Special Report - VARTA PartnerNet UK
Special Report - VARTA PartnerNet UK
Special Report - VARTA PartnerNet UK
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Uwe Köhler and<br />
Jörg Kümpers,<br />
NBT GmbH, Hannover<br />
Eberhard Meissner,<br />
VB Autobatterie<br />
GmbH, Hannover<br />
Fig. 1:<br />
NiMH Power Assist<br />
Battery for hybrid<br />
electric vehicles<br />
(energy content:<br />
2.8 kWh, maximum<br />
discharge power:<br />
55 kW)<br />
<strong>Special</strong><br />
<strong>Report</strong><br />
High-Performance Batteries for<br />
New Automotive Applications<br />
1. Introduction<br />
2. Development Trends in the Automotive<br />
Industry<br />
3. Requirements on Battery Systems<br />
1 Introduction<br />
Triggered by a variety of new applications in vehicles<br />
of the future, battery manufacturers are<br />
currently investing much activity in developments<br />
aimed at meeting the growing technical<br />
demands of vehicle manufacturers. These new<br />
applications range from traction batteries for hybrid<br />
electric vehicles (HEV) to new battery systems<br />
for the 42V vehicle electrical power supply<br />
systems of tomorrow. Interest in hybrid electric<br />
vehicles has grown considerably, as pure electric<br />
vehicles (EV) have failed to live up to<br />
expectations. In addition to the limited range of<br />
electric vehicles, the high costs of the large traction<br />
batteries needed for EVs are also responsible<br />
for their poor acceptance on the market.<br />
1<br />
4. Battery Systems for the Vehicles of<br />
Tomorrow<br />
– Lead-Acid Batteries<br />
– Nickel - Metal Hydride Batteries<br />
– Lithium-Ion Batteries<br />
5. Summary and Outlook<br />
6. Varta – The Battery Experts<br />
7. References<br />
Hybrid electric vehicles represent an interesting<br />
compromise between an environmentallyfriendly<br />
electric vehicle and a vehicle driven by<br />
a combustion engine without range restrictions.<br />
By lowering the fuel consumption and reducing<br />
exhaust gas emissions, HEVs can make a significant<br />
contribution to increasing the environmental<br />
compatibility of automobiles.<br />
Besides hybrid electric vehicles, there are a<br />
variety of technical developments underway<br />
that are aimed at improving the comfort, safety,<br />
environmental compatibility and cost-effectiveness<br />
of conventional vehicles through the<br />
use of innovative electrical components. These
High-Performance Batteries for<br />
New Automotive Applications<br />
new vehicles can be expected to exhibit a growing<br />
need for electrical performance and power<br />
(Fig. 2). In order to meet these needs, the electrical<br />
architecture of the vehicles will have to<br />
change. Under discussion are dual-voltage<br />
electrical systems (14V/42V), high-voltage electrical<br />
systems, implementation of Integrated<br />
Starter/Alternator and energy recovery devices.<br />
These are aimed at boosting the efficiency of<br />
producing, distributing, controlling and storing<br />
of electrical energy within the vehicle.<br />
Performances required for future electrical systems<br />
Maximum Average<br />
Application performance (W) performance (W)<br />
Electrical wind shield heating 1,500 120<br />
Electro mechanical valve actuation (EMVA) 1,800 - 3,400 700<br />
Electro hydraulical valve actuation (EHVA) 400 200<br />
Electrical cooling fan 650 50<br />
Electrical water pump 600 100<br />
Electrical power steering (servo) (EPS) 900 200<br />
Electro mechanical brake 3,000 50<br />
Wave stabilisator 2,000 150<br />
Electrical fuel pump 450 150<br />
Electrical A/C compressor 4,000 1,000<br />
2 Development Trends in the Automotive Industry<br />
The architecture of future energy supply systems<br />
for vehicles will be determined by a number<br />
of different factors.<br />
Lower fuel consumption: The more efficient<br />
use of fuel in vehicles is becoming increasingly<br />
important, given the rising costs of fossil fuels,<br />
stricter legislation governing emissions and regulations<br />
aimed at cutting fleet fuel consumption.<br />
The potential fuel savings in hybrid electric<br />
vehicles can be as much as 50% compared to<br />
conventional vehicles. Yet even in conventional<br />
vehicles, significant improvements can be made.<br />
Efficient fuel consumption in this situation is a<br />
matter of generating, storing and using electrical<br />
energy efficiently within the vehicle. The potential<br />
savings can range from around 10% to<br />
way above 20%.<br />
2<br />
Fig. 2: Future vehicle electrical supply systems<br />
Power (kW)<br />
5<br />
4<br />
3<br />
2<br />
1<br />
0<br />
1995 2000 2005 2010<br />
New functions: There will be many components<br />
requiring significantly higher voltages<br />
