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Bilag GBilag G: Væsentligste patenter for ISTD-anvendelse i DanmarkFILED AND/OR GRANTED INTERNATIONAL PATENT APPLICATIONS(i.e., OUTSIDE THE USA)Title: Remediation MethodInventors: Stegemeier, G.L., Rouffignac, E. P. de, Vinegar, H. J.Abstract: A method is provided to remove volatile contaminates from a contaminatedvolume of earth, the contaminated volume lying above a non-contaminated layer ofearth, the method including the steps of: penetrating the contaminated volume with atleast one wellbore so that a wellbore penetrates the contaminated volume and the noncontaminatedlayer; applying heat from the wellbore within the non-contaminated layer tothe non-contaminated layer until the temperature of a substantial portion of thenoncontaminated layer is about the boiling point of liquids within the non-contaminatedlayer; and applying heat from the wellbore within the contaminated volume to thecontaminated volume wherein the temperature of the contaminated volume rises toabout the boiling point of liquids in the contaminated layer after a substantial portion ofthe non-contaminated layer is about the boiling point of water within the noncontaminatedlayer at the pressure of the non-contaminated layer.Country Filed Appl. No. Published Publ. No. Granted Patent No. ExpiresAustralia 04-Jan-200082151/98 28-Sep-2000720947 03-Jun-2018Austria 21-Oct-199998932146.8 14-Aug-2002E222147 03-Jun-2018Belgium 21-Oct-199998932146.8 14-Aug-20021011882 03-Jun-2018Brazil 03- PI9809922-1Dec-1999Canada 04- 2289080Nov-1999China 02-Dec-199998805738.7 05-Jul-20001259062A 01-Aug-200398805738.7 03-Jun-2018CzechRepublicPV4320-9902-Dec-199907-Feb-2005Denmark 21-Oct-199998932146.8 14-Aug-2002Ireland 21-Oct- 98932146.8 14-Aug-19992002France 21-Oct- 98932146.8 14-Aug-19992002Great 21-Oct- 98932146.8 14-Aug-Britain 19992002Germany 21-Oct- 98932146.8 14-Aug-19992002Hungary 03- P0003002294883 03-Jun-20181011882 03-Jun-20181011882 03-Jun-20181011882 03-Jun-20181011882 03-Jun-2018P69807238.3- 03-Jun-082018244
Bilag GSouthKoreaDec-1999Indonesia 03-Dec-1999Italy 21-Oct-1999Japan 02-Dec-199902-Dec-1999Mexico 25-Nov-1999NetherlandsNewZealand1011882 03-Jun-2018500724 03-Jun-201821-Oct-199901-Nov-1999Poland 03-Dec-1999Russia 24-Dec-1999Singapore 03-Nov-1999SpainSweden1011882 03-Jun-201898932146.8 03-Jun-201821-Oct-199921-Oct-1999W1999152220-Jun-200298932146.8 14-Aug-2002501597/997011302/19999910909 12-Sep-200398932146.8 14-Aug-2002500724 10-Jan-2002P33720219990179 25-Jun-20019905274-8 19-Mar-2002PV1624-99Slovakia 29-Nov-199918-Jul-200398932146.8 14-Aug-200298932146.8 14-Aug-2002ID000818103-Jun-20181011882 03-Jun-2018216411 03-Jun-2018001706 03-Jun-201868767 03-Jun-2018283577 03-Jun-2018245
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Termisk assisteret oprensning afhø
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IndholdFORKORTELSESLISTE 7FORORD 9S
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5.1.2 Overordnet procesbeskrivelse
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ForordDenne rapport udgør slutrapp
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• Patentforholdene for anvendelse
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Summary and conclusionsOn behalf of
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ility of parathion, methyl-parathio
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• De aktuelle stoffers stabilitet
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2 Litteraturstudie2.1 Beskrivelse a
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Der er endvidere gennemført en ræ
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for både teoretiske og praktiske u
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2.2.3 Elektrisk opvarmningVed elekt
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opnå en jordtemperatur i oprensnin
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temperaturer mellem 260 og 427 °C,
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• Fri fase udskiller• En 45-50
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Tabel 2.2: Oprensningsmekanismer ve
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Kogepunktet for størstedelen af pr
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Tabel 2.5 Halveringstid for malathi
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PCE, men sådanne beskrivelser kan
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Endvidere kan der ske en opadrettet
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2.7.3 Cheminovas erfaringerI forbin
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aTherm har fra andre termiske proje
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af, at de oppumpede gasser var bran
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Som nævnt skal der som led i detai
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2.10.1 Injektion/cirkulation af var
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ekstraherede luft. Fordi depotet ho
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opbevaret i hver sin kraftige plast
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3.2.5 HydrolyseforsøgFire 1-liters
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Prøven blev lukket med tæt låg o
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De to batches uden NaOH-tilsætning
