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Special Report - VARTA PartnerNet UK

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Uwe Köhler and<br />

Jörg Kümpers,<br />

NBT GmbH, Hannover<br />

Eberhard Meissner,<br />

VB Autobatterie<br />

GmbH, Hannover<br />

Fig. 1:<br />

NiMH Power Assist<br />

Battery for hybrid<br />

electric vehicles<br />

(energy content:<br />

2.8 kWh, maximum<br />

discharge power:<br />

55 kW)<br />

<strong>Special</strong><br />

<strong>Report</strong><br />

High-Performance Batteries for<br />

New Automotive Applications<br />

1. Introduction<br />

2. Development Trends in the Automotive<br />

Industry<br />

3. Requirements on Battery Systems<br />

1 Introduction<br />

Triggered by a variety of new applications in vehicles<br />

of the future, battery manufacturers are<br />

currently investing much activity in developments<br />

aimed at meeting the growing technical<br />

demands of vehicle manufacturers. These new<br />

applications range from traction batteries for hybrid<br />

electric vehicles (HEV) to new battery systems<br />

for the 42V vehicle electrical power supply<br />

systems of tomorrow. Interest in hybrid electric<br />

vehicles has grown considerably, as pure electric<br />

vehicles (EV) have failed to live up to<br />

expectations. In addition to the limited range of<br />

electric vehicles, the high costs of the large traction<br />

batteries needed for EVs are also responsible<br />

for their poor acceptance on the market.<br />

1<br />

4. Battery Systems for the Vehicles of<br />

Tomorrow<br />

– Lead-Acid Batteries<br />

– Nickel - Metal Hydride Batteries<br />

– Lithium-Ion Batteries<br />

5. Summary and Outlook<br />

6. Varta – The Battery Experts<br />

7. References<br />

Hybrid electric vehicles represent an interesting<br />

compromise between an environmentallyfriendly<br />

electric vehicle and a vehicle driven by<br />

a combustion engine without range restrictions.<br />

By lowering the fuel consumption and reducing<br />

exhaust gas emissions, HEVs can make a significant<br />

contribution to increasing the environmental<br />

compatibility of automobiles.<br />

Besides hybrid electric vehicles, there are a<br />

variety of technical developments underway<br />

that are aimed at improving the comfort, safety,<br />

environmental compatibility and cost-effectiveness<br />

of conventional vehicles through the<br />

use of innovative electrical components. These


High-Performance Batteries for<br />

New Automotive Applications<br />

new vehicles can be expected to exhibit a growing<br />

need for electrical performance and power<br />

(Fig. 2). In order to meet these needs, the electrical<br />

architecture of the vehicles will have to<br />

change. Under discussion are dual-voltage<br />

electrical systems (14V/42V), high-voltage electrical<br />

systems, implementation of Integrated<br />

Starter/Alternator and energy recovery devices.<br />

These are aimed at boosting the efficiency of<br />

producing, distributing, controlling and storing<br />

of electrical energy within the vehicle.<br />

Performances required for future electrical systems<br />

Maximum Average<br />

Application performance (W) performance (W)<br />

Electrical wind shield heating 1,500 120<br />

Electro mechanical valve actuation (EMVA) 1,800 - 3,400 700<br />

Electro hydraulical valve actuation (EHVA) 400 200<br />

Electrical cooling fan 650 50<br />

Electrical water pump 600 100<br />

Electrical power steering (servo) (EPS) 900 200<br />

Electro mechanical brake 3,000 50<br />

Wave stabilisator 2,000 150<br />

Electrical fuel pump 450 150<br />

Electrical A/C compressor 4,000 1,000<br />

2 Development Trends in the Automotive Industry<br />

The architecture of future energy supply systems<br />

for vehicles will be determined by a number<br />

of different factors.<br />

Lower fuel consumption: The more efficient<br />

use of fuel in vehicles is becoming increasingly<br />

important, given the rising costs of fossil fuels,<br />

stricter legislation governing emissions and regulations<br />

aimed at cutting fleet fuel consumption.<br />

The potential fuel savings in hybrid electric<br />

vehicles can be as much as 50% compared to<br />

conventional vehicles. Yet even in conventional<br />

vehicles, significant improvements can be made.<br />

Efficient fuel consumption in this situation is a<br />

matter of generating, storing and using electrical<br />

energy efficiently within the vehicle. The potential<br />

savings can range from around 10% to<br />

way above 20%.<br />

2<br />

Fig. 2: Future vehicle electrical supply systems<br />

Power (kW)<br />

5<br />

4<br />

3<br />

2<br />

1<br />

0<br />

1995 2000 2005 2010<br />

New functions: There will be many components<br />

requiring significantly higher voltages<br />