than the normal 14V on offer today. For powerhungry<br />
consumers such as electrically-heated<br />
windows, DC converters for transforming to<br />
higher voltages do not represent a cost-efficient<br />
solution in the long term. Modern combustion<br />
engines (especially diesel engines) also need<br />
greater starting power. The subsequent shortening<br />
of the starting routine that this allows<br />
cuts emissions and reduces noise. Fast and<br />
clean starting is a key requirement for the introduction<br />
of start/stop systems, which contribute<br />
significantly to saving fuel in urban traffic.<br />
The recovery of braking energy and acceleration<br />
assistance will need even higher power,<br />
making increased operating voltages absolutely<br />
essential.<br />
Average power<br />
performance IntegratedStarter/Alternators<br />
with lead-acid<br />
batteries (42V)<br />
Average power<br />
performance<br />
conventional<br />
alternators (14V)<br />
Average power<br />
demand of vehicle<br />
electrical power<br />
supply systems
Comfort features: With the introduction of<br />
further comfort features, the overall demand for<br />
electrical energy on board the vehicle will also<br />
increase. A belt-driven system can currently<br />
provide a maximum of 2 to 2.5 kW of electrical<br />
energy. Because the power generated by the<br />
alternator however is significantly less when<br />
the engine is idle, extreme driving conditions in<br />
urban traffic with lots of waiting can lead to insufficient<br />
energy being available to supply the<br />
new comfort features. This deficit needs to be<br />
bridged with batteries.<br />
Safety: In modern vehicles, only a limited number<br />
of components that are critical for the<br />
vehicle´s operation use electrical energy, e.g.<br />
brake lights, airbag, ABS, ESP. This will change<br />
with the new “drive-by-wire” technologies,<br />
which include functions as steering, braking,<br />
locks, etc. These systems will require additional<br />
electrical energy, and in many cases at<br />
relatively high levels, at least for short periods.<br />
Besides technical advantages the changeover<br />
from mechanically to electrically-driven systems<br />
and components also offers the automotive<br />
industry opportunities to lower production<br />
costs and make better use of the available<br />
space.<br />
The new challenges facing battery systems<br />
make it all the more important to be able to determine<br />
the actual State of Charge (SOC) and<br />
the State of Function (SOF). This applies just as<br />
3 Requirements on Battery Systems<br />
42V Vehicle Electrical Power<br />
Supply Systems<br />
With the introduction of new functions such<br />
as the start/stop system, the technical demands<br />
placed on the battery system are set to change<br />
dramatically. Start/stop systems require fast,<br />
quiet and low-emission vehicle startup, and<br />
with a far greater frequency than is common<br />
today. In addition to providing the electrical<br />
energy for the starter system during startup,<br />
the battery also has to supply power to all<br />
consumers at times when the engine is switched<br />
off. Under certain circumstances, this can<br />
mean that the battery has to deliver a continuous<br />
power of 1 kW for more than a minute.<br />
After discharge, the combustion engine needs<br />
3<br />
much for hybrid concepts as it does for the<br />
other on-board battery systems of the future,<br />
and will have far-reaching consequences for the<br />
battery industry. The battery will cease to be a<br />
passive component, and will become a central<br />
system component requiring monitoring and<br />
management functions in order to safeguard<br />
the vehicle´s functionality and safety.<br />
to be restarted. The previously discharged<br />
battery needs to be recharged as quickly as possible<br />
before the vehicle comes to another standstill<br />
and the engine is switched off again. Over<br />
the life of the vehicle, tens of thousands of such<br />
charge/discharge cycles can be expected. This<br />
will increase the battery´s capacity throughput<br />
by at least one order of magnitude compared<br />
to the present situation.<br />
The demands on battery discharge power<br />
grow further if both the combustion engine<br />
needs to be started and electrical acceleration<br />
assistance (boosting) is used (approx. 10 kW<br />
for a few seconds). In regenerative braking<br />
(energy recovery), the recharge capability of the<br />
battery needs to be of the same magnitude.<br />
Fig. 3: The Battery<br />
Management System<br />
(BMS) will be part of<br />
an intelligent electrical<br />
supply system.<br />
The BMS delivers<br />
information about<br />
State of Charge and<br />
State of Function.
