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X-Encontro-Nacional-de-Fisica-da-Materia-Condensada

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11:15/SA .F ESTUDO DE KICELAS EN SOLO& NO SISIDIA 00DECIL(LAURIL1 SULFATO DE SONO (SLS)<br />

EN ACOA FOR ESPALKAKOM) DE RAIOS-X EliSAIXO GULO (SAIS): Rosangela ltri e Lie Queiros<br />

Amaral (Iostituto <strong>de</strong> <strong>Fisica</strong> Ms USP)<br />

Estu<strong>da</strong>mos amo bin: r i aa isotrapicas ow viries concentregies <strong>de</strong>eds 4,921 <strong>de</strong> SLS a<br />

26,251 <strong>de</strong> SLS. As curves <strong>de</strong> espalhamento ate concentragio <strong>de</strong> 151 <strong>de</strong> SLS ap aaaaa Cam um ;nice pica<br />

mmmmm garrotte° <strong>da</strong> fungio <strong>de</strong> inter( is interne <strong>da</strong> micela. Efeitos <strong>de</strong> interferincia antra part;<br />

colas at ease con rrrrr nip "feul a curve <strong>de</strong> SAES <strong>de</strong> use mimics Rerceptrvel. Da mills. <strong>da</strong><br />

Fong, astudo do Eaton <strong>de</strong> estrutura <strong>da</strong> funsio <strong>de</strong> distribuicio <strong>de</strong> distencia p(r), conclmimos<br />

qua nti a concentraqio <strong>de</strong> 102 <strong>de</strong> SLS as mIcelam min emfirices cam raio total <strong>de</strong> or<strong>de</strong>m <strong>de</strong> 25,511.<br />

Para Roomed cam conceatracoe ■ majors. que 152 <strong>de</strong> SLS, observamos o apareciemoto <strong>de</strong> um<br />

segundo rico que me torn" nether <strong>de</strong>finido quanta maior e concentracio <strong>de</strong> enfifilico, essociado<br />

Interfarencie entre similes. Da.anilise <strong>da</strong> omelets° dos picas cam s concentraqao concIulmos qua<br />

nee 'mists indicaqao <strong>de</strong> alterageo <strong>de</strong> forma <strong>da</strong> micela ea a cccccc trivia <strong>de</strong> 26 1252 <strong>de</strong> SLS, man ape<br />

nas a surgimento <strong>de</strong> interlaces entre Riegle' e um pa 1 imams= do agregaquo extra e1am. A poi<br />

sibili<strong>da</strong><strong>de</strong> is transigio <strong>de</strong> forma esfera-cilindro ser mediaa pole formaqie <strong>de</strong> diner*s <strong>de</strong> micelii<br />

parses Instants viivel.<br />

011/11:35/5A.F I SAKS STUDIES OF CROTAKINE SOLUTIONS AT 01 ■4.5. J.R. Oeltreq, Y.P. Itasca -<br />

renham, A.F. Cr51evic2.(lostituto <strong>de</strong> P' ' Quimica <strong>de</strong> Kio Curios, C.P. 369, 13.360, Sio Car-<br />

los', SP, Brasil and C.J.Lurg, Vac. <strong>de</strong> Ned. <strong>de</strong> Rib ' Preto, Si° Paulo, brazil).<br />

Crotamine. a neuratoxia isolated from the brzilian raelemnake Crotelus durimses<br />

terrificum, is a polypepti<strong>de</strong> toxin strongly basic (pHi 10.3) with Al residue. of common emin2_<br />

acids including six heIfeystines. It has very high lysine (9 residual) and low evening (2<br />

;residues) . The W -terminal is tyrosine and C-terminus glycine. It has been sequenced by<br />

J.C. Laura (Hoppe-SeyIer's Physiol. Chem. 213-215 (1975) who also localized the four<br />

.cystine bridge. (Collected Abst., SIIPC, Annual Nest., 19801. In preview' work (liophys. J. Ai.<br />

ljan. 1985. 13-33) we <strong>de</strong>termined the apparent radii of gyration as f ' I pH. la this work<br />

I re ob ' d the SAES curves at pH 4.5 and the following molecular perimeters could be <strong>de</strong>rived<br />

radio" of oral= ■ 15.3(6) A, .ax. dim. ■ 40.0(2) A. volume ■ 20200 13 , surface 3200 12 .<br />

From this <strong>da</strong>ta we bad the indication that the molecular shops should be of a oblate a1ipsoid<br />

with a ■ b 22.8 A. c 8.4 I v a cis 0.37 . Using O. Glitter program the pair dimtribution<br />

function wee calculated ant the found was not that expected for a perfect oblate<br />

ellipsoid. A molecular mo<strong>de</strong>l was then proposed taking in consi<strong>de</strong>ration a rough Wimps as<br />

suggested by the secon<strong>da</strong>ry ■tructur ■ predicted by Chou and Ferman and hydrofobicity profile'<br />

methods. Work spo d by CNN. FAPESP and FINE?.<br />

CRI/11:55/54.FIEST0O0 E CARACTERIZAGA0 OE ESPIERALDAS OE SANTA 7EREZIIIHA DE GOIAS<br />

Carlito Lariucc (Oepartamento <strong>de</strong> <strong>Fisica</strong> - UFG) e Regina Helena <strong>de</strong> Almei<strong>da</strong> Santos (Instituto <strong>de</strong><br />

1.1sica a guimica <strong>de</strong> Sao Carlos - USP)<br />

A seguincia ao trabalho iniciado em 1985, sobre esmeral<strong>da</strong>s <strong>de</strong> Santa Terezinha <strong>de</strong> Golfs,<br />

levou a obtencao dos resultados aqui expostos.<br />

As medi<strong>da</strong>s do Tndice <strong>de</strong> refracio, usando o Mitodo <strong>de</strong> imersio resultaram em: n e n aeriando<br />

<strong>de</strong> 1.515 a 1.585 a 1.590 a 1,600, respectivamente.<br />

e o<br />

Os parimetros cristalogrificos<br />

0<br />

isao: a ■b■9.2837(7). c9.2092(4)R, 11=687.8(3)n 2.2 solicu<br />

las poe cela unitiria. d"..2,750(5)g/cm- , grupo especial P,/mcc. sisteam cristalino Hexagonal. A7<br />

resoluclo <strong>da</strong> estruture Idfdu localizacio <strong>de</strong> uma mplicula <strong>de</strong> igua na posicio (0. 0. 1/4) e um on<br />

(Ns, Ca, ...) na posicio (0, O. 0). As principals distincias interatomicas encontra<strong>da</strong>s foram:<br />

A1-0(2) ■ 1.947(1), Be-0(2) ■ 1,654(1), 5i-0(1) 1.618(I). Si-0(2) ■ 1,608(1) e (Na, ca. ...)-0.<br />

2.302(1) A.<br />

0 alominio tem coor<strong>de</strong>nacio octaidrice enguanto qua o berillo e silicio tetraidrIca.<br />

Com o objetivo <strong>de</strong> verificar qual Ton este coor<strong>de</strong>nado a igua. recorreu-se a anilise quTmi<br />

ca complete. a qual encontra-se em an<strong>da</strong>mento.<br />

Orgios Flnanciadores: CAPES, CNN, FIMEP, FAPESP.

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