than the normal 14V on offer today. For powerhungry<br />

consumers such as electrically-heated<br />

windows, DC converters for transforming to<br />

higher voltages do not represent a cost-efficient<br />

solution in the long term. Modern combustion<br />

engines (especially diesel engines) also need<br />

greater starting power. The subsequent shortening<br />

of the starting routine that this allows<br />

cuts emissions and reduces noise. Fast and<br />

clean starting is a key requirement for the introduction<br />

of start/stop systems, which contribute<br />

significantly to saving fuel in urban traffic.<br />

The recovery of braking energy and acceleration<br />

assistance will need even higher power,<br />

making increased operating voltages absolutely<br />

essential.<br />

Average power<br />

performance IntegratedStarter/Alternators<br />

with lead-acid<br />

batteries (42V)<br />

Average power<br />

performance<br />

conventional<br />

alternators (14V)<br />

Average power<br />

demand of vehicle<br />

electrical power<br />

supply systems


Comfort features: With the introduction of<br />

further comfort features, the overall demand for<br />

electrical energy on board the vehicle will also<br />

increase. A belt-driven system can currently<br />

provide a maximum of 2 to 2.5 kW of electrical<br />

energy. Because the power generated by the<br />

alternator however is significantly less when<br />

the engine is idle, extreme driving conditions in<br />

urban traffic with lots of waiting can lead to insufficient<br />

energy being available to supply the<br />

new comfort features. This deficit needs to be<br />

bridged with batteries.<br />

Safety: In modern vehicles, only a limited number<br />

of components that are critical for the<br />

vehicle´s operation use electrical energy, e.g.<br />

brake lights, airbag, ABS, ESP. This will change<br />

with the new “drive-by-wire” technologies,<br />

which include functions as steering, braking,<br />

locks, etc. These systems will require additional<br />

electrical energy, and in many cases at<br />

relatively high levels, at least for short periods.<br />

Besides technical advantages the changeover<br />

from mechanically to electrically-driven systems<br />

and components also offers the automotive<br />

industry opportunities to lower production<br />

costs and make better use of the available<br />

space.<br />

The new challenges facing battery systems<br />

make it all the more important to be able to determine<br />

the actual State of Charge (SOC) and<br />

the State of Function (SOF). This applies just as<br />

3 Requirements on Battery Systems<br />

42V Vehicle Electrical Power<br />

Supply Systems<br />

With the introduction of new functions such<br />

as the start/stop system, the technical demands<br />

placed on the battery system are set to change<br />

dramatically. Start/stop systems require fast,<br />

quiet and low-emission vehicle startup, and<br />

with a far greater frequency than is common<br />

today. In addition to providing the electrical<br />

energy for the starter system during startup,<br />

the battery also has to supply power to all<br />

consumers at times when the engine is switched<br />

off. Under certain circumstances, this can<br />

mean that the battery has to deliver a continuous<br />

power of 1 kW for more than a minute.<br />

After discharge, the combustion engine needs<br />

3<br />

much for hybrid concepts as it does for the<br />

other on-board battery systems of the future,<br />

and will have far-reaching consequences for the<br />

battery industry. The battery will cease to be a<br />

passive component, and will become a central<br />

system component requiring monitoring and<br />

management functions in order to safeguard<br />

the vehicle´s functionality and safety.<br />

to be restarted. The previously discharged<br />

battery needs to be recharged as quickly as possible<br />

before the vehicle comes to another standstill<br />

and the engine is switched off again. Over<br />

the life of the vehicle, tens of thousands of such<br />

charge/discharge cycles can be expected. This<br />

will increase the battery´s capacity throughput<br />

by at least one order of magnitude compared<br />

to the present situation.<br />

The demands on battery discharge power<br />

grow further if both the combustion engine<br />

needs to be started and electrical acceleration<br />

assistance (boosting) is used (approx. 10 kW<br />

for a few seconds). In regenerative braking<br />

(energy recovery), the recharge capability of the<br />

battery needs to be of the same magnitude.<br />

Fig. 3: The Battery<br />

Management System<br />

(BMS) will be part of<br />

an intelligent electrical<br />

supply system.<br />

The BMS delivers<br />

information about<br />

State of Charge and<br />

State of Function.


