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Effect of hygrothermal treatment on the tensile properties - ethesis ...

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wood), and geotextiles. The jute composites may be used in everyday applicati<strong>on</strong>s<br />

such as lampshades, suitcases, paperweights, helmets, shower and bath units. They are<br />

also used for covers <str<strong>on</strong>g>of</str<strong>on</strong>g> electrical appliances, pipes, post-boxes, ro<str<strong>on</strong>g>of</str<strong>on</strong>g> tiles, grain<br />

storage silos, panels for partiti<strong>on</strong> & false ceilings, bio-gas c<strong>on</strong>tainers, and in <strong>the</strong><br />

c<strong>on</strong>structi<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> low cost,<br />

mobile or pre-fabricated buildings which can be used in times <str<strong>on</strong>g>of</str<strong>on</strong>g> natural calamities<br />

such as floods, cycl<strong>on</strong>es, earthquakes, etc.<br />

2.2.4. Limitati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> jute fibre composites<br />

Unfortunately, all mechanical and o<strong>the</strong>r physical <strong>properties</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> natural fibres are<br />

influenced by <strong>the</strong>ir growing c<strong>on</strong>diti<strong>on</strong>s, fibre processing technique and, as for o<strong>the</strong>r<br />

fibre types, by <strong>the</strong> fineness <str<strong>on</strong>g>of</str<strong>on</strong>g> <strong>the</strong> fibre and sample test-length. Although, as with most<br />

<str<strong>on</strong>g>of</str<strong>on</strong>g> <strong>the</strong> o<strong>the</strong>r plant-based natural fibres, cellulose forms <strong>the</strong> main structural comp<strong>on</strong>ent<br />

<str<strong>on</strong>g>of</str<strong>on</strong>g> jute, <strong>the</strong> n<strong>on</strong>-cellulosic comp<strong>on</strong>ents e.g., lignin and hemicellulose, also play an<br />

important part in determining <strong>the</strong> characteristic <strong>properties</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> <strong>the</strong> fibres.<br />

There is, however, a major drawback associated with <strong>the</strong> applicati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> jute fibres for<br />

reinforcement <str<strong>on</strong>g>of</str<strong>on</strong>g> resin matrices. Due to presence <str<strong>on</strong>g>of</str<strong>on</strong>g> hydroxy and o<strong>the</strong>r polar groups in<br />

various c<strong>on</strong>stituents <str<strong>on</strong>g>of</str<strong>on</strong>g> jute fibre, <strong>the</strong> moisture uptake is high (approx. 12.5% at 65%<br />

relative humidity & 20 o C) by dry fibre and 14.6% by wet fibre. All this leads to (i)<br />

poor wettability with resin and (ii) weak interfacial b<strong>on</strong>ding between jute fibre and <strong>the</strong><br />

relatively more hydrophobic matrices. Envir<strong>on</strong>mental performance <str<strong>on</strong>g>of</str<strong>on</strong>g> such<br />

composites is generally poor due to delaminati<strong>on</strong> under humid c<strong>on</strong>diti<strong>on</strong>s. With<br />

increase in relative humidity upto 70%, <strong>the</strong> tenacity and Young’s modulus <str<strong>on</strong>g>of</str<strong>on</strong>g> jute<br />

increases but bey<strong>on</strong>d 70%, a decrease is observed.<br />

2.5. Polyester<br />

Cure at room or elevated temperature. It has good chemical resistance.<br />

Limitati<strong>on</strong>s:- emissi<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> styrene, shrinkage <strong>on</strong> curing (7-10%)<br />

The term polyester covers a very large chemical family <str<strong>on</strong>g>of</str<strong>on</strong>g> which “unsaturated resins”<br />

covering orthophthalic, isophthalic, vinyl esters and blends form <strong>the</strong> largest single<br />

group <str<strong>on</strong>g>of</str<strong>on</strong>g> fibre reinforced <strong>the</strong>rmosets. They are usually manufactured by reacting<br />

toge<strong>the</strong>r dihydric alcohols (glycols) and dibasic organic acid, ei<strong>the</strong>r or both <str<strong>on</strong>g>of</str<strong>on</strong>g> which<br />

c<strong>on</strong>tain a double-b<strong>on</strong>ded pair <str<strong>on</strong>g>of</str<strong>on</strong>g> C atoms. By eliminati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> water between <strong>the</strong> acids<br />

and glycols, ester linkages are formed, producing a l<strong>on</strong>g chain molecule comprising<br />

14

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