as relatively certain for<br />

a stable process, this value is still mainly significant<br />

30


Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

English Issue<br />

for the observation of its long-term development…” (2006).<br />

They also point out that a mere pH check in a well-buffered<br />

renewable raw materials biogas plant with or without liquid manure<br />

(TIC>7,000) is insufficient because the pH value hardly<br />

changes.<br />

There is no universal validated reference to estimate the VOA/<br />

TIC ratio for a safe biogas process. Our own experience shows<br />

that the slurry-corn biogas plants (TIC value between 9,000 and<br />

25,000) such as those of Rieger and Weiland with an acceptable<br />

range with a VOA/TIC value of


English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

ergy, 2013) on “Process Monitoring in Bio gas Plants”,<br />

however one that is commercially available with freely<br />

adjustable titration points. The VOA equivalent GC value<br />

determined in the test should in no case be smaller<br />

than the buffer capacity (usually the latter should be<br />

four times greater), as the biogas reactor would acidify.<br />

Diagrams 3 and 4 show process monitoring at a typical<br />

agricultural biogas plant (2.5 MW el, install<br />

) with 70 percent<br />

maize, 30 percent liquid manure, dung and grain<br />

waste over a period of ten months. They show that the<br />

VOA Nordmann/TIC Nordmann (red) never falls below<br />

0.25, and partly rise from 0.4 to 0.5 due to imbalances.<br />

The VOA Equ GC values (converted to total acetic acid<br />

equivalents) react parallel to that. To make the curves<br />

lie directly above each other for better comparison, the<br />

VOA Equ GC/TIC was added by 0.3. The pH merely value<br />

fluctuated between 7.75 and 8.0, and the TIC value<br />

moved from 15,000 to 25,000 mg CaCO 3<br />

equivalent<br />

per liter (see Diagram 3).<br />

The quantitative fatty acid pattern through gas chromatography<br />

would supply even more information for the<br />

biology, in this case particularly the propionic acid or<br />

the ratio of propionic acid to acetic acid (PA/AA) as a<br />

marker (see Diagram 4). Butyric acid, that can be split<br />

into two acetic acid molecules, occurs comparatively<br />

seldom, like valerian acid (C 5<br />

) or caproic acid (C 6<br />

) and<br />

is thus not shown. A high acetic acid level with low propionic<br />

acid AA/PA = between 5 and 10 to 1 (AA>1,000<br />

mg/l) may indicate a deficiency in micronutrients. However,<br />

biogas plants are particularly at risk from propionic<br />

acid, which is difficult to degrade. Therefore the<br />

PA/AA ratio was selected here.<br />

To make sure that the PA/AA ratio provides useful, unambiguous<br />

results, it is important to take into account<br />

that a division by zero is not mathematically defined.<br />

That means that the concentration of acetic acid has<br />

to be greater than zero [AA]>0. Furthermore, a visually<br />

more balanced interpretation of the measurement results<br />

in the diagrams is shown if the low concentrations<br />

are hidden, so that the following applies:<br />

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I. [AA]: (0 ; 200] = { C ∈ R : 0 < C ≤ 200}<br />

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The defined limits of 200 mg/l acetic acid (AA) and 150<br />

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to counteract any bias in the result, an amplification of<br />

peaks with low propionic acid concentrations proved<br />

to be useful,<br />

III. PA


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33


English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

NuTriSep: Nutrient extraction and<br />

peat substitute from digestates<br />

When the pilot project began two years ago, it was small enough to fit into one container on<br />

the farm in the Kupferzell district of Füßbach. But now a fully operable treatment facility<br />

for digestates on the operating area of the Agro Energie Hohenlohe GmbH & Co. KG fills the<br />