High-Performance Batteries for<br />

New Automotive Applications<br />

Fig. 5:<br />

Varta 36V/42V VRLA-<br />

AGM – battery for<br />

application in advanced<br />

vehicle<br />

systems with high<br />

power demand<br />

Integrated starter/alternator systems of various<br />

designs are under development for start/stop<br />

systems, boosting and energy recovery systems.<br />

The differences between these systems<br />

are related to the type of electric motor used,<br />

the transmission ratio to the crank shaft and the<br />

arrangement of the clutch systems.<br />

High-Voltage Systems for Hybrid<br />

Electric Vehicles (HEVs)<br />

The biggest motivation behind the development<br />

of hybrid electric vehicles is the dramatic reduction<br />

in fuel consumption and exhaust gas emissions.<br />

HEVs, with their typical power assist and<br />

energy recovery functions, generally work at<br />

operating voltages in excess of 200V. The battery<br />

capacity depends on the minimum requirements<br />

for energy storage and electrical performance.<br />

Virtually all hybrid electric vehicles use<br />

relatively small batteries that have been designed<br />

specifically for high discharge and<br />

recharge performance. Pure electrical propulsion<br />

has been abandoned in favor of high<br />

power capabilities. The reduction in fuel consumption<br />

is achieved by the optimized combination<br />

of combustion engine and electrical propulsion<br />

system, and by the recovery of braking<br />

energy.<br />

4 Battery Systems for the Vehicles of Tomorrow<br />

Lead-acid batteries (Fig. 5), nickel - metal hydride<br />

(NiMH) batteries and lithium-ion (Li-Ion)<br />

batteries are all under discussion for use in the<br />

vehicle electrical systems of the future. Nickelcadmium<br />

(NiCd) batteries have very poor prospects<br />

because of the same environmental con-<br />

4<br />

CIDI internal<br />

combustion engine<br />

5-speed manual transmission<br />

& automated clutch Final drive<br />

Integrated power electronics<br />

Typical power requirements for HEV battery<br />

systems vary from 20 kW to 60 kW. Because<br />

of the enormous energy throughput, high demands<br />

are placed on the long-term stability of<br />

the battery system. These battery systems<br />

need to provide sufficient power for the vehicle<br />

to travel at least 200,000 km.<br />

cerns that caused them to be ousted by NiMH<br />

batteries in many portable battery applications.<br />

High-temperature batteries such as sodiumsulfur<br />

and sodium-nickel-chloride exhibit high<br />

energy losses due to their very high internal<br />

operating temperature, which can be tolerated<br />

only in pure electric vehicles.<br />

Supercapacitors capable of delivering extremely<br />

high power are under development for applications<br />

with extreme demands in terms of performance<br />

and endurance. However, they exhibit<br />

only low specific and volumetric energy densities,<br />

and costs and weight of the power electronics<br />

needed to manage the steep voltage<br />

characteristics have so far seriously limited their<br />