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Bemærk, at en LEL på 100 % betyde
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Tabel 3.8 Koncentrationen af Hg i s
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3.4.1 Oprensningsprocesser og effek
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Tabel 3.10 Opsummering af risiko fo
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I [NIRAS, 2005] er det endvidere es
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Tabel 4.4 Resultat af screenings-ma
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4.3.4 Opvarmning til 300 o C (ISTD
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5 Termiske afværgeforanstaltninger
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Figur 5.2 Konceptuelt tværsnit med
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5.1.3 Boringsdetaljer og placeringD
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Figur 5.7 Foreløbig boringsplaceri
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5.2 Masse- og energibalancerTabel 5
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• 3 måneder med trykcyklusser ti
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5.4 Forventede oprensningseffektivi
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5.5.4 Pneumatisk kontrol og lugtgen
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6 Anbefalinger til fase 2I dette af
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Figur 6.1 Skitse af pilotforsøg. E
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Figur 6.3 Skitse af injektions- og
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Tabel 6.4 Energibalance og estimat
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Tabel 6.6 Forslag til monitering og
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Den endelige pris på anlægget afh
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Tabel 7.1 Sammenligning af pilotfor
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112
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Recalcitrant Compounds—2004. Proc
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Jacobsen, C.S., S. Elmholt, C.B. Je
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on Remediation of Chlorinatetd and
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1 Fuldskalaoprensning med ISTDI det
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Figur 1.2. Konceptuelt tværsnit me
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Figur 1.4. Skitse af anlæg til beh
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Figur 1.5. Skitseret layout af ISTD
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ISTD varmeboringerne forventes plac
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Tabel 1.3 Vandbalance for fuldskala
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4. Installation af varmeboringer, e
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Klargøring af oprensningsområde o
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1.5.2 Behandling og afledning af sp
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2 Pilotforsøg med ISTDI dette afsn
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Anlægget til behandling af ekstrah
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1. Der etableres hydraulisk og pneu
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I tabel 2.4 er den beregnede energi
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Tabel 2.6. Forslag til monitering o
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I pilotprojektet forudsættes gæng
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Abbas, B. 1995, "Input of DDT into
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Andrus, V.E., Nanny, M.A. & Philp,
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Bang, S. 1997, "Molecular analysis
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PCT Reg. Des. States: Designated St
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Exposition, 74th, Atlanta, GA, Unit
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Cho, Y.G., Lee, S.T., Park, Y.H. &
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and Recalcitrant Compounds, 1st, Mo
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Dott, W., Feidieker, D., Steiof, M.
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Farrell, R., Lamar, R. & White, R.
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systems.", Transp.React.Processes A
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C02F., PCT Designated States: Desig
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Ho, S.V., Athmer, C.J., Brackin, J.
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Hunt, J. 1999, "Thermal and base-ca
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Biosorption Process.", Water, Air,
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Kokkalis, E., Kouimtzis, T., Samara
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Laha, S. & Petrova, K.P. 1998, "Bio
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Lipczynska-Kochany, E., Sprah, G. &
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Matin, M.A., Malek, M.A., Amin, M.R
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Muller, R.H., Muller, R.A., Jahn, Y
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Nurzhanova, A., Kulakow, P., Turner
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Okazaki, S., Michizoe, J., Goto, M.