entire building, which was formerly used to keep pigs.<br />

By Dipl.-Ing. Heinz Wraneschitz<br />

Fabian Geltz calls the nutrient recycling system<br />

a “nutrient production plant” and seems to be<br />

very pleased with it. “Besides phosphorous,<br />

other nutrients and peat substitutes are recovered<br />

systematically in high-quality separate<br />

fractions,” explains the process engineer, who is the<br />

junior manager and executive assistant of Geltz Umwelttechnologie<br />

GmbH in Mühlacker, which is a town<br />

in northwestern Baden-Wuerttemberg.<br />

Phosphorous: About 40 million tonnes of it are applied<br />

as phosphate fertilizer to fields and gardens all over the<br />

world. That is about more than 80 percent of the mineral<br />

wealth of white phosphate minerals extracted from<br />

the earth per annum, usually in Africa, China and North<br />

America. But scientists around the world agree that<br />

there will only be enough reserves of phosphate rock<br />

for a few more decades. That is why a whole series of<br />

research projects are underway for the recovery of used<br />

phosphate. A lot of experiments are being made with a<br />

variety of liquids. Even in Germany: Experts are trying<br />

to make this recovery in the large municipal sewage<br />

plants. Or on the biogas plant in Kupferzell-Füßbach.<br />

The Agro Energie Hohenlohe power plant, with its rated<br />

output of 700 kilowatts electric (kW el<br />

), has been in<br />

photos: Heinz Wraneschitz<br />

34


Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

English Issue<br />

Thomas Karle explaining<br />

the plant for the recovery of<br />

phosphorous (phosphate)<br />

and other substances.<br />

operation since 2001. The gas<br />

tank has been enlarged several<br />

times, peak power has doubled.<br />

The plant has a total of three<br />

combined heat and power plants<br />

(CHP plants). An ORC turbine to<br />

convert the heat of exhaust gas<br />

into electricity was installed in<br />

the largest CHP in 2019 to increase<br />

efficiency.<br />

The purchase of heat from the<br />

CHP plant has been fully secured<br />

for years, says the director<br />

Thomas Karle. Füßbach itself is<br />

a real bioenergy village and has<br />

been obtaining most of its energy,<br />

electricity and heat from<br />

its biogas plant. There is also a<br />

hall on the company premises in<br />

which grain and other substances<br />

can be dehumidified for a fee.<br />

NADU with a positive life<br />

cycle assessment<br />

Last but not least, the digestates<br />

from the plant are dried there.<br />

The product Agro Energie Hohenlohe<br />

advertises in the Internet<br />

is called “NADU Natural Fertilizer”:<br />

“An innovative fertilizer<br />

from Baden-Wuerttemberg that<br />

is not only good for your plants,<br />

but also for the environment.”<br />

Because of its “positive life cycle<br />

assessment, NADU has received<br />

several sustainability awards! It<br />

is produced by a controlled fermentation<br />

process and is made exclusively out of raw<br />

materials and products.”<br />

The biogas plant in Füßbach differs from many others<br />

when it comes to substrate material for the fermenter.<br />

“Various fractions of animal manure – from cows,<br />

pigs and horses. And added to that, mainly vegetable<br />

by-products, such as grape marc or vegetable waste,”<br />

Karle adds. The bulk of animal manure is provided by<br />

full-time farmers from the small village and from a radius<br />

of three kilometers, the plant remains come from<br />

no more than 17 kilometers of the surrounding area.<br />

Thomas Karle has been promoting the concept of getting<br />

nutrients from land cultivation for a long time now.<br />

“Where does it make sense to place the nutrients outside<br />

of agricultural application?” So far, he has mainly<br />

been trying to respond to this question by using the<br />

NADU gained from the digestate. His involvement may<br />

also be due to the fact that he is the honorary chairman<br />

of Gütegemeinschaft Gärprodukte e.V. (GGG),<br />

which cooperates closely with Fachverband Biogas e.V.<br />

“The problem with the nutrients is exacerbated even<br />

further by the fertilizer ordinance,” says Karle. And<br />

while elsewhere digestate dewatering “usually only<br />

reduces the volume, here something is filtered out, individual<br />

tradable substances,” says the biogas plant<br />

operator enthusiastically. And he points to the huge<br />

plant with numerous containers and machines in what<br />

used to be a pigsty.<br />

NuTriSep – Technology on an industrial<br />

scale<br />

Basically, this system, which was developed by Geltz<br />

and set up in 2019, is an upscaling of the container<br />

prototypes that have already been tested here on an<br />

industrial scale. But there is a small catch: The largescale<br />

plant could process 70,000 tonnes (t) of liquid<br />

per year, but the Agro Energie Biogas plant only has an<br />

annual flow rate of 18,000 tonnes.<br />

In 2019, the VR Banks in Baden-Wuerttemberg awarded<br />

Geltz first prize at the Innovations Awards for the Nu-<br />

TriSep development and the step towards the versatile<br />

industrial scale, which was an achievement for the test<br />

facility that was already in operation in Füßbach at the<br />

time. Since January 2020, Isabella Maier, who works<br />

for Geltz as a product engineer with a master’s degree<br />

in environmental protection engineering, has been able<br />

to demonstrate in real terms on tours of the plant that<br />

the anticipated award was obviously justified. Even if<br />

visitors do not really know straight away what there is to<br />

see. The former pigsty has exactly 30 single units that<br />

are consecutively numbered. Geltz describes this as<br />

follows: “A sequence of several filtration, solution and<br />

precipitation steps to extract nutrients from digestates<br />

and gain uncontaminated residual water with-<br />

Isabella Maier from Geltz Umwelttechnologie holding<br />

various forms of phosphate sludge.<br />

35


English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

Overview of the NuTriSep process<br />

Biogas plant of Agro Energie<br />

Hohenlohe GmbH & Co. KG.<br />

The process starts with the separation of organic solids:<br />

The phosphate and the ammonium nitrogen dissolve<br />

when sulphuric acid is added; the solid matter<br />

is also freed of it. The (gaseous) ammonia converts to<br />

liquid ammonium when the pH value is lowered, thus<br />

preventing it from escaping.<br />

The sulphuric acid that is used does not endanger<br />

plant growth. That is important, as after the hygienization,<br />

the solid matter that accrues should be able<br />

to be used as a peat substitute in horticulture. This<br />

material is valued at more than 10 Euros per cubic<br />

meter and more than 40 Euros per tonne.<br />

“Phosphate is precipitated from the remaining liquid.<br />

The phosphate salts that result are of mineral quality<br />

and can either act as fertilizer instead of apatite fluoride<br />

or be used in the chemical industry,” says Geltz<br />

describing the next process step. The phosphate salt<br />

costs about 80 Euros per tonne.<br />

The liquid that is now free of phosphate is stripped of<br />

ammonia in a closed stripping unit – by raising the pH<br />

value and the temperature. According to Geltz, “in this<br />

process, the ammonium is changed back to ammonia<br />

and advances to the gas phase in the stripping unit.<br />

It is freed of ammonia in an acid gas scrubber, which<br />

produces an ammonium sulphate solution, briefly referred<br />

to as ASL.” With a nitrogen content of 8 percent,<br />

ASL is a common commercial product. Value: about 25<br />

Euros per tonne. After this process step, the residual<br />

water is free of solids, phosphate and ammonium.<br />

It can be used to irrigate the fields.<br />

WRA<br />

Irrigation on<br />

arable land<br />

Separation of<br />

organic matter<br />

Phosphate<br />

precipitation<br />

Ammonia<br />

stripping<br />

Physical<br />

separation<br />

Direct<br />

discharge<br />

Organic<br />

solids<br />

Phosphate<br />

salts<br />

Nitrogen<br />

solution<br />

out a fertilization effect to create valuable,<br />

marketable products.”<br />

Development of digestate<br />

The digestate is pumped over from the biogas<br />

plant via a pipeline. A new supply shaft<br />

was constructed specially for that. On its<br />

way through the units in the former pigsty,<br />

the liquid always has to flow through<br />

increasingly finer filters and a number of<br />

chemicals are added during the process. At<br />

the beginning of the process chain, there<br />

are two identical storage tanks, T1 and T2.<br />

“The addition of sulfuric acid dissolves<br />

phosphorus from the solid and it passes<br />

into the liquid phase. The coarse organic<br />

solids are separated,” says Maier.<br />

Thomas Karle describes the solids and fibres<br />

that are filtered out as a “loose product<br />

that is very similar to peat”. Agro Energie<br />

sells this peat substitute “to a certain industrial<br />

customer, who uses it to make<br />

composites for riding arenas or for the production<br />

of turf.” The liquids essentially go<br />

through three steps: A screw press sorts the<br />

fibres. Then even smaller solids are sifted<br />

out in a vacuum separator, also called a vacuum<br />

spiral filter. The final micro-filtration<br />

then removes the entire suspended matter<br />

residues that are above 0.2 micro-meters<br />

(µm). “After that, the digestate looks like<br />

apple juice,” says Isabelle Maier, holding<br />

up a glass of that liquid. The salts and other<br />

nutrients that are still dissolved in it are extracted<br />

later.<br />

Recovery of phosphate salts and<br />

ammonium sulphate<br />

“Phosphate is taken out by adding caustic<br />

soda. The phosphate salts become phosphate<br />

sludge and in the end, after the drying,<br />

there are phosphate plates that can be<br />

granulated,” Maier and the plant operator<br />

Karle explain together. The nitrogen in turn<br />

is separated from the liquid as “ammonium<br />

sulphate”. During the so-called “ammonia<br />

stripping”, the liquid is heated to 50<br />

degrees Celsius, the pH value rises, the<br />

ammonia becomes gaseous and escapes.<br />

Energy is later extracted again from the<br />

heated liquid through heat recovery. “The<br />

packing of the stripping unit enlarges the<br />

Dosage of sulphuric acid: When sulphuric acid is<br />

added, the phosphorous is dissolved from the solid<br />

matter and goes into the liquid phase.<br />

36


Biogas Journal | <strong>Spring</strong>_<strong>2021</strong> English Issue<br />

