Metal-metal bond
Metal-metal bond
Metal-metal bond
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p z<br />
L L<br />
M M<br />
L L<br />
<strong>Metal</strong>‐<strong>metal</strong> <strong>bond</strong> d 8 case<br />
L L ‐2<br />
CNR<br />
L L<br />
σ∗<br />
σ<br />
σ∗<br />
p z<br />
d z 2 d z 2<br />
σ<br />
RNC Ir CNR<br />
RN<br />
C<br />
R R3P 3P Cl<br />
Ir<br />
NC<br />
C<br />
R<br />
NR CNR<br />
RNC Ir CNR<br />
RN<br />
C<br />
‐2<br />
‐2<br />
‐2<br />
‐2
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