High-Performance Batteries for<br />
New Automotive Applications<br />
Fig. 5:<br />
Varta 36V/42V VRLA-<br />
AGM – battery for<br />
application in advanced<br />
vehicle<br />
systems with high<br />
power demand<br />
Integrated starter/alternator systems of various<br />
designs are under development for start/stop<br />
systems, boosting and energy recovery systems.<br />
The differences between these systems<br />
are related to the type of electric motor used,<br />
the transmission ratio to the crank shaft and the<br />
arrangement of the clutch systems.<br />
High-Voltage Systems for Hybrid<br />
Electric Vehicles (HEVs)<br />
The biggest motivation behind the development<br />
of hybrid electric vehicles is the dramatic reduction<br />
in fuel consumption and exhaust gas emissions.<br />
HEVs, with their typical power assist and<br />
energy recovery functions, generally work at<br />
operating voltages in excess of 200V. The battery<br />
capacity depends on the minimum requirements<br />
for energy storage and electrical performance.<br />
Virtually all hybrid electric vehicles use<br />
relatively small batteries that have been designed<br />
specifically for high discharge and<br />
recharge performance. Pure electrical propulsion<br />
has been abandoned in favor of high<br />
power capabilities. The reduction in fuel consumption<br />
is achieved by the optimized combination<br />
of combustion engine and electrical propulsion<br />
system, and by the recovery of braking<br />
energy.<br />
4 Battery Systems for the Vehicles of Tomorrow<br />
Lead-acid batteries (Fig. 5), nickel - metal hydride<br />
(NiMH) batteries and lithium-ion (Li-Ion)<br />
batteries are all under discussion for use in the<br />
vehicle electrical systems of the future. Nickelcadmium<br />
(NiCd) batteries have very poor prospects<br />
because of the same environmental con-<br />
4<br />
CIDI internal<br />
combustion engine<br />
5-speed manual transmission<br />
& automated clutch Final drive<br />
Integrated power electronics<br />
Typical power requirements for HEV battery<br />
systems vary from 20 kW to 60 kW. Because<br />
of the enormous energy throughput, high demands<br />
are placed on the long-term stability of<br />
the battery system. These battery systems<br />
need to provide sufficient power for the vehicle<br />
to travel at least 200,000 km.<br />
cerns that caused them to be ousted by NiMH<br />
batteries in many portable battery applications.<br />
High-temperature batteries such as sodiumsulfur<br />
and sodium-nickel-chloride exhibit high<br />
energy losses due to their very high internal<br />
operating temperature, which can be tolerated<br />
only in pure electric vehicles.<br />
Supercapacitors capable of delivering extremely<br />
high power are under development for applications<br />
with extreme demands in terms of performance<br />
and endurance. However, they exhibit<br />
only low specific and volumetric energy densities,<br />
and costs and weight of the power electronics<br />
needed to manage the steep voltage<br />
characteristics have so far seriously limited their<br />
application.<br />
Electrochemical storage systems, on the other<br />
hand, deliver more energy at a more stable voltage<br />
level. They can be designed either to deliver<br />
a high power output or have a high energy<br />
Battery<br />
pack<br />
Final drive<br />
5-speed manual<br />
transmission &<br />
automated clutch<br />
Electric machine<br />
Fig. 4:<br />
Energy recovered<br />
during braking<br />
can be reused for<br />
acceleration<br />
Picture:<br />
DaimlerChrysler AG
Fig. 6: Specific data of different energy storage systems<br />
Specific cold cranking<br />
power (W/kg) 1)<br />
80<br />
60<br />
40<br />
20<br />
300<br />
200<br />
100<br />
Specific energy (Wh/kg) 2)<br />
PAG<br />
POB<br />
AGM<br />
Present demands are met by a standard<br />
SLI battery of about 20 - 25 kg<br />
• Cold cranking power: ~4 kW<br />
• Energy content: ~1 kWh<br />
• Energy throughput: ~100 kWh<br />
PAG: Lead-calcium-silver technology<br />
POB: Power-optimized battery<br />
AGM: Absorptive glass mat<br />
Li-Ion: Lithium-Ion<br />
NiMH: Nickel - metal hydride<br />
Li-Ion<br />
storage capacity. Depending on the specific application,<br />
the requirements on the energy and<br />
the power density need to be harmonized, at<br />
least in part.<br />
Lead-Acid Batteries<br />