surface of the liquid through which the ammonia is<br />

emitted,” Maier explains pointing to an enclosure covered<br />

by Plexiglas with two redundant systems. That is<br />

where the ammonia gas is filtered in an “acid scrubber”<br />

and combined with sulphuric acid to form the ammonium<br />

sulphate solution ASL. “The procedure is finished<br />

when the pH value is 7, meaning that it is neutral,” says<br />

Maier. An ASL produces about 200 liters per hour.<br />

The fourth separation step is in the<br />

testing phase<br />

But the development of NuTriSep is still continuing:<br />

Geltz Umwelttechnologie is currently trying to treat residual<br />

waters by means of reverse osmosis so that it<br />

can be discharged into watercourses. “After the process<br />

preceding it, the reverse osmosis is extremely efficient.<br />

The concentrate of the reverse osmosis is rich in potassium<br />

and can be used as a potash fertilizer.” So, will the<br />

digestate from the biogas plant of Agro Energie Hohenlohe,<br />

that is often considered a “taboo issue” (Thomas<br />

Karle), soon be producing a fourth viable product besides<br />

peat substitute, phosphate and an ammonium<br />

sulphate solution?<br />

Solid content is separated by the vacuum separator.<br />

Author<br />

Dipl.-Ing. Heinz Wraneschitz<br />

Feld-am-See-Ring 15a<br />

91452 Wilhermsdorf<br />

00 49 91 02/31 81 62<br />

heinz.wraneschitz@t-online.de<br />

www.bildtext.de · www.wran.de<br />

Original image at the gas leak detection at the biogas plant<br />

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37


English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

Seven biogas plants<br />

supply one gas<br />

feed-in plant<br />

A majority of the biogas plants in the state of Rhineland-<br />

Palatinate are located in the Bitburg-Prüm district (Eifel<br />

region). Most of them were commissioned in the period<br />

from 2009 to 2011, but some as early as 2001. Now the<br />

operators are asking themselves how things will continue<br />

when the funding by the Renewable Energy Sources Act<br />

(EEG) expires.<br />

By Marie-Luise Schaller, EUR ING<br />

Wolfgang Francois<br />

and Jürgen Neuß in<br />

front of the raw gas<br />

storage unit of the<br />

treatment plant.<br />

The regional energy provider, the Stadtwerke<br />

Trier (SWT) public utility, is working on<br />

incorporating the proven potential of the<br />

regional biogas producers into the future<br />

energy supply strategy. In the “Regional<br />

Interconnection System Western Eifel”, [Regionales<br />

Verbundsystem Westeifel] the Eifel municipal networks<br />

(Kommunale Netze Eifel (KNE), established in 2009<br />

by the Bitburg-Prüm district (Eifel region) and the SWT)<br />

connect the long-term security of the drinking water<br />

supply with the improvement of the structures for expanding<br />

renewable energies.<br />

The core component of this infrastructure project, the<br />

only one of its kind in the country, is an 80 kilometre long<br />

pipeline route for drinking water, electricity and broadband<br />

lines as well as biogas and natural gas pipelines.<br />

It runs from the boundary with the state of North Rhine-<br />

Westphalia in the north to the region around Trier in the<br />

south. To Arndt Müller, technical management director<br />

of the SWT, it is important to make the best possible<br />

use of the existing, abundant renewable energies by constructing<br />

a flexible system in connection with biogas.<br />

As a result, he became one of the primary initiators<br />

of another cooperative solution which supports the repowering<br />

of the biogas plants. H. Berg & Partner, an<br />

engineering firm based in Aachen, provided guidance<br />

for design and planning for the initial feasibility analyses<br />

produced in 2013, which examined the idea of<br />

connecting several operations to one biogas collection<br />

pipeline in order to treat the biogas on a large scale in<br />

a central plant and then to feed it into the new natural<br />

gas interconnected grid system.<br />

The participants founded their own company, Biogaspartner<br />

Bitburg GmbH, for this purpose. Company<br />

partners are the Stadtwerke Trier (SWT), the private disposal<br />

business Luzia Francois and the Landwerke Eifel<br />

AöR public utility. In turn, the following are partners<br />

in the Landwerke Eifel AöR: the Eifel municipal networks<br />

(KNE), the Bitburg-Prüm district (Eifel region),<br />

the Bitburg public utility and the collective municipality<br />

Bitburger Land, the community of Speicher, the<br />

Südeifelwerke AöR public utility and the water works<br />

associations Trier-Land and Kylltal.<br />

A gas collection pipeline 42 kilometres long<br />

The idea didn’t stop here. The 42 kilometre long biogas<br />

collection pipeline was laid in an east-to-west direction,<br />

seven biogas plants were connected and in February<br />

2020, start-up operation began for the central gas<br />

treatment after a construction period of just six months.<br />

Wolfgang Francois, managing director of Biogaspartner<br />

Bitburg GmbH, remembers the challenging time during<br />

which he and his partners were developing the project:<br />

“The complexity and size of the project required numerous,<br />

intense discussions in order to convince the<br />

farmers to connect their plants to the collection pipephoto:<br />

Marie-Luise Schaller<br />

38


Biogas Journal | <strong>Spring</strong>_<strong>2021</strong> English Issue<br />

photo: ETW Energietechnik GmbH<br />

line. They are experienced experts in biogas production,<br />

which is their contribution to the project. Their<br />

participation in the project offers them prospects for<br />

the period after which the EEG funding expires. The<br />

banks also needed specific clarification in view of the<br />

tremendous dimensions of the project so that project<br />

financing could be secured.”<br />

In addition, he continues, the amendments to the EEG<br />

always generated new challenges with regard to costeffectiveness,<br />

which continually forced the partners to<br />

develop new strategies. “In general, we focus on reducing<br />

costs to a competitive level and on developing<br />

business models that don’t rely on EEG funding and<br />

that contribute to the success of the energy transition<br />

by producing green gas.”<br />

And in this sense, the contribution of this large project<br />

is quite impressive. Jürgen Neuß, managing director at<br />

the H. Berg & Partner engineering firm, notes that in<br />

the future, about 40 percent of the natural gas used by<br />

Bitburg will be replaced by the infeed of biogas from the<br />

treatment plant of Biogaspartner Bitburg GmbH. That<br />

is almost exactly equivalent to the amount required by<br />

the Bitburger brewery, one of the largest and most distinguished<br />

private breweries.<br />

As a partner, the Stadtwerke Trier public utility plays a<br />

key role because it takes care of the regional and transregional<br />

distribution of the biomethane, which keeps<br />

the value in the region. Wolfgang Francois explains: “A<br />

significant future issue for us and our partners is that<br />

we will soon begin marketing biogas as fuel for the public<br />

transport of the SWT and for heavy cargo traffic. The<br />

division responsible for the public transport of SWT and<br />

the location at the middle of the industrial park at the<br />

Bitburg airport play a helpful role here.”<br />

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39<br />

Knowledge in motion


English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

Distribution of biogas plants, route of the raw gas pipeline and location of the biogas treatment<br />