application.<br />

Electrochemical storage systems, on the other<br />

hand, deliver more energy at a more stable voltage<br />

level. They can be designed either to deliver<br />

a high power output or have a high energy<br />

Battery<br />

pack<br />

Final drive<br />

5-speed manual<br />

transmission &<br />

automated clutch<br />

Electric machine<br />

Fig. 4:<br />

Energy recovered<br />

during braking<br />

can be reused for<br />

acceleration<br />

Picture:<br />

DaimlerChrysler AG


Fig. 6: Specific data of different energy storage systems<br />

Specific cold cranking<br />

power (W/kg) 1)<br />

80<br />

60<br />

40<br />

20<br />

300<br />

200<br />

100<br />

Specific energy (Wh/kg) 2)<br />

PAG<br />

POB<br />

AGM<br />

Present demands are met by a standard<br />

SLI battery of about 20 - 25 kg<br />

• Cold cranking power: ~4 kW<br />

• Energy content: ~1 kWh<br />

• Energy throughput: ~100 kWh<br />

PAG: Lead-calcium-silver technology<br />

POB: Power-optimized battery<br />

AGM: Absorptive glass mat<br />

Li-Ion: Lithium-Ion<br />

NiMH: Nickel - metal hydride<br />

Li-Ion<br />

storage capacity. Depending on the specific application,<br />

the requirements on the energy and<br />

the power density need to be harmonized, at<br />

least in part.<br />

Lead-Acid Batteries<br />

Through technical modifications, e.g. reduced<br />

electrode height, improved grid design and different<br />

arrangement of the terminals, the performance<br />

behavior of lead-acid batteries can be<br />

significantly improved. This was realized, for example,<br />

in the power-optimized battery (POB)<br />

from VB Autobatterie. In this battery, only minimal<br />

compromises are made in terms of specific<br />

and volume-related energy values. The immobilization<br />

of the electrolyte in an absorptive<br />

glass mat (AGM) brings about major improvements<br />

in the cycle life. While there is some reduction<br />

in the specific energy, the volumetric<br />

energy density remains virtually unchanged.<br />

5<br />

NiMH<br />

10 200 500<br />

Specific<br />

energy<br />

throughput<br />

of battery<br />

(kWh/kg) 3)<br />

1) t = 3 sec., Umin > 22V, T = -18 °C<br />

2) t = 20 h, T = 20 °C<br />

3) within 3 - 4 years<br />

Considerably higher power capability can be<br />

achieved through the use of ultra-thin electrodes.<br />

Because thin electrodes cannot be processed<br />

individually, electrode pairs, separated<br />

from each other by an absorptive glass mat, are<br />

spiral-wound to form a coil. The improved performance,<br />

however, is achieved at the expense<br />

of the specific energy, the energy density and,<br />

depending on the design, the endurance.<br />

Figure 6 shows the three key parameters<br />

specific energy (Wh/kg), specific cold cranking<br />

power (W/kg) and specific energy throughput<br />

(kWh/kg) of various lead systems, compared to<br />

the alternative NiMH and Li-Ion systems. The<br />

crucial advantage of the Lithium-Ion system is<br />

its higher specific energy. The most prominent<br />

feature of the NiMH system is its drastically<br />

higher energy throughput.