Through technical modifications, e.g. reduced<br />
electrode height, improved grid design and different<br />
arrangement of the terminals, the performance<br />
behavior of lead-acid batteries can be<br />
significantly improved. This was realized, for example,<br />
in the power-optimized battery (POB)<br />
from VB Autobatterie. In this battery, only minimal<br />
compromises are made in terms of specific<br />
and volume-related energy values. The immobilization<br />
of the electrolyte in an absorptive<br />
glass mat (AGM) brings about major improvements<br />
in the cycle life. While there is some reduction<br />
in the specific energy, the volumetric<br />
energy density remains virtually unchanged.<br />
5<br />
NiMH<br />
10 200 500<br />
Specific<br />
energy<br />
throughput<br />
of battery<br />
(kWh/kg) 3)<br />
1) t = 3 sec., Umin > 22V, T = -18 °C<br />
2) t = 20 h, T = 20 °C<br />
3) within 3 - 4 years<br />
Considerably higher power capability can be<br />
achieved through the use of ultra-thin electrodes.<br />
Because thin electrodes cannot be processed<br />
individually, electrode pairs, separated<br />
from each other by an absorptive glass mat, are<br />
spiral-wound to form a coil. The improved performance,<br />
however, is achieved at the expense<br />
of the specific energy, the energy density and,<br />
depending on the design, the endurance.<br />
Figure 6 shows the three key parameters<br />
specific energy (Wh/kg), specific cold cranking<br />
power (W/kg) and specific energy throughput<br />
(kWh/kg) of various lead systems, compared to<br />
the alternative NiMH and Li-Ion systems. The<br />
crucial advantage of the Lithium-Ion system is<br />
its higher specific energy. The most prominent<br />
feature of the NiMH system is its drastically<br />
higher energy throughput.
High-Performance Batteries for<br />
New Automotive Applications<br />
Fig. 8:<br />
Battery system<br />
for use in a hybrid<br />
electric bus (energy<br />
content: 14 kWh,<br />
power: 80 kW)<br />
Nickel - Metal Hydride Batteries<br />
(NiMH)<br />
Of all the new battery systems, nickel - metal<br />
hydride is regarded worldwide as the most technically<br />
advanced. Therefore a large proportion of<br />
new-generation electric vehicles introduced<br />
into the market have already been equipped<br />
with batteries of this type (e.g. Toyota RAV4, General<br />
Motors EV1). But the market volume of<br />
this battery types is still very small. In addition<br />
to the actual NiMH high-energy cells which have<br />
been developed to high specific energy levels<br />
of approx. 80 Wh/kg, two product lines are of<br />
interest for hybrid electric vehicles and the vehicle<br />
electrical power supply systems of the future.<br />
These product lines have been developed<br />
specially for high power requirements (Fig. 7).<br />
Power (P) Cells<br />
A typical application scenario for NiMH power<br />
cells would be the propulsion battery for conventional<br />
hybrid electric vehicles, with a specific<br />
range when used in purely electrical mode<br />
(e.g. hybrid electric buses). High performance,<br />
rapid-charging capabilities and a long service<br />
life are all important for such applications. Due<br />
to the relatively high capacity values (> 40 Ah)<br />
resulting from the energy requirements, the<br />
cells are produced in prismatic form. Even at<br />
large capacities, this construction enables a relatively<br />
large cell surface, which is required for<br />
dissipating the waste heat generated during<br />
battery operation.<br />
6<br />
Fig. 7:<br />
NiMH-Product lines for high power requirements<br />
Power(P)-Cells High-Power(HP)-Cells<br />
60, 40 Ah 5, 8, 12 Ah<br />
prismatic cylindric<br />
< 60 Wh/kg < 45 Wh/kg<br />
< 300 W/kg < 1300 W/kg (90% SOC)<br />
The high requirements in terms of electrical<br />
power are met at the expense of the specific<br />
energy and energy density, which up to 60<br />
Wh/kg and 150 Wh/l lie far below the level of<br />
high-energy cells. However, the performance<br />
during discharging and charging is significantly<br />
better. Even when discharging with a 10minute<br />
current (6 C rate), 85% of the stored<br />
energy can be converted to useful energy. The<br />
maximum specific power lies in the region of
Fig. 9:<br />
NiMH-40V-battery for<br />
new vehicle electrical<br />
power supply<br />