and feed-in plant in the Bitburg region and key project data<br />

Raw gas pipe – approx. 42 km long<br />

Biogas plant<br />

Biogas treatment plant<br />

Key project data<br />

Biogas suppliers<br />

Biogas collection pipeline<br />

There are currently seven biogas plants with up to 900 nm³/h raw gas volume<br />

DN 125 … 250, 42 km long<br />

Biogas storage capacity 5,300 m 3<br />

Treatment technology<br />

Treatment capacity<br />

Pressure swing adsorption (PSA)<br />

1,800 nm 3 /h raw gas – 1,000 nm 3 /h biomethane<br />

ETW Energietechnik GmbH, located in Moers, is the<br />

treatment supplier. Their convincing response to the<br />

functional tender of the H. Berg & Partner engineering<br />

firm, which was open to all types of technology, offered<br />

the lowest energy costs. Dr. Oliver Jende, sales engineer<br />

at ETW, emphasises that the ETW SmartCycle ® PSA<br />

gas treatment method also features a simple process<br />

and high availability (reference plants with 99 percent<br />

availability) and it handles changing raw gas qualities<br />

and amounts well.<br />

“A significant future issue for us and<br />

our partners is that we will soon begin<br />

marketing biogas as fuel for the public<br />

transport of the SWT and for heavy<br />

cargo traffic”<br />

Wolfgang Francois<br />

Jürgen Neuß notes that the main challenge of the planning<br />

contract was to optimise the transportation of<br />

the raw gas through the 42 kilometre long collection<br />

pipeline both technically and with regard to power. The<br />

biogas producers deliver the biogas up to this point.<br />

Biogaspartner Bitburg GmbH has already begun with<br />

the construction and operation of the feed-in plants. At<br />

the plant site at the Bitburg airport, the raw biogas is<br />

first collected from the gas tank with a capacity of up to<br />

5,300 cubic metres.<br />

It consists of about 53 percent methane (CH 4<br />

) and<br />

about 46 percent carbon dioxide (CO 2<br />

). In addition, it<br />

contains low concentrations of oxygen, hydrogen sulphide,<br />

nitrogen, etc. To remove pollutants, particularly<br />

hydrogen sulphide, an activated carbon filter is located<br />

upstream of the biogas treatment plant. This treatment<br />

removes primarily CO 2<br />

from the raw biogas. This process<br />

is performed in six containers filled with a special<br />

activated carbon and subject to pressure in alternation<br />

(adsorbers).<br />

Pure gas with 98 percent methane content<br />

In the first phase, the containers are filled with the raw<br />

biogas at a pressure of about 3 bar. The CO 2<br />

molecules<br />

in the activated carbon are adsorbed at this pressure.<br />

The raw gas flow is removed at a methane content of<br />

about 98 percent and transferred to the feed-in station<br />

on the natural gas grid. When the pressure then<br />

decreases in the second phase of the pressure swing<br />

adsorption process, the separated CO 2<br />

is discharged<br />

from the adsorbers.<br />

The plant is designed to process 1,800 nm³ of raw gas<br />

per hour; it is currently running at about half of that<br />

load. The plan is to connect up to three more biogas<br />

plants to the existing group. Altogether, the biogas from<br />

up to 48 biogas plants in the region could be used in<br />

a central treatment process. In order to do so, more<br />

transport and treatment systems must be constructed.<br />

According to information provided by Wolfgang Francois,<br />

the initial operating experiences of Biogaspartner<br />

Bitburg GmbH have been consistently positive. Currently,<br />

fine-tuning is underway. In a few months, the<br />

40


Biogas Journal | <strong>Spring</strong>_<strong>2021</strong> English Issue<br />

valuable insights gained from practice will be available.<br />

Some of this knowledge will be transferrable to other<br />

sites and will become the basis for further project developments.<br />

photo: Stadtwerke Trier Versorgungs-GmbH<br />

Flexible utilisation of biogas possible<br />

Participating farmers have two options for utilising<br />

their biogas. One possibility is feeding in the maximum<br />

amount, which increases the total amount of green<br />

gas produced regionally. Another possibility, however,<br />

is that they can still use their CHP system for on-site<br />

conversion of the biogas to electricity. This way, they<br />

can profit from market developments if less energy can<br />

be produced with the fluctuating renewable sources of<br />

wind and solar power. This makes them an important<br />

component of the regional energy network that the SWT<br />

public utility is building.<br />

The Stadtwerke Trier public utility is creating the distribution<br />

and sales structures so that profitable business<br />

models can be created, and in turn, so that the region<br />

generates added value and establishes a secure, inexpensive<br />

energy supply. The ideas that regional energy<br />

provider SWT will realise in the future also include integrating<br />

the production of green hydrogen. This will<br />

make SWT a pioneer in the implementation of regional<br />

interconnection concepts for expanding renewable energies.<br />

That`s why it`s no wonder that the minister of<br />

the environment for the state of Rhineland-Palatinate,<br />

Ulrike Höfken, did not hesitate to attend the official<br />

commissioning ceremony on 24 August 2020.<br />

Author<br />

Marie-Luise Schaller, EUR ING<br />

ML Schaller Consulting<br />

mls@mlschaller.com<br />

www.mlschaller.com<br />

Official commissioning<br />

of the Bitburg biogas<br />

feed-in plant on<br />

August 24, 2020.<br />

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41


English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

Denmark totally<br />

committed to<br />

organic residues<br />

Copenhagen<br />

Only residues such as<br />

stable manure, stover<br />

and potato peelings<br />

are used at the plant<br />

in Ringe.<br />

Denmark is among the growing markets for biogas. In the period from 2012 to 2020, the biogas production of<br />

our neighbours to the north increased more than threefold, currently reaching about 4.1 billion kilowatt hours.<br />

Biogas is primarily used to generate electricity; however, it is expected that the percentage that is treated and<br />

fed into the gas grid will increase. The ambitious goals that Denmark has set for 2035 also include a complete<br />

shift away from fossil fuel sources and the decarbonisation of 70 percent of the gas grid. Notably, in addition<br />

to agricultural biogas plants, there are quite a few very large plants at industrial scale.<br />