High-Performance Batteries for<br />

New Automotive Applications<br />

Fig. 8:<br />

Battery system<br />

for use in a hybrid<br />

electric bus (energy<br />

content: 14 kWh,<br />

power: 80 kW)<br />

Nickel - Metal Hydride Batteries<br />

(NiMH)<br />

Of all the new battery systems, nickel - metal<br />

hydride is regarded worldwide as the most technically<br />

advanced. Therefore a large proportion of<br />

new-generation electric vehicles introduced<br />

into the market have already been equipped<br />

with batteries of this type (e.g. Toyota RAV4, General<br />

Motors EV1). But the market volume of<br />

this battery types is still very small. In addition<br />

to the actual NiMH high-energy cells which have<br />

been developed to high specific energy levels<br />

of approx. 80 Wh/kg, two product lines are of<br />

interest for hybrid electric vehicles and the vehicle<br />

electrical power supply systems of the future.<br />

These product lines have been developed<br />

specially for high power requirements (Fig. 7).<br />

Power (P) Cells<br />

A typical application scenario for NiMH power<br />

cells would be the propulsion battery for conventional<br />

hybrid electric vehicles, with a specific<br />

range when used in purely electrical mode<br />

(e.g. hybrid electric buses). High performance,<br />

rapid-charging capabilities and a long service<br />

life are all important for such applications. Due<br />

to the relatively high capacity values (> 40 Ah)<br />

resulting from the energy requirements, the<br />

cells are produced in prismatic form. Even at<br />

large capacities, this construction enables a relatively<br />

large cell surface, which is required for<br />

dissipating the waste heat generated during<br />

battery operation.<br />

6<br />

Fig. 7:<br />

NiMH-Product lines for high power requirements<br />

Power(P)-Cells High-Power(HP)-Cells<br />

60, 40 Ah 5, 8, 12 Ah<br />

prismatic cylindric<br />

< 60 Wh/kg < 45 Wh/kg<br />

< 300 W/kg < 1300 W/kg (90% SOC)<br />

The high requirements in terms of electrical<br />

power are met at the expense of the specific<br />

energy and energy density, which up to 60<br />

Wh/kg and 150 Wh/l lie far below the level of<br />

high-energy cells. However, the performance<br />

during discharging and charging is significantly<br />

better. Even when discharging with a 10minute<br />

current (6 C rate), 85% of the stored<br />

energy can be converted to useful energy. The<br />

maximum specific power lies in the region of


Fig. 9:<br />

NiMH-40V-battery for<br />

new vehicle electrical<br />

power supply<br />

around 300 W/kg. Generally speaking, highpower<br />

cells can be completely recharged within<br />

around 60 minutes. Partial charging up to<br />

around 80% is even possible within 10 minutes.<br />

Rapid charging is limited by the temperature<br />

rise within the cells, caused by the exothermic<br />

formation of hydrides, and losses generated by<br />

electrical resistance, as well as gas evolution at<br />

the positive electrode in high states of charge.<br />

High-Power (HP) Cells<br />

High-power cells are the most important development<br />

of the NiMH system. They have<br />

been designed mainly for “Power-Assist” applications<br />

in state-of-the-art hybrid electric vehicles,<br />

where the improvement of energy efficiency<br />

and the reduction of exhaust gas emissions<br />

are at the forefront of the development<br />

work. Their use in new 42V vehicle electrical<br />

power supply systems is also very promising.<br />

The NiMH system has been optimized specifically<br />

for these applications to provide significantly<br />

greater performance. HP cells are currently<br />

available with capacities ranging from<br />

5 Ah to 12 Ah. Because of their relatively low<br />

capacities, these cells are produced in cylindrical<br />

form. Positive and negative electrodes, separated<br />

by a polymer fiber sheet, are spirally<br />

wound. This process is inexpensive, and is currently<br />

used to manufacture billions of portable<br />

batteries.<br />

HP cells can be continuously discharged at discharge<br />

rates of up to approx. 40 C (1.5-minute<br />

discharge) (Fig. 10). The full capacity is available<br />

at a high voltage in excess of 0.9 V (approx.<br />

80% of the open circuit voltage). The maximum<br />

specific power output of HP cells can be up to<br />

1,300 W/kg (Fig. 11). These cells can also be<br />

charged from completely discharged state at<br />

very high currents. At a charge rate of approx.<br />

20 C, HP cells can be charged to approx. 80%<br />

7<br />

Fig. 10: NiMH-HP 5 Ah<br />

Discharge characteristics<br />

Voltage (V)<br />

1.6<br />

1.4<br />

1.2<br />

1.0<br />

0.8<br />

0.6<br />

0.4<br />

0 1 2 3 4 5 6<br />

Capacity (Ah)<br />