around 300 W/kg. Generally speaking, highpower<br />
cells can be completely recharged within<br />
around 60 minutes. Partial charging up to<br />
around 80% is even possible within 10 minutes.<br />
Rapid charging is limited by the temperature<br />
rise within the cells, caused by the exothermic<br />
formation of hydrides, and losses generated by<br />
electrical resistance, as well as gas evolution at<br />
the positive electrode in high states of charge.<br />
High-Power (HP) Cells<br />
High-power cells are the most important development<br />
of the NiMH system. They have<br />
been designed mainly for “Power-Assist” applications<br />
in state-of-the-art hybrid electric vehicles,<br />
where the improvement of energy efficiency<br />
and the reduction of exhaust gas emissions<br />
are at the forefront of the development<br />
work. Their use in new 42V vehicle electrical<br />
power supply systems is also very promising.<br />
The NiMH system has been optimized specifically<br />
for these applications to provide significantly<br />
greater performance. HP cells are currently<br />
available with capacities ranging from<br />
5 Ah to 12 Ah. Because of their relatively low<br />
capacities, these cells are produced in cylindrical<br />
form. Positive and negative electrodes, separated<br />
by a polymer fiber sheet, are spirally<br />
wound. This process is inexpensive, and is currently<br />
used to manufacture billions of portable<br />
batteries.<br />
HP cells can be continuously discharged at discharge<br />
rates of up to approx. 40 C (1.5-minute<br />
discharge) (Fig. 10). The full capacity is available<br />
at a high voltage in excess of 0.9 V (approx.<br />
80% of the open circuit voltage). The maximum<br />
specific power output of HP cells can be up to<br />
1,300 W/kg (Fig. 11). These cells can also be<br />
charged from completely discharged state at<br />
very high currents. At a charge rate of approx.<br />
20 C, HP cells can be charged to approx. 80%<br />
7<br />
Fig. 10: NiMH-HP 5 Ah<br />
Discharge characteristics<br />
Voltage (V)<br />
1.6<br />
1.4<br />
1.2<br />
1.0<br />
0.8<br />
0.6<br />
0.4<br />
0 1 2 3 4 5 6<br />
Capacity (Ah)<br />
Fig. 11: Energy power diagramm for different<br />
NiMH cell design<br />
Specific energy (Wh/kg)<br />
75<br />
50<br />
25<br />
5.5 A<br />
27.5 A<br />
55 A<br />
82.5 A<br />
110 A<br />
165 A<br />
220 A<br />
0<br />
0 250 500 750 1,000 1,250 1,500<br />
Specific power (W/kg)<br />
Power<br />
High power
High-Performance Batteries for<br />
New Automotive Applications<br />
Fig. 12: Influence of DOD (depth of discharge)<br />
on cycling endurance of NiMH cells<br />
Capacity throughput<br />
(Nominal capacity)<br />
14,000<br />
12,000<br />
10,000<br />
1)<br />
2)<br />
8,000<br />
6,000<br />
4,000<br />
2,000<br />
0<br />
2,400<br />
cycles<br />
100%<br />
1C/1C<br />
5,000<br />
cycles<br />
80%<br />
10C/10C<br />
Depth of Discharge (DOD)<br />
Charge/discharge rate<br />
approx. 80,000<br />
cycles<br />
12%<br />
18C/27C<br />
> 300,000<br />
cycles<br />
5% 1)<br />
2)<br />
5C+2C/27C<br />
SOC in less than 3 minutes. This corresponds<br />
to a specific power absorption of approx. 1,200<br />
W/kg.<br />
A “Power-Assist” battery comprising 200 HP<br />
round cells of 12 Ah nominal capacity is displayed<br />
in Fig. 1. With a relatively low energy<br />
content of 2.8 kWh, the maximum discharge<br />
power at normal ambient temperatures is more<br />
than 55 kW.<br />
Fig. 9 shows the prototype of a NiMH battery<br />
as may be used for a future 42V vehicle electrical<br />
power supply system. The battery comprises<br />
32 series-arranged individual cells, each<br />
delivering a capacity of 12 Ah. With a system<br />
weight of approx. 14 kg and an energy content<br />
of approx. 500 Wh, the maximum electrical discharge<br />
power at 20 °C is approx. 11 kW.<br />
The service life – calculated in terms of either<br />
calendar life or cycle life – is crucial for the costeffectiveness<br />
of a battery system, particularly in<br />
vehicle applications. The achievable capacity<br />
throughput is mainly determined by the charging<br />
and discharging conditions. Fig. 12 displays<br />
the dominant influence of the depth of discharge<br />
(DOD) on the attainable capacity throughputs<br />
for NiMH systems tested under various<br />
8<br />
cycling conditions. Under a cycling regime with<br />