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laboratory incubation studies in so
Page 194 and 195: Rhykerd, R.L., Sen, D., McInnes, K.
Page 196 and 197: Sakagami, A., Ito, K., Ogino, S. &
Page 198 and 199: Sethunathan, N. 1973, "Organic matt
Page 200 and 201: Petroleum Hydrocarbons and Organic
Page 202 and 203: Association, vol. 87th, no. Vol. 9,
Page 204 and 205: Traister, M. 1997, "Field verificat
Page 206 and 207: FI, GB, GD, GE, GH, GM, HR, HU, ID,
Page 208 and 209: WANG, T.C. & HOFFMAN, M.E. 1991, "D
Page 210 and 211: Wroblewski, D.M., Brayack, D.D. & D
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Page 214 and 215: Kogepunkt[°C]Densitet 1)[ g/ml]Hen
Page 216 and 217: Bilag CStof pH Temperatur[°C ]T ½
Page 218 and 219: Bilag DHealth and safety Plan, Rock
Page 220 and 221: Bilag D___ OrdnanceLowNot expected,
Page 222 and 223: Bilag DThe following competent pers
Page 224 and 225: Bilag D13. DECONTAMINATIONRequired
Page 226 and 227: Bilag D16. TRAININGThe following tr
Page 228 and 229: Bilag DIf an emergency situation de
Page 230 and 231: Bilag DATTACHMENT AACTIVITY HAZARD
Page 232 and 233: 232Bilag D
Page 234 and 235: Bilag ETerraTherm, Inc. - Standard
Page 236 and 237: Bilag Ephysician or other licensed
Page 238 and 239: 238Bilag E
Page 240 and 241: Bilag FBilag F: Internationale ISTD
Page 242 and 243: Bilag FUS Patents Pending:U.S. Seri
Page 246 and 247: Bilag GTitle: Thermally Enhanced So
Page 248 and 249: Bilag GTitle: Remediation of Mercur
Page 250 and 251: 250Bilag G
Page 252 and 253: Bilag HTHERMAL PESTICIDE STUDYFOR T
Page 254 and 255: Bilag Hplaced on a laboratory magne
Page 256 and 257: Bilag Hconnect will be attached to
Page 258 and 259: Bilag HIn addition to off-gas monit
Page 260 and 261: Bilag HThe test set-up will include
Page 262 and 263: Bilag H262CHEMINOVA - TERRATHERM Pa
Page 264 and 265: DENMARK THERMAL PESTICIDE STUDYHARB
Page 266 and 267: Denmark Thermal Pesticide StudyHarb
Page 278 and 279: KEMRON ENVIRONMENTAL SERVICES, INC.
Page 280 and 281: REACTOR SETUPPARAMETER10 °C - no p
Page 282 and 283: KEMRON ENVIRONMENTAL SERVICES, INC.
Page 284 and 285: Figure 1 - 70 oCKEMRON ENVIRONMENTA
Page 286 and 287: Figure 3 - 100 oC286120.0110.0100.0
Page 288 and 289: APPENDIX ACHAIN OF CUSTODY288Data c
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Page 292 and 293: APPENDIX BLABORATORY REPORTS292Data
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296
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156 Starlite Drive, Marietta, OH 45
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ID: 37863KEMRON ENVIRONMENTAL SERVI
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Report Number:L0607075Report Date :
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WORKGROUP SUMMARY BY METHODKEMRON F
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Kemron Environmental ServicesAnalys
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KEMRON Environmental ServicesMETHOD
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KEMRON Environmental ServicesLABORA
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312Page 15
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2960 Foster Creighton Road Nashvill
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2960 Foster Creighton Road Nashvill
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322
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326REACTOR WITH DISTRIBUTION "T"
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328REACTOR SITUATED IN OVEN
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33070 C, 90 C, AND 100 C TEST SET-U
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332
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