Fig. 11: Energy power diagramm for different<br />

NiMH cell design<br />

Specific energy (Wh/kg)<br />

75<br />

50<br />

25<br />

5.5 A<br />

27.5 A<br />

55 A<br />

82.5 A<br />

110 A<br />

165 A<br />

220 A<br />

0<br />

0 250 500 750 1,000 1,250 1,500<br />

Specific power (W/kg)<br />

Power<br />

High power


High-Performance Batteries for<br />

New Automotive Applications<br />

Fig. 12: Influence of DOD (depth of discharge)<br />

on cycling endurance of NiMH cells<br />

Capacity throughput<br />

(Nominal capacity)<br />

14,000<br />

12,000<br />

10,000<br />

1)<br />

2)<br />

8,000<br />

6,000<br />

4,000<br />

2,000<br />

0<br />

2,400<br />

cycles<br />

100%<br />

1C/1C<br />

5,000<br />

cycles<br />

80%<br />

10C/10C<br />

Depth of Discharge (DOD)<br />

Charge/discharge rate<br />

approx. 80,000<br />

cycles<br />

12%<br />

18C/27C<br />

> 300,000<br />

cycles<br />

5% 1)<br />

2)<br />

5C+2C/27C<br />

SOC in less than 3 minutes. This corresponds<br />

to a specific power absorption of approx. 1,200<br />

W/kg.<br />

A “Power-Assist” battery comprising 200 HP<br />

round cells of 12 Ah nominal capacity is displayed<br />

in Fig. 1. With a relatively low energy<br />

content of 2.8 kWh, the maximum discharge<br />

power at normal ambient temperatures is more<br />

than 55 kW.<br />

Fig. 9 shows the prototype of a NiMH battery<br />

as may be used for a future 42V vehicle electrical<br />

power supply system. The battery comprises<br />

32 series-arranged individual cells, each<br />

delivering a capacity of 12 Ah. With a system<br />

weight of approx. 14 kg and an energy content<br />

of approx. 500 Wh, the maximum electrical discharge<br />

power at 20 °C is approx. 11 kW.<br />

The service life – calculated in terms of either<br />

calendar life or cycle life – is crucial for the costeffectiveness<br />

of a battery system, particularly in<br />

vehicle applications. The achievable capacity<br />

throughput is mainly determined by the charging<br />

and discharging conditions. Fig. 12 displays<br />

the dominant influence of the depth of discharge<br />

(DOD) on the attainable capacity throughputs<br />

for NiMH systems tested under various<br />

8<br />

cycling conditions. Under a cycling regime with<br />

one hour charging and one hour discharging at<br />

100% DOD, the typical service life is 2,400 cycles<br />

(reduction in capacity to 80% of the starting<br />

value). If however the cells are run in a limited<br />

SOC-window of 10% to 90%, the capacity<br />

throughputs double. Operating the batteries<br />

in a considerably smaller SOC-window (5%)<br />

enables an extreme cycle life to be achieved<br />

which corresponds to more than 14,000 times<br />

the nominal capacity throughput. Internal resistance<br />

and performance data remain virtually unchanged<br />

in this cycling operation. This means<br />

a consistent level of energy efficiency over the<br />

battery´s entire lifetime.<br />

Lithium-Ion Batteries (Li-Ion)<br />

The tremendous weight advantage over other<br />

battery systems makes the Li-Ion system a highly<br />

attractive candidate for future energy storage<br />

systems in vehicles with a particularly high demand<br />

for electric energy. While NiMH highenergy<br />

cells deliver specific energies of up to<br />

80 Wh/kg, Li-Ion high-energy cells can deliver<br />

approx. 130 Wh/kg, some 50% higher. The volumetric<br />

energy density, at 270 Wh/l, lies approximately<br />

20% above the density of equivalent<br />

NiMH high-energy cells.<br />

Current Li-Ion portable battery systems make<br />

almost exclusive use of cobalt oxide for the<br />

cathode material. However, this material cannot<br />

be used in vehicle batteries due to its poor<br />

availability and high costs. Battery manufacturers<br />

are endeavoring to use cheaper materials<br />

instead. In this regard, Varta has concentrated<br />

on the lithium-manganese spinel.<br />

Despite the tremendous technological advances,<br />

the wide-scale use of Li-Ion batteries in<br />

electric vehicles cannot yet be foreseen. This is<br />

due firstly to the old problem of inadequate<br />

energy density, as is also the case with other<br />

battery systems. The other reason is that, even<br />

when inexpensive materials are used, the price<br />

for a battery with an energy storage capacity of<br />

approx. 30 kWh is still prohibitively high. On the<br />

other hand, smaller and higher-powered battery<br />

systems are of great interest for 42V vehicle<br />

electrical power supply systems and hybrid<br />

electric vehicle applications. Similar to the NiMH<br />

cell situation, there are two product lines that<br />

are considered to offer the best opportunities<br />

for the markets of the future (Fig. 13).