one hour charging and one hour discharging at<br />
100% DOD, the typical service life is 2,400 cycles<br />
(reduction in capacity to 80% of the starting<br />
value). If however the cells are run in a limited<br />
SOC-window of 10% to 90%, the capacity<br />
throughputs double. Operating the batteries<br />
in a considerably smaller SOC-window (5%)<br />
enables an extreme cycle life to be achieved<br />
which corresponds to more than 14,000 times<br />
the nominal capacity throughput. Internal resistance<br />
and performance data remain virtually unchanged<br />
in this cycling operation. This means<br />
a consistent level of energy efficiency over the<br />
battery´s entire lifetime.<br />
Lithium-Ion Batteries (Li-Ion)<br />
The tremendous weight advantage over other<br />
battery systems makes the Li-Ion system a highly<br />
attractive candidate for future energy storage<br />
systems in vehicles with a particularly high demand<br />
for electric energy. While NiMH highenergy<br />
cells deliver specific energies of up to<br />
80 Wh/kg, Li-Ion high-energy cells can deliver<br />
approx. 130 Wh/kg, some 50% higher. The volumetric<br />
energy density, at 270 Wh/l, lies approximately<br />
20% above the density of equivalent<br />
NiMH high-energy cells.<br />
Current Li-Ion portable battery systems make<br />
almost exclusive use of cobalt oxide for the<br />
cathode material. However, this material cannot<br />
be used in vehicle batteries due to its poor<br />
availability and high costs. Battery manufacturers<br />
are endeavoring to use cheaper materials<br />
instead. In this regard, Varta has concentrated<br />
on the lithium-manganese spinel.<br />
Despite the tremendous technological advances,<br />
the wide-scale use of Li-Ion batteries in<br />
electric vehicles cannot yet be foreseen. This is<br />
due firstly to the old problem of inadequate<br />
energy density, as is also the case with other<br />
battery systems. The other reason is that, even<br />
when inexpensive materials are used, the price<br />
for a battery with an energy storage capacity of<br />
approx. 30 kWh is still prohibitively high. On the<br />
other hand, smaller and higher-powered battery<br />
systems are of great interest for 42V vehicle<br />
electrical power supply systems and hybrid<br />
electric vehicle applications. Similar to the NiMH<br />
cell situation, there are two product lines that<br />
are considered to offer the best opportunities<br />
for the markets of the future (Fig. 13).
Fig. 13: Li-Ion-High-<br />
Energy Cells with<br />
40 or 60 Ah (prismatic)<br />
and Li-Ion High<br />
Power Cell with 6 Ah<br />
High-Energy (HE) Cells<br />
The main stimulus for the development of Li-Ion<br />
high-energy cells is a dramatic improvement in<br />
the storage of energy (in terms of weight and<br />
volume) for supplying the vehicle electrical<br />
power supply system. Vehicles equipped with<br />
comfort features such as continuous air conditioning,<br />
infotainment, will require electrical<br />
energy storing devices of up to approx.<br />
2 kWh. Because of their high specific energy,<br />
Li-Ion batteries offer clear weight advantages<br />
over today´s lead and NiMH high-energy batteries.<br />
Were it to deliver the required storage<br />
capacity of e.g. 2 kWh or so, the weight of a<br />
lead battery would have to be around 50 kg,<br />
while a high-energy NiMH battery would be approx.<br />
30 kg. An equivalent Li-Ion battery would<br />
weigh around 20 kg, not much more than a<br />
modern lead starter battery. Fig. 16 shows a<br />
Li-Ion high-energy battery (2.4 kWh) (operating<br />
voltage: 40V) comprising 10 prismatic 60 Ah<br />
cells.<br />
High-Power (HP) Cells<br />
While the high-power NiMH system has already<br />
moved through the prototype stage and is<br />
moving towards series production, a similar<br />
development in terms of technology for Li-Ion<br />
systems is still some way in the future. Nevertheless,<br />
the results achieved to date have demonstrated<br />
the enormous potential of this system<br />
for the high-power sector.<br />
9<br />
Similar to the developments with NiMH, efforts<br />
are being concentrated on relatively small cell<br />
capacities in the range of 5 Ah to a maximum<br />
of 10 Ah. The increase in power capability is<br />
caused mainly by the use of thinner electrodes<br />
and materials that are more able to carry high<br />