By Thomas Gaul<br />

In terms of biogas production, Denmark<br />

has always followed its own path.<br />

For example, energy crops have never<br />

played the same role as substrate as<br />

they have here up to now. Instead, from<br />

the very beginning, Denmark committed<br />

to using residues and made the circular<br />

economy a priority. This demonstrates that<br />

cattle manure and pig slurry can serve as a<br />

source of nutrients for the bacteria in the<br />

digester, even on a large scale.<br />

Up to now, substrate in Danish biogas<br />

plants was still allowed to contain up to 25<br />

percent maize, but this figure has now been<br />

reduced to 12 percent. In future, the plants<br />

will have to manage with just six percent<br />

maize. The Nature Energy Midtfyn biogas<br />

plant in Ringe demonstrates how this looks<br />

in practice. In three digesters, each with a<br />

volume of 8,500 cubic metres, 360,000<br />

tonnes of biomass are processed annually.<br />

Previously, this also included a percentage<br />

of maize silage and grain meal.<br />

Stable manure, stover and the like<br />

instead of maize<br />

But now only alternative biomass such as<br />

stable manure, stover or potato peelings is<br />

used. The amount of agricultural residues<br />

totals 75 percent; 25 percent is biowaste<br />

from households, restaurants and cafeterias.<br />

To prevent unpleasant smells, collection<br />

takes place in a closed hall. After the<br />

residues are unloaded into an underground<br />

container, a crane with a gripper is used to<br />

feed the biomass into the chopping process<br />

because it is important to open up the cell<br />

walls of the material before fermentation.<br />

The treatment is performed with a hammer<br />

mill in a drum in which heavy steel chains<br />

rotate and chop the material. Together with<br />

slurry from animal husbandry, the material<br />

is pumped into the first digester. After<br />

a retention time of 20 days, the substrate<br />

is pumped into the second digester, where<br />

it remains for another ten days. The process<br />

takes place at a temperature of 52<br />

degrees Celsius in the digesters. The lorries<br />

that pick up the slurry from the agricultural<br />

operations take the liquid fermentation<br />

residues back with them as return freight.<br />

The biogas is processed and fed into the<br />

gas grid. They have also discovered an application<br />

for the CO 2<br />

removed during biogas<br />

treatment: It is used to produce beer.<br />

Biogas from fish residues<br />

In a recently expanded plant in Herning,<br />

after pasteurisation they also ferment<br />

slaughterhouse waste and fish residues<br />

that arrive from Norway by ship. In addition,<br />

650 tonnes of slurry flow daily into the<br />

four digester towers of Herning Bioenergi<br />

A/S where it is transformed into biogas. Two<br />

of the towers have a volume of 3,500 cubic<br />

metres each and the other two 8,000 cubic<br />

metres each.<br />

In Herning, gas is not converted to electricity<br />

in combined gas and heat power plants.<br />

Neither is the biogas specially treated in<br />

photos: Thomas Gaul<br />

42


Biogas Journal | <strong>Spring</strong>_<strong>2021</strong> English Issue<br />