Fig. 13: Li-Ion-High-<br />

Energy Cells with<br />

40 or 60 Ah (prismatic)<br />

and Li-Ion High<br />

Power Cell with 6 Ah<br />

High-Energy (HE) Cells<br />

The main stimulus for the development of Li-Ion<br />

high-energy cells is a dramatic improvement in<br />

the storage of energy (in terms of weight and<br />

volume) for supplying the vehicle electrical<br />

power supply system. Vehicles equipped with<br />

comfort features such as continuous air conditioning,<br />

infotainment, will require electrical<br />

energy storing devices of up to approx.<br />

2 kWh. Because of their high specific energy,<br />

Li-Ion batteries offer clear weight advantages<br />

over today´s lead and NiMH high-energy batteries.<br />

Were it to deliver the required storage<br />

capacity of e.g. 2 kWh or so, the weight of a<br />

lead battery would have to be around 50 kg,<br />

while a high-energy NiMH battery would be approx.<br />

30 kg. An equivalent Li-Ion battery would<br />

weigh around 20 kg, not much more than a<br />

modern lead starter battery. Fig. 16 shows a<br />

Li-Ion high-energy battery (2.4 kWh) (operating<br />

voltage: 40V) comprising 10 prismatic 60 Ah<br />

cells.<br />

High-Power (HP) Cells<br />

While the high-power NiMH system has already<br />

moved through the prototype stage and is<br />

moving towards series production, a similar<br />

development in terms of technology for Li-Ion<br />

systems is still some way in the future. Nevertheless,<br />

the results achieved to date have demonstrated<br />

the enormous potential of this system<br />

for the high-power sector.<br />

9<br />

Similar to the developments with NiMH, efforts<br />

are being concentrated on relatively small cell<br />

capacities in the range of 5 Ah to a maximum<br />

of 10 Ah. The increase in power capability is<br />

caused mainly by the use of thinner electrodes<br />

and materials that are more able to carry high<br />

currents. One fundamental problem is the conductivity<br />

of the organic electrolyte, which is<br />

around two orders of magnitude below that<br />

of aqueous media. Similar to the high-performance<br />

NiMH cells, the Li-Ion cells are manufactured<br />

using a winding technology, for technical<br />

and cost reasons.<br />

Fig. 14 shows the voltage behavior of a Li-Ion<br />

cell with a capacity of 6 Ah when it is discharged<br />

with currents ranging from 6 A to<br />

100 A. Even with a discharge current of 100 A<br />

(approx. 16 C rate), voltages amounting to more<br />

than 70% of the nominal voltage are observed.<br />

The differences between the energy storage<br />

and power behavior compared to an Li-Ion highenergy<br />

battery can be seen in Fig. 15. While the<br />

specific energy of an Li-Ion high-power cell of<br />

55 Wh/kg is around half that of a high-energy<br />

cell, its specific power is almost four times<br />

higher at approx. 900 W/kg.<br />

(cylindric) Fig. 14: Discharge characteristics of a<br />

6 Ah Li-Ion High Power cell<br />

Voltage (V)<br />

4.2<br />

4.0<br />

3.8<br />

3.6<br />

3.4<br />

3.2<br />

3.0<br />

2.8<br />

2.6<br />

2.4<br />

0 1 2 3 4 5 6 7<br />

Capacity (Ah)<br />

2A<br />

20A<br />

35A<br />

70A<br />

100A


High-Performance Batteries for<br />

New Automotive Applications<br />

Fig. 15: Energy/power diagram (Ragone Plot)<br />

for different Li-Ion cells<br />

Specific Energy (Wh/kg)<br />

125<br />

100<br />

75<br />

50<br />

25<br />

0<br />

0 250 500 750 1,000<br />

Specific power (W/kg)<br />

High energy cell<br />

High power cell<br />

Fig. 18:<br />

Electrode belt manufacturing<br />

for NiMH cells<br />

The limited service life of Li-Ion batteries is still<br />

their major weakness. It is currently determined<br />

primarily by the drop in capacity over the<br />

battery´s life. Depending on the size and type of<br />

5 Summary and Outlook<br />

The strengths of the existing lead-acid system<br />

include high availability, low costs, an existing<br />

recycling infrastructure and low self-discharge.<br />

The system´s tolerance to limited overcharging<br />

and deep discharging means only limited battery<br />

management is required for existing applications.<br />

The higher demands of future electri-<br />

10<br />

the cell, services lives of 2 to 4 years are standard<br />

under normal ambient temperatures. This<br />

is entirely adequate for most portable battery<br />

applications, although in vehicle applications a<br />

minimum service life of 5 years is required. The<br />

advances that have been made in the stability<br />

of the materials used have given rise to optimism<br />

that this problem will be solved in the<br />

foreseeable future.<br />

cal power supply systems in vehicles, however,<br />

make some battery management essential –<br />

even for lead-acid batteries.<br />

The results achieved with nickel - metal hydride<br />

technology not only support their use in the hybrid<br />

electric vehicles of tomorrow, but also open<br />

up additional areas of application for new 42V<br />

vehicle electrical power supply systems. With<br />

specific power of approx. 1,000 W/kg, these<br />

systems are in direct competition with capacitor<br />

systems. At comparable performance values,<br />

they offer an approximately 20 times higher<br />

energy storage capacity. Particular strengths include<br />

a high specific power and a high power<br />

density, high capacity and energy throughput<br />

and a long service life.<br />

As far as applications in the vehicle sector are<br />

concerned, lithium-ion technology still has some<br />

way to go before it catches up with nickel -<br />

metal hydride technology. The results achieved<br />

so far, however, show that there is considerable<br />

scope for technical enhancements. Specific<br />

powers of up to 1500 W/kg at a specific energy<br />

level of up to 80 Wh/kg would seem to be possible.<br />

The main problem currently is the calendar<br />

service life, especially under temperature<br />

conditions that can be expected in automotive<br />

applications.<br />

Fig. 17: Li-Ion<br />

High-Energy Module<br />

(40V/60Ah)


