a3)595*! ! !

stu-s Sromebi – TRANSACTIONS OF GTU – ТРУДЫ ГТУ № 2 (484), 2012
gaTvlilia: C12H7N3O: C, 68.89%; H, 3.37%; N,
20.09%; S, 7,65%. napovnia: C, 70.10%; H 3.07%; N
19.40%; S 7.18%.
3H-benzo[b]furo[2,3-f] benzotriazoli (5) –
gamosavlianoba 72–80%;
iw speqtri , υ: 3375 (NH) სმ –1 .
1H-bmr speqtri (DMSO) (/ppm): 7,134 (1H, m, H-
8); 7,35 (1H, m, H-7); 7,648 (1H, m, H-6); 8,04 (1H, m,
H-9); 8,066 (1H, m, J10,4=0,63, H-10); 8,195 (1H, m,
J4,5=0,63, H-4); 9,752 (1H, s, H-3, NH);
gaTvlilia: C12H7N3O: C 68.89%; H 3.37%;
N 20.09%; S, 7,65%. napovnia: C 69.55%; H 3.12%;
N 19.57%; S 7.20%.
1H-benzo[b]furo [3,2-g] benzotriazoli (6)
gamosavlianoba 75–82%;
iw speqtri, υ: 3345 (NH) სმ –1 .
1H-bmr speqtri (DMSO) (/ppm): 7,314 (1H, m, H-
7); 7,434 (1H, m, H-8); 7,734 (1H, m, J5,4=8,87, H-5);
7,68 (1H, m, H-9); 7,929 (1H, m, J4,5=8,87, H-4); 8,04
(1H, m, H-6); 9,792 (1H, s, H-1, NH);
gaTvlilia: C12H7N3O: C 68.89%; H 3.37%;
N 20.09%; S, 7,65%. napovnia: C 69.83%; H 3.05%;
N 19.10%; S 7.43%.
3. daskvna
heterociklebi furanisa da triazolis
biologiuri aqtiurobidan gamomdinare, Cven
mier am heterociklebis erT molekulaSi gaerTianebiT
Seiqmna axali heterocikluri
kondensirebuli tetracikluri sistemebi, dibenzofuranze
trabolis yvela SesaZlo anelirebiT.
miRebuli sistemebi Seswavlilia 1Hbmr
da infrawiTeli speqtroskopiis meSveobiT.
damuSavebulia maTi miRebis preparatuli
meTodebi.
literatura
1. http://en.wikipedia.org/wiki/Fuel_cell
2. Manale Maalouf, Hossein Ghassemi, Thomas A.
Zawodzinski. Triazole-based Electrolytes for Fuel Cell
Applications Material Properties and Proton Transfer
Capabilities. Choong-Gon Lee Case Western Reserve
University, Dept. of Chemical Engineering. 10900
Euclid Ave., Cleveland, OH 44106
3. Т. Eicher, S. Hauptmann. The Chemistry of Heterocycles,
Structure, Reactions, Syntheses and
Applications. Georg Thiem Verlag Stuttgart, New
York. 1995. P. 505.
4. Fan, W.-Q.; Katritzky, A.R. 1,2,3-TriazoIes in
Comprehesive Heterocyclic Chemistry II. Katritzky,
A.R., Rees, C.W., Scriven, E.F.V., Eds. Elsevier
Science: Oxford. 1996. Vol. 4. P. 1-126.
5. Robert C. Elderfield. Heterocyclic Compounds.
Volume 7. New York. 1961. P-322.
6. Patent of USA 4,233,059.1,2,3-Triazole Carboxylic
Acid Amides and Biocidal Compositions Containing
the Same. Krüger, H.-R. et. al. U.S. (CI. C07D249/04).
1980. Published 1.11.1980.
7. Ram Janam Singh*. 1, 2, 3-TRIAZOLE DERIVATI-
VES AS POSSIBLE ANTI–INFLAMMATORY
AGENTS, Quality Control Laboratory, Indian Oil
Corporation Limited, Panipat Refinery Panipat,
Haryana-132140 (India) , 1Synthetic Research
Laboratory, Department of Chemistry, Faculty of
Science, Tilak Dhari Post; Graduate College, Veer
Bahadur Singh Purvanchal University, Jaunpur, U.P.-
222002 (India);E-mail: singhram@iocl.co.in
8. 1,2,3-Triazole as a Peptide Surrogate in the Rapid
Synthesis of HIV-1 Protease Inhibitors Ashraf Brik,[a]
Jerry Alexandratos,[b] Ying-Chuan Lin,[c] JohnH.
Elder,[c] Arthur J. Olson,[c] Alexander Wlodawer,*[b]
DavidS. Goodsell,*[c] and Chi HueyWong*[a]
9. A. Pozharsky, V. Anisimova, V. Tsupak. "Practical
Works in The Chemistry of Heterocycles" Rostov
1988.
UDC 66.098
TRIAZOLE AND FURAN CONTAINING NEW HETEROCYCLIC CONDENSED SYSTEMS
M.Maisuradze, G Phalavandishvili, G.Ugulava
Department of chemical and biological technologies, Georgian Technical University, 77, Kostava str, Tbilisi, 0175,
Georgia
Resume: By the actions to orto ‐diamines of dibenzofuran of nitrous acid and hydrochloric acid as a result are ob‐
tained new tetracyclic condensed heterocyclic systems ‐ 3H‐benzo[b]furo[3,2‐e]benzotriazole, 3H‐benzo[b]furo[2,3‐
f]benzotriazole and 1H‐benzo[b]furo[3,2‐g]benzotriazole with the anticipated biological activity. There are studied
their spectral characteristics.
Key words: benzofuran; triazole; benzotriazole.
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