order to feed it into the natural gas grid.<br />

Instead, Herning Bioenergi has two large,<br />

direct customers – and they belong to Arla<br />

Foods, a global dairy company with cooperative<br />

ownership including over 13,500<br />

dairy farmers from Sweden, Denmark, Germany,<br />

Great Britain, Belgium, Luxembourg<br />

and the Netherlands.<br />

A 21 kilometre long gas pipeline connects<br />

the biogas plant in Herning to the first farm<br />

in Naviro. From there, another 6 kilometre<br />

long pipeline runs to the Arla production<br />

site in Videbæk. Only when it reaches these<br />

two production sites the biogas is burned in<br />

a total of three combined heat and power<br />

plants (CHP). The electrical power generated<br />

is used on site for the base load supply<br />

as well as for heat.<br />

But even though all three CHP plants<br />

achieve an output of about three megawatts<br />

with cogeneration, the demand for<br />

the two milk processing operations is many<br />

times greater. “Because the base load is so<br />

high and we only contribute only a small<br />

percentage of it, we can be sure that the<br />

biogas is really used,” explains Olav Hald,<br />

plant manager of the biogas plants in Herning.<br />

This offtake security creates a basis<br />

for continuous operation with optimum<br />

biological processes.<br />

Lots of cows and a grit washer<br />

Torben Pedersen currently has 2,000 cows<br />

in Holsted. From a small operation at the<br />

beginning, the farm has grown continuously<br />

over the years. Each cow produces<br />

an average of 40 litres of milk per day. The<br />

yields of 800 hectares of forage maize,<br />

400 hectares of grass and 200 hectares<br />

of grain are used to feed the cattle. When<br />

they are in their stalls, the cows stand on a<br />

bed of sand. “Since then I haven’t had to<br />

deal with hoof problems anymore,” Torben<br />

Pedersen reports.<br />

The disadvantage here, though, due to the<br />

herd size, is the huge demand for sand.<br />

“Per week I need 160 tonnes,” says Pedersen.<br />

This not only poses a logistics problem,<br />

but it is also a cost issue. In 2016, in<br />

order to separate the sand from the slurry,<br />

Pedersen invested in an innovative grit<br />

washer. He uses it to reprocess the sand<br />

so that it can be used in the stalls again.<br />

The separated slurry is delivered to a biogas<br />

plant. By regulating the dry matter and<br />

flow meter, the grit washer is continuously<br />

supplied with the slurry-sand mixture. A<br />

cyclone separator divides the slurry from<br />

the sand. The sand settles out in the grit<br />

washer, where it is rinsed with clean water<br />

and removed by the screw conveyor.<br />

After it is dried, the sand can be reused.<br />

The desanded slurry flows from the grit<br />

washer through a drum screen, where it is<br />

separated into a liquid portion and a solid<br />

phase. About 10 to 12 cubic metres of raw<br />

slurry can be pumped into the grit washer<br />

per hour.<br />

Slurry acidification is quite<br />

common<br />

An important issue for our neighbours<br />

to the north is the acidification of slurry.<br />

There are various practical methods for<br />

adding sulphuric acid to slurry. The goal<br />

is to decrease the outgassing of ammonia<br />

by reducing the pH value. This eliminates<br />

the need to immediately incorporate it into<br />

the soil. In general, the pH value is set at<br />

6 if the slurry will be distributed within the<br />

next 24 hours.<br />

The pH value setting is reduced to 5.5 if<br />

the slurry will be distributed within a period<br />

of up to three months. The addition of the<br />

sulphuric acid is carried out in the storage<br />

container. Reportedly, the acidified slurry<br />

does not damage the concrete. But the acid<br />

can also be added directly before distribution,<br />

either when the container is filled or<br />

directly during the spreading process. To<br />

do so, the front tractor hydraulics are used<br />

to pick up the acid tank, usually an IBC<br />

container, and the acid is dosed continuously<br />

as the slurry is spread.<br />

Johan Solmer, a farmer with an operation<br />

near Sonderborg in southern Denmark, decided<br />

to add acid to the slurry while it is<br />

still in the tank. “That gives me more flexibility<br />

during spreading in the spring,” he<br />

says, explaining his decision. The slurry is<br />

used to fertilise 250 hectares of grain and<br />

rapeseed. All of the field work is done with<br />

his own machines. Only the slurry transport<br />

and a few other small tasks are performed<br />

by a contractor. The slurry is produced by<br />

750 breeding sows. The piglets remain on<br />

the farm until they reach a weight of 30<br />

kilogrammes and then they are exported.<br />

Johan Solmer doesn`t need to handle the<br />

96% sulphuric acid solution himself. A<br />

service provider delivers it in a tank lorry. A<br />

hose connection is used to supply the acid<br />

to an agitator. The agitator is mounted on<br />

a high-performance tractor and can<br />

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43


English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

The sulphuric acid is added directly at the agitator.<br />

Tall digesters are typical at large plants in Denmark.<br />

The residues delivered in Ringe are stored temporarily in a<br />

collection hall in a container equipped with grippers.<br />

High-performance tractors are used together with large<br />

agitators for stirring and acidification.<br />

A special washing system separates the sand, a<br />

bedding material, from the organic matter, which is<br />

fermented in the digester.<br />

Slurry is transported to the plants in large tank lorries.<br />

44


Biogas Journal | <strong>Spring</strong>_<strong>2021</strong> English Issue<br />

agitate containers with volumes starting at 500 cubic metres. The<br />

acid is dosed through a nozzle located directly above the agitator<br />

paddles. The amount is set based on results provided by a pH<br />

measuring instrument. Foam is produced when the slurry is agitated<br />

vigorously as the sulphuric acid is added. For this reason, the<br />

agitator operator must constantly watch the contents of the slurry<br />

container in order to prevent it from overflowing. When the desired<br />

pH value is reached, the acidification process is stopped. When the<br />

tank lorry has left the farm, there is no longer any risk of danger.<br />

Currently, 26 percent of the farm fertiliser is fermented in Danish<br />

biogas plants, of which there are more than 90. The increase is<br />

notable because in 2012 it was just four to five percent. However,<br />

imported biomass such as molasses or olive stones also play a role<br />

in biogas production. “Danish farmers also consider maize to be an<br />

energy crop after animals have eaten it,” says Jin Mi Triolo at the<br />

University of Southern Denmark (USD) in Odense.<br />

Professor Triolo, who researches alternative biomass for biogas<br />

plants, thinks that more slaughterhouse waste will end up in the<br />

digesters of Danish biogas plants in the future. She thinks a share<br />

of 25 percent of the substrate input is conceivable. Hog operations<br />

represent an important sector of Danish agriculture, which<br />

is export oriented.<br />

Biogas has a future<br />

In the highly advanced laboratories at SDU, scientists work on<br />

the future for biogas. This energy source could play an important<br />

role in the hydrogen economy. Algae can also be produced in the<br />

digester of a biogas plant. But in Odense they are also researching<br />

material applications, such as harvesting high-quality oils from<br />

cherry stones.<br />

In the context of the EU Interreg project BIOCAS (BIOmass CAScade),<br />

they share their work with German colleagues. The project<br />

brings together 18 partners from four EU countries to cooperate in<br />

the area of the sustainable transformation of biomass streams by<br />

using new technologies, process sequences and business models.<br />

Furthermore, they are working together with other local partners.<br />

The German partners include the Heidekreis district, the 3N Competence<br />

Centre and the University of Oldenburg.<br />

In the meantime, Denmark is developing into a significant market<br />

for German manufacturers in the biogas area. For the planned<br />

construction of a mega biogas plant in Hojslev, near Viborg in the<br />

central Jutland region, Stallkamp is producing and erecting all<br />

of the digesters and equipping the plant with pump and agitator<br />

technology. Lundsby Biogas ApS, located in Denmark, is the ordering<br />

client for the large-scale project, but assembly will be executed<br />

by the Danish sales representative Biogas Teknik A/S. The biogas<br />

plant is designed for a total of 14 containers. The three tall digesters<br />

will be assembled with stainless steel roofs and the remaining<br />

11 will be equipped with gas-tight, double membrane roofs.<br />

Author<br />

Thomas Gaul<br />

Freelance Journalist<br />

Im Wehrfeld 19a · 30989 Gehrden<br />

00 49 1 72/512 71 71<br />

gaul-gehrden@t-online.de<br />

45


English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

South Korea<br />

Seoul<br />

Mandarin orange juice production –<br />

residues used to produce biogas<br />

At the centre of Jeju, by far the largest of South Korea’s islands, the German in East Württemberg-based<br />

company Lipp was able to participate in an impressive project to figure out a system for the environmentally<br />

sustainable use of residues from the manufacture of mandarin orange juice. In just ten months this system<br />