currents. One fundamental problem is the conductivity<br />
of the organic electrolyte, which is<br />
around two orders of magnitude below that<br />
of aqueous media. Similar to the high-performance<br />
NiMH cells, the Li-Ion cells are manufactured<br />
using a winding technology, for technical<br />
and cost reasons.<br />
Fig. 14 shows the voltage behavior of a Li-Ion<br />
cell with a capacity of 6 Ah when it is discharged<br />
with currents ranging from 6 A to<br />
100 A. Even with a discharge current of 100 A<br />
(approx. 16 C rate), voltages amounting to more<br />
than 70% of the nominal voltage are observed.<br />
The differences between the energy storage<br />
and power behavior compared to an Li-Ion highenergy<br />
battery can be seen in Fig. 15. While the<br />
specific energy of an Li-Ion high-power cell of<br />
55 Wh/kg is around half that of a high-energy<br />
cell, its specific power is almost four times<br />
higher at approx. 900 W/kg.<br />
(cylindric) Fig. 14: Discharge characteristics of a<br />
6 Ah Li-Ion High Power cell<br />
Voltage (V)<br />
4.2<br />
4.0<br />
3.8<br />
3.6<br />
3.4<br />
3.2<br />
3.0<br />
2.8<br />
2.6<br />
2.4<br />
0 1 2 3 4 5 6 7<br />
Capacity (Ah)<br />
2A<br />
20A<br />
35A<br />
70A<br />
100A
High-Performance Batteries for<br />
New Automotive Applications<br />
Fig. 15: Energy/power diagram (Ragone Plot)<br />
for different Li-Ion cells<br />
Specific Energy (Wh/kg)<br />
125<br />
100<br />
75<br />
50<br />
25<br />
0<br />
0 250 500 750 1,000<br />
Specific power (W/kg)<br />
High energy cell<br />
High power cell<br />
Fig. 18:<br />
Electrode belt manufacturing<br />
for NiMH cells<br />
The limited service life of Li-Ion batteries is still<br />
their major weakness. It is currently determined<br />
primarily by the drop in capacity over the<br />
battery´s life. Depending on the size and type of<br />
5 Summary and Outlook<br />
The strengths of the existing lead-acid system<br />
include high availability, low costs, an existing<br />
recycling infrastructure and low self-discharge.<br />
The system´s tolerance to limited overcharging<br />
and deep discharging means only limited battery<br />
management is required for existing applications.<br />
The higher demands of future electri-<br />
10<br />
the cell, services lives of 2 to 4 years are standard<br />
under normal ambient temperatures. This<br />
is entirely adequate for most portable battery<br />
applications, although in vehicle applications a<br />
minimum service life of 5 years is required. The<br />
advances that have been made in the stability<br />
of the materials used have given rise to optimism<br />
that this problem will be solved in the<br />
foreseeable future.<br />
cal power supply systems in vehicles, however,<br />
make some battery management essential –<br />
even for lead-acid batteries.<br />
The results achieved with nickel - metal hydride<br />
technology not only support their use in the hybrid<br />
electric vehicles of tomorrow, but also open<br />
up additional areas of application for new 42V<br />
vehicle electrical power supply systems. With<br />
specific power of approx. 1,000 W/kg, these<br />
systems are in direct competition with capacitor<br />
systems. At comparable performance values,<br />
they offer an approximately 20 times higher<br />
energy storage capacity. Particular strengths include<br />
a high specific power and a high power<br />
density, high capacity and energy throughput<br />
and a long service life.<br />
As far as applications in the vehicle sector are<br />
concerned, lithium-ion technology still has some<br />
way to go before it catches up with nickel -<br />
metal hydride technology. The results achieved<br />
so far, however, show that there is considerable<br />
scope for technical enhancements. Specific<br />
powers of up to 1500 W/kg at a specific energy<br />
level of up to 80 Wh/kg would seem to be possible.<br />
The main problem currently is the calendar<br />
service life, especially under temperature<br />
conditions that can be expected in automotive<br />
applications.<br />
Fig. 17: Li-Ion<br />
High-Energy Module<br />
(40V/60Ah)
Fig. 19:<br />
Production of VRLA-<br />
AGM batteries<br />
6 Varta – The Battery Experts<br />
VB Autobatterie GmbH is a joint-venture company<br />
shared between <strong>VARTA</strong> AG and Robert-<br />
