Metal-metal bond

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Elementary steps in organometallic chemistry Ligand dissociation / coordination Me Me3Al 3Al + NMe 3 6e 8e Mo(CO) 6 18e 16e Me Me3Al-NMe 3Al-NMe 3 Mo(CO) 5 + CO
Β‐Elimination Elementary steps in organometallic chemistry ‐Alkyl group with a β‐hydrogen ‐Coordination vacant on the metal or an easy to dissociate ligand in cis‐ position ‐An empty orbital at the metal ‐Feasible approach of the β‐ hd hydrogen to themetal h l ‐A full orbital at the metal
Page 1 and 2: Metal‐metal bond
Page 3 and 4: L L L L M L M M L L L σ∗ σ Meta
Page 5 and 6: ‐2 L L L L M M L L L L σ∗ π
Page 7 and 8: Metal‐metal quintuple bond
Page 9 and 10: Isolobal analogy ‐Simplification
Page 11 and 12: Isolobal analogy
Page 21: Isolobal analogy
Page 37 and 38: Β‐Elimination Elementary steps i
Page 39 and 40: Β‐Elimination P P Elementary ste
Page 41 and 42: Elementary steps in organometallic
Page 43 and 44: Elementary steps in organometallic
Page 45 and 46: Olefin reduction

Metal-metal bond

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