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Hazardous Waste Disposal with Thermal Oxidation - John Zink ...

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WASTE EXAMPLE PRODUCTS OF OXIDATION<br />

GAS / SOLID<br />

SOLID<br />

CO + H2/C + ASH<br />

COAL FINES<br />

FG, NOXA, PARTICULATE<br />

FG, NOXA, PARTICULATE<br />

STEAM<br />

HOPPER<br />

ESP<br />

AIR<br />

350° F<br />

FUEL<br />

CYCLONIC T.O.<br />

Configuration 7.2 : <strong>Waste</strong> Process<br />

<strong>Waste</strong>s Containing Combustible Solids<br />

Figure 8 is a diagram of a process to dispose of a waste that contains combustible solids in the<br />

particle size range of 10 to 500 microns that produces a flue gas containing excessive amounts of<br />

NOx. It consists of the following major components:<br />

• A cyclonic reduction furnace in which a high radial velocity, high temperature, reducing (less<br />

than stoichiometric air) environment converts the bound nitrogen to N 2 and the fuel to water gas.<br />

• A quench section which cools the water gas to approximately 1400° F.<br />

• A heat recovery boiler which produces steam in cooling the flue gas to 350° F.<br />

• An unlined vent stack.<br />

DRY ASH CONDITIONING<br />

TOWER<br />

HOT CYCLONE<br />

Recycle flue gas cooling is an integral part of the process to minimize NOx formation and<br />

maximize heat recovery.<br />

19<br />

BOILER<br />

Recycled Gas<br />

350° F<br />

DRY ASH<br />

DRY ASH<br />

BAG HOUSE<br />

WASTE EXAMPLE PRODUCTS OF OXIDATION<br />

GAS / SOLID<br />

SOLID<br />

HOPPER<br />

FUEL<br />

AIR<br />

Water Gas<br />

CO 2<br />

H 2<br />

CO<br />

H 2O<br />

N 2<br />

CYCLONIC REDUCTION<br />

FURNACE<br />

Figure 8 : <strong>Waste</strong> Process<br />

MELAMINE SLURRY<br />

DNT CELLULOSE<br />

QUENCH<br />

RECYCLED GAS<br />

AIR<br />

FG, NOx<br />

FG, NOx<br />

T.O<br />

OR<br />

STEAM<br />

BOILER<br />

FLUE GAS<br />

STACK<br />

FLUE GAS<br />

STACK

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