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Environmental Internship Program - 2019 Booklet

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Kasey Bowyer ’21<br />

NEUROSCIENCE<br />

Certificate: <strong>Environmental</strong> Studies<br />

CLIMATE CHANGE AND<br />

ENVIRONMENTAL SCIENCE<br />

PROJECT TITLE<br />

Impacts of Sea-Level Rise<br />

on the Halogenated Organic<br />

Compound Production in<br />

Mangrove Ecosystems*<br />

ORGANIZATION(S)<br />

Myneni Group, Department<br />

of Geosciences,<br />

Princeton University<br />

LOCATION(S)<br />

Princeton, New Jersey;<br />

Menlo Park, California<br />

MENTOR(S)<br />

Satish Myneni,<br />

Professor of Geosciences;<br />

Danielle Schlesinger, Ph.D.<br />

candidate, Geosciences<br />

I worked to understand how increasing sea-level<br />

rise has affected the production of halogenated<br />

organic compounds in various coastal<br />

environments, including mangroves. Bromide<br />

and chloride from seawater react with organic<br />

carbon in the soil to create compounds called<br />

organohalogens. Organohalogens are toxic to<br />

plant and animal life in local ecosystems and<br />

catalytically destructive to the stratospheric<br />

ozone layer, which contributes to global<br />

warming. However, the relationship between<br />

organohalogen production and sea-level rise<br />

is not well understood. I studied soil and leaflitter<br />

samples from coastal mangrove forests<br />

in Panama, Punta Galeta and Bocas del Toro.<br />

I performed synchrotron analyses (XANES<br />

and microspectroscopy), along with X-ray<br />

fluorescence (XRF), to identify the speciation of<br />

organochlorine and organobromine compounds<br />

in the samples and to determine the degree to<br />

which halogenation reactions are occurring in<br />

mangrove ecosystems. The Myneni Group also<br />

is interested in how this reaction occurs and<br />

what catalyzes it. I studied the role of iron redox<br />

chemistry in catalyzing halogenation reactions<br />

by incubating soils with various naturally<br />

occurring substances.<br />

* This internship is connected to the PEI Water<br />

and the Environment Grand Challenges project,<br />

“Impacts of Sea-Level Rise and Associated<br />

Saltwater Intrusion on the Coastal Biogeochemical<br />

Processes and Greenhouse Gas Emissions.”<br />

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