became a reality.<br />

By Achim Kaiser<br />

Jeju is a subtropical, volcanic<br />

island located 100 kilometres<br />

south of the Korean peninsula. It<br />

is about half the size of Majorca<br />

and, due to its mild climate, it<br />

offers optimum conditions for cultivating<br />

citrus plants. Moreover, thanks to its lush<br />

and diversified natural setting and its expansive<br />

beaches, it is a popular port of call<br />

on cruises through East Asia.<br />

With a market share of 55 percent, China is<br />

by far the world’s largest producer of mandarin<br />

oranges. South Korea, where cultivation<br />

is limited to Jeju, is in tenth place, with<br />

a production total of just about two percent.<br />

Due to the mild climate, more than 40 different<br />

varieties thrive on this island. On<br />

Jeju, the mandarin orange harvest takes<br />

place from October through February. Because<br />

of its high content of vitamins A and<br />

C, calcium and potassium, this well-known<br />

winter fruit is also a very healthy food. But<br />

primarily due to strict regulations, which<br />

stipulate that mandarin orange juice must<br />

consist of 100 percent fruit, the oranges<br />

are seldom processed into juice.<br />

The only production site for mandarin orange<br />

juice in Korea is located on Jeju. Its<br />

production capacity has increased steadily<br />

in recent years. The pressing residues accumulated<br />

from juice production are processed<br />

further in a dewatering system. The<br />

press cakes produced in this way are used<br />

in cattle feed and the thin, liquid phase is<br />

used to feed the biogas plant.<br />

Because the requirements for the quality<br />

of fresh water and processing water are<br />

high in the beverage industry, the increase<br />

in juice production pushed the cleaning<br />

performance of the aerobically operated<br />

wastewater treatment plant to its limits.<br />

Consequently, treating the water such that<br />

its quality is sufficient for discharge into<br />

receiving waters has become more complex<br />

and expensive in recent years. The<br />

reason was that at 165 grammes per litre,<br />

the biochemical oxygen demand (BOD),<br />

which represents the amount of oxygen required<br />

by bacteria for the biological decomposition<br />

of the organic compounds in the<br />

wastewater, was significantly higher than<br />

the permissible limit value. On the island<br />

of Jeju, the state’s environmental requirements<br />

are high. Compliance necessitated<br />

that solutions be found.<br />

Plant construction and operating<br />

experience<br />

Mandarin orange juice is not produced all<br />

year long; instead, it is a seasonal business<br />

that starts at the beginning of the harvest<br />

and lasts somewhat longer than half a year.<br />

For this reason, to ensure uniform operating<br />

performance for the biogas plant to be<br />

constructed, four vertical containers with<br />

a total storage capacity of 20,000 cubic<br />

metres were required to store the mandarin<br />

orange residue. To achieve maximum leak<br />

tightness, these containers, as well as all<br />

of the others supplied by the Lipp company,<br />

were manufactured with the patented<br />

double-seam system using a stainless steel<br />

composite material.<br />

The other containers include a universal digester<br />

(850 cubic metre) for the anaerobic<br />

treatment of the highly polluted wastewater<br />

before further aerobic treatment in the municipal<br />

wastewater treatment plant as well<br />

as a mixing tank and a buffer tank. Each of<br />

these tanks has a volume of 100 cubic metres.<br />

The biogas produced in the digester<br />

is used for heat generation for the wastewater<br />

treatment plant and the production<br />

site. The entire plant was commissioned<br />

in 2019. Since then it has been operating<br />

successfully and achieves very good BOD<br />

values of less than 3 grammes per litre for<br />

the wastewater.<br />

Author<br />

Achim Kaiser<br />

Managing Director of FnBB e.V.<br />

and Project Engineer at IBBK<br />

Fachgruppe Biogas GmbH<br />

kaiser@fnbb.de<br />

Photo: LIPP GMBH<br />

46


Biogas Journal | <strong>Spring</strong>_<strong>2021</strong> English Issue<br />

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47


English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

Manila<br />

Philippines<br />

Converting pineapple waste<br />

into biogas<br />

The Philippines is an archipelago located in Southeast Asia comprised of more than 7,000<br />

islands dotting the Pacific Ocean. With a long total coastline, the Philippines is blessed<br />

with stretches of pristine white sand beaches at the edge of crystal-clear waters. The<br />

warmth and hospitality of the Filipinos increase the potential of Philippines to become one<br />

of the top destinations for holiday and exotic travel with budget friendly options. But the<br />