Fig. 19:<br />

Production of VRLA-<br />

AGM batteries<br />

6 Varta – The Battery Experts<br />

VB Autobatterie GmbH is a joint-venture company<br />

shared between <strong>VARTA</strong> AG and Robert-<br />

Bosch GmbH, and has production sites in Germany,<br />

Spain, France, Austria and the Czech<br />

Republic, making it one of the largest manufacturers<br />

of automotive batteries in Europe. Alongside<br />

the ongoing further development of the<br />

existing 12V (14V) lead-acid battery, VB is also<br />

working on the development of the lead-acid<br />

battery systems of tomorrow. This work mainly<br />

involves AGM technology (AGM = Absorptive<br />

Glass Mat) both for 12V (14V) and 36V (42V)<br />

systems.<br />

Batteries for new electrical power systems represent<br />

a particular area of development focus.<br />

These include various applications, such as the<br />

upcoming 42V vehicle electrical system, multivoltage<br />

vehicle electrical systems (14V/42V),<br />

and separate systems for energy and power<br />

storage. The spurs for these activities are the<br />

rapidly-growing technical demands on electrical<br />

performance in vehicles.<br />

Varta Automotive’s NBT Technology Center focuses<br />

on the development of new battery technologies.<br />

These mainly include the nickel - metal<br />

hydride and lithium-ion systems, which over<br />

the last decade have become well established<br />

in the portable battery industry and have superseded<br />

other technologies (nickel-cadmium,<br />

lead-acid) to a large extent in that field. Possible<br />

areas of application for these technologies in<br />

vehicles include 42V batteries for particularly<br />

powerful vehicle electrical systems and supply<br />

batteries for state-of-the-art, energy-saving and<br />

11<br />

ecofriendly hybrid vehicles. The features of<br />

these new applications are high electrical performance<br />

and the ability to deliver very highenergy<br />

throughput over the vehicle’s service life.<br />

The growing requirements of vehicle manufacturers<br />

on battery system technology are being<br />

met head-on through development activities focusing<br />

on intelligent batteries. The aim is to develop<br />

energy storage systems that use modern<br />

electronics, for example, to determine their current<br />

status in relation to readiness for operation,<br />

state of charge, state of health, their remaining<br />

service life and so on, to process this information<br />

and to then forward it to the vehicle’s<br />

electronic systems. VB Autobatterie and NBT<br />

are both working closely with leading vehicle<br />

manufacturers in these areas of research and<br />

development.<br />

Fig: 18:<br />

Development of<br />

Li-Ion cells<br />

Fig. 20:<br />

Electrode manufacturing<br />

for NiMH cells


High-Performance Batteries for<br />

New Automotive Applications<br />

7 References<br />

1. J. Kassakian Challenges of the New 42<br />

Volt Architecture and Progress on its International<br />

Acceptance; VDI Berichte No.<br />

1415, p.21, VDI Verlag, Düsseldorf 1998<br />

2. MIT Industry Consortium on Advanced<br />

Automotive Electrical / Electronic Components<br />

and Systems; c/o Massachusetts<br />

Inst. of Technology, Laboratory for Electromagnetic<br />

and Electronic Systems, 77<br />

Massachusetts Ave., Cambridge, MA<br />

02139<br />

3. W. Buschhaus, A. K. Jaura, M. A.Tamor,<br />

VDI <strong>Report</strong>s No. 1459, 1999<br />

4. J. R. Pierson, J. P. Zagrodnik, R. T. Johnson,<br />

Power Sources 67 (1997) 7<br />

5. D. Berndt, Maintenance Free Batteries,<br />

John Wiley & Sons, New York, 1997<br />

6. D. S. Ginley , Materials for Electrochemical<br />

Energy Storage and Conversion 2-Batteries,<br />

Capacitors and Fuel Cells; Material<br />

Research Society, Warrendale, 1998<br />

Publisher: <strong>VARTA</strong> Aktiengesellschaft<br />

Corporate Communications<br />

Am Leineufer 51<br />

D-30419 Hannover<br />

12<br />

7. M. Wakihara, O. Yasmamoto, Lithium Ion<br />

Batteries, Wiley-VCH Verlag; Weinheim,<br />

1998<br />

8. B. E. Conway, Electrochemical Supercapacitors,<br />

Kluwer Academic / Plenum<br />

Publishers, New York, 1999<br />

9. F. Burke, M. Miller, J. T. Guerin, Proceedings<br />

of Sixth International Seminar on<br />

Double-layer Capacitors and Similar Energy<br />

Storage Devices, 1996<br />

10. K. Brandt, Solid State Ionics 69 (1994) 173<br />

11. P. Bäuerlein, J. Kuempers, E. Meissner,<br />

J. Power Sources, 81-82 (1999) 585<br />

Phone +49 5 11 79 03-8 21<br />

Fax +49 5 11 79 03-7 17<br />

E-mail: uwe.koehler@nbt.auto.varta.com<br />

http://www.varta.com

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