Bosch GmbH, and has production sites in Germany,<br />
Spain, France, Austria and the Czech<br />
Republic, making it one of the largest manufacturers<br />
of automotive batteries in Europe. Alongside<br />
the ongoing further development of the<br />
existing 12V (14V) lead-acid battery, VB is also<br />
working on the development of the lead-acid<br />
battery systems of tomorrow. This work mainly<br />
involves AGM technology (AGM = Absorptive<br />
Glass Mat) both for 12V (14V) and 36V (42V)<br />
systems.<br />
Batteries for new electrical power systems represent<br />
a particular area of development focus.<br />
These include various applications, such as the<br />
upcoming 42V vehicle electrical system, multivoltage<br />
vehicle electrical systems (14V/42V),<br />
and separate systems for energy and power<br />
storage. The spurs for these activities are the<br />
rapidly-growing technical demands on electrical<br />
performance in vehicles.<br />
Varta Automotive’s NBT Technology Center focuses<br />
on the development of new battery technologies.<br />
These mainly include the nickel - metal<br />
hydride and lithium-ion systems, which over<br />
the last decade have become well established<br />
in the portable battery industry and have superseded<br />
other technologies (nickel-cadmium,<br />
lead-acid) to a large extent in that field. Possible<br />
areas of application for these technologies in<br />
vehicles include 42V batteries for particularly<br />
powerful vehicle electrical systems and supply<br />
batteries for state-of-the-art, energy-saving and<br />
11<br />
ecofriendly hybrid vehicles. The features of<br />
these new applications are high electrical performance<br />
and the ability to deliver very highenergy<br />
throughput over the vehicle’s service life.<br />
The growing requirements of vehicle manufacturers<br />
on battery system technology are being<br />
met head-on through development activities focusing<br />
on intelligent batteries. The aim is to develop<br />
energy storage systems that use modern<br />
electronics, for example, to determine their current<br />
status in relation to readiness for operation,<br />
state of charge, state of health, their remaining<br />
service life and so on, to process this information<br />
and to then forward it to the vehicle’s<br />
electronic systems. VB Autobatterie and NBT<br />
are both working closely with leading vehicle<br />
manufacturers in these areas of research and<br />
development.<br />
Fig: 18:<br />
Development of<br />
Li-Ion cells<br />
Fig. 20:<br />
Electrode manufacturing<br />
for NiMH cells
High-Performance Batteries for<br />
New Automotive Applications<br />
7 References<br />
1. J. Kassakian Challenges of the New 42<br />
Volt Architecture and Progress on its International<br />
Acceptance; VDI Berichte No.<br />
1415, p.21, VDI Verlag, Düsseldorf 1998<br />
2. MIT Industry Consortium on Advanced<br />
Automotive Electrical / Electronic Components<br />
and Systems; c/o Massachusetts<br />
Inst. of Technology, Laboratory for Electromagnetic<br />
and Electronic Systems, 77<br />
Massachusetts Ave., Cambridge, MA<br />
02139<br />
3. W. Buschhaus, A. K. Jaura, M. A.Tamor,<br />
VDI <strong>Report</strong>s No. 1459, 1999<br />
4. J. R. Pierson, J. P. Zagrodnik, R. T. Johnson,<br />
Power Sources 67 (1997) 7<br />
5. D. Berndt, Maintenance Free Batteries,<br />
John Wiley & Sons, New York, 1997<br />
6. D. S. Ginley , Materials for Electrochemical<br />
Energy Storage and Conversion 2-Batteries,<br />
Capacitors and Fuel Cells; Material<br />
Research Society, Warrendale, 1998<br />
Publisher: <strong>VARTA</strong> Aktiengesellschaft<br />
Corporate Communications<br />
Am Leineufer 51<br />
D-30419 Hannover<br />
12<br />
7. M. Wakihara, O. Yasmamoto, Lithium Ion<br />
Batteries, Wiley-VCH Verlag; Weinheim,<br />
1998<br />
8. B. E. Conway, Electrochemical Supercapacitors,<br />
Kluwer Academic / Plenum<br />
Publishers, New York, 1999<br />
9. F. Burke, M. Miller, J. T. Guerin, Proceedings<br />
of Sixth International Seminar on<br />
Double-layer Capacitors and Similar Energy<br />
Storage Devices, 1996<br />
10. K. Brandt, Solid State Ionics 69 (1994) 173<br />
11. P. Bäuerlein, J. Kuempers, E. Meissner,<br />
J. Power Sources, 81-82 (1999) 585<br />
Phone +49 5 11 79 03-8 21<br />
Fax +49 5 11 79 03-7 17<br />
E-mail: uwe.koehler@nbt.auto.varta.com<br />
http://www.varta.com