Philippines also has other unseen potential, hidden in form of energy.<br />

By Medina Berbic<br />

Biogas technology was introduced in the Philippines<br />

in 1965 by Dr. Felix D. Maramba,<br />

an agricultural and mechanical engineer<br />

who is still well known there as an important<br />

scientist and developer of biogas applications.<br />

At the time it was introduced, biogas technology<br />

did not receive social or economic support as a<br />

method of energy production because fuel was cheap<br />

and readily available. It would take a few decades for<br />

the technology to gain environmental and commercial<br />

significance.<br />

The oil crisis of 1973 affected the Philippines in a way<br />

similar to the largest oil spill incident in the country’s<br />

history. After the crisis, more attention was paid to renewable<br />

energy, with a focus on the development and<br />

utilisation of hydropower, geothermal and solar energy.<br />

The biogas industry, with its complex technology, really<br />

got started much later, early in 21st century (2000),<br />

after carrying out various studies and analysing the potential<br />

of biomass. Up to this time, practical applications<br />

included just small biogas plants for home use<br />

because large-scale plants were not economically feasible<br />

due to the ubiquity of coal for power generation.<br />

After the Philippines joined the Paris Climate Accord<br />

in 2017, when the country committed to reduce greenhouse<br />

gas emissions by 70% and to increase renewable<br />

energy sources to 35% by 2030, biogas technology<br />

started to play a larger role in reaching this goal.<br />

The great potential of the Philippines, as an agricultural<br />

country, lies in the large quantities of biowaste,<br />

a problem with which the Philippine government is<br />

struggling.<br />

Photos: LIPP GMBH<br />

48


Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

English Issue<br />

4,700 MW could be produced by using<br />

all organic waste<br />

The waste management system is still not established<br />

in practice and the collected biowaste is unsorted,<br />

mixed with plastic and another waste. Further potential<br />

lies in municipal waste, animal manure – pork production<br />

is one of most important industries in the Philippines<br />

fish waste and waste from exotic fruits. For example,<br />

a study by the U.S. Energy Association, carried<br />

out in 2015, indicates that 4,700 megawatts (MW) of<br />

energy could be generated if all of the organic waste in<br />

the Philippines were utilised.<br />

Despite this high potential, biogas technology and its<br />

implementation is not yet widespread in the Philippines.<br />

There is not enough social and economic support<br />

to make up for the lack of information and experience<br />

and to help manufacturers and developers of biogas<br />

technology succeed.<br />

A few large biogas plants, with an average capacity of<br />

1 MW have been built, but most of the potential is still<br />

unused. At the same time, the country still depends<br />

heavily on coal for power generation and has the highest<br />

energy costs in comparison with other ASEAN countries.<br />

This affects not only the Filipino population, but<br />

also the country’s global competitiveness.<br />

How was the project started?<br />

Mindanao, the second-largest island in the Philippines<br />

(after Luzon), is located in the southern region of the<br />

archipelago. The largest pineapple canning facility in<br />

the Philippines, Dole Philippines, Inc., is located here.<br />

The company has two operating sites, Surallah and Polomolok,<br />

and processes fruit juices and canned fruits<br />

from pineapple as well as from smaller amounts of other<br />

exotic fruits such as bananas and mangos. Dole Philippines,<br />

Inc. is part of the Dole company, an international<br />

market leader with an extensive range of high-quality<br />

exotic fruits and products made from them. Their products<br />

can be found in every supermarket in Germany.<br />

Dole Philippines, Inc. produced more than 180,000<br />

metric tonnes of organic waste (pineapple peels) in<br />

2018 (based on the company’s statistical data), and<br />

the amount is expected to grow in the coming years.<br />

The unprocessed pineapple residue was field-composted,<br />

releasing methane into the atmosphere during the<br />

process. Using the unprocessed pineapple residue in<br />

this way, however, called attention to the high methane<br />

emissions and the insufficient consumption of the rich<br />

nutrients in the fertiliser. This resulted in the identification<br />

of ways to improve the waste management system<br />

with an eye toward reducing greenhouse gas emissions<br />

and increasing the quality of fertiliser.<br />

It was found that capturing the methane produced from<br />

the anaerobic digestion of pineapple peel waste can reduce<br />

CO 2<br />

emissions by about 50,000 t per year. In turn,<br />

this methane can be used instead of fossil fuels to generate<br />

power and steam in the factory. These significant<br />

findings and CO 2<br />

compensation played an important<br />

role in the decision to install an industrial biogas plant<br />

with a total capacity of 7.9 MW. This plant consists of<br />

two biogas plants, one at Surallah, with a capacity of<br />

2.9 MW and one at Polomolok, with a capacity of 5 MW.<br />

The estimated costs for realising this project totaled<br />

one billion Philippine pesos (16.7 million euros).<br />

With the support of the Joint Crediting Mechanism<br />

(JCM), a progamme introduced by the Government of<br />

Japan, it was possible to secure co-financing to implement<br />

this idea. The JMC programme supports the<br />

reduction of global greenhouse gas emissions by promoting<br />

advanced low carbon technologies and systems<br />

and so on in developing countries. This financing programme<br />

supports 172 projects in 17 different developing<br />

countries. This biogas project in the Philippines is<br />

titled “Biogas Power Generation and Fuel Conversion”.<br />

How did LIPP become part of the project?<br />

The German company Lipp GmbH is well-known on the<br />

international biogas market with their unique “Double-<br />

Seam System” construction technique and tanks produced<br />

from Verinox ® material. Thanks to many years of<br />

experience and expert technology, the company offered<br />

competitive solutions for meeting the challenges of realising<br />

this large biogas plant and processing pineapple<br />

residue, a feedstock that has not been adequately<br />

researched. In addition, this German biogas technology<br />

was considered a suitable technology for meet-<br />

49


English Issue<br />

Biogas Journal<br />

| <strong>Spring</strong>_<strong>2021</strong><br />

ing the high requirements for a<br />

JCM grant to ensure the longterm,<br />

reliable operation of the<br />

biogas plant and equipment.<br />

Lipp was commissioned by Met-<br />

Power Venture Partners, the official<br />

contractor of the project,<br />

to develop and build two biogas<br />

plants to be integrated into<br />

Dole’s Surallah and Polomolok<br />

canning facilities (South Cotabato,<br />

Philippines). The first<br />

draft of pre-feasibility studies<br />

for these two large-scale plants<br />

was started in 2017. Two years<br />

were needed to complete the<br />

final plans and obtain all of the<br />

necessary permits and required<br />

contracts.<br />

The biogas plant complex in<br />

Surallah consists of the following<br />

LIPP components: two LIPP<br />

ECO Digesters, each with a volume<br />

of 5,000 m 3 ,with an additional<br />

8,300 m 3 gas storage<br />

membrane, one LIPP buffer<br />

tank with a volume of 2,500 m 3<br />

and another LIPP buffer tank<br />

with a volume of 900 m 3 . The<br />

biogas plant complex in Polomolok<br />

consists of the following<br />

LIPP components: three LIPP<br />

ECO Digesters, each with a volume<br />

of 6,000 m 3 , with an additional<br />

8,300 m 3 gas storage<br />

membrane, one LIPP buffer<br />

tank with a volume of 5,000 m 3<br />

and another LIPP buffer tank<br />

with a volume of 1,300 m 3 .<br />

The construction of the first biogas plant in Surallah<br />

started in 2019, but due to the impact of covid-19 in<br />

2020, building was postponed for a few months. Additional<br />

difficulties with international travel restrictions<br />

and quarantine protocols have strongly affected the<br />

continuing work on site. Thanks to good cooperation<br />

and organization among all participants, however, work<br />

has been completed up to commissioning phase. Hopefully<br />

the plant will be in full operation in the next few<br />

months. The construction of the second biogas plant<br />

in Polomolok, with a planned start in 2020, had to be<br />

postponed due to the covid-19 pandemic. Despite the<br />

current situation, the Lipp team arrived in the Philippines<br />

some time ago and continues to work on site.<br />

Once fully operational, the two plants will utilise 100%<br />

of the pineapple waste designated for disposal to produce<br />

renewable energy and contribute to reducing<br />

greenhouse gases and air pollutant emissions along<br />

with lowering electricity costs for Dole. Once the biogas<br />

power plant is operational, the digestate, which is much<br />

more potent and environmentally sustainable, will be<br />

used. This project will certainly be among the best references<br />

for all of the participants, but it also represents<br />

one more successful milestone among the challenging<br />

projects in which Lipp has participated.<br />

Educational project for Filipinos – biogas<br />

training<br />

“Can I smell methane?” “Doesn’t it smell bad?” “What<br />

can I do with biogas?” These questions illustrate the<br />

lack of information about and experience with the biogas<br />

industry in this country. For this reason, the LIPP<br />

company carried out an additional promotion project<br />

in the Philippines with educational content. As part of<br />

a develoPPP.de project programme, experienced German<br />

biogas experts, the team of the German Biogas<br />

Association (GBA) and the LIPP team, supported by a<br />

local partner, the German-Philippine Chamber of Commerce<br />

and Industry (AHK Philippines), will provide<br />

biogas training and a biogas laboratory. This project<br />

incorporates not only high-quality technology, but also<br />

the transfer of technical know-how as well as thorough<br />

and comprehensive theoretical and practical training,<br />

including safety training.<br />

Due to the covid-19 pandemic, the experts from GBA<br />

could not travel to the Philippines to conduct the first<br />

training on site, but a virtual training programme was<br />

organized. Designed with six blocks of three hours<br />

each, the training was performed in March <strong>2021</strong> with<br />

70 participants. Filipinos participated in interactive<br />

activities and showed interest in continuing education,<br />

which provides positive feedback regarding the overall<br />

feasibility of the project. Spots are available in the three<br />

additional training sessions which will be organised in<br />

the near future.<br />

The develoPPP.de project was co-financed by the German<br />

Investment Corporation (DEG) with public funds<br />

from the German Federal Ministry for Economic Cooperation<br />

and Development (BMZ, www.developpp.de).<br />

BMZ can support your company’s innovative projects<br />

and commercial investments in developing and emerging<br />

countries provided that they offer long-term benefits<br />

for the local population.<br />

Author<br />

Medina Berbic<br />

Lipp GmbH<br />

m.berbic@lipp-system.de<br />

50


Biogas Journal | <strong>Spring</strong>_<strong>2021</strong> English Issue<br />

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