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KEMRON ENVIRONMENTAL SERVICES, INC.TERRATHERMDENMARK THERMAL PESTICIDE STUDYTABLE 1Untreated Material CharacterizationTESTINGPARAMETERUNITUNTREATEDCOMPOSITEUNTREATEDGROUNDWATERMaterial pHs.u.5.8-Moisture Content%19.07-Percent Solids%83.99-Bulk Densitylb/ft 3122.3-Dry Densitylb/ft 3102.7-Solid Specific Gravity-2.7*-Water Saturation%.80.5-Total Organic Carbonmg/kg2740-Cation Exchange Capacitymeg/100g
KEMRON ENVIRONMENTAL SERVICES, INC.TERRATHERMDENMARK THERMAL PESTICIDE STUDYTABLE 2Titration DataUntreated CompositeCumulativeAddition(ml)0.00.10.20.30.4*0.50.60.70.80.91.01.11.21.31.41.51.61.71.81.92.02.12.22.32.42.52.62.72.82.93.0pH6.187.187.558.028.208.548.899.109.379.559.689.9310.1410.2010.3110.3810.5910.9210.9711.1111.3811.4911.5111.5511.6811.8911.9812.0112.0412.0612.10CumulativeAddition(ml)3.13.23.33.43.53.63.73.83.94.04.24.44.64.85.05.25.45.65.86.06.26.46.87.27.68.08.48.89.29.610.0pH12.1512.1612.1812.2412.2712.2912.3112.3512.3712.4012.4612.4812.5312.5612.5912.6212.6412.6712.6912.7112.7212.7312.7712.7912.8112.8312.8712.9112.9312.9512.96CumulativeAddition(ml)10.410.811.211.612.012.412.813.213.614.014.414.815.215.616.016.617.217.818.619.620.621.622.623.625.030.035.0pH12.9812.9913.0013.0013.0113.0313.0413.0413.0413.0513.0513.0613.0713.0713.0813.0913.1013.1113.1213.1313.1413.1513.1713.1813.1913.2313.26NOTES:The untreated composite was prepared using 60g of soil and 20g of waterKEY* Not a complete 0.1mlTable 2 - Titration Data279KEMRON Environmental Services, Inc.Applied Technologies Group
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Termisk assisteret oprensning afhø
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IndholdFORKORTELSESLISTE 7FORORD 9S
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5.1.2 Overordnet procesbeskrivelse
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ForordDenne rapport udgør slutrapp
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• Patentforholdene for anvendelse
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Summary and conclusionsOn behalf of
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ility of parathion, methyl-parathio
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• De aktuelle stoffers stabilitet
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2 Litteraturstudie2.1 Beskrivelse a
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Der er endvidere gennemført en ræ
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for både teoretiske og praktiske u
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2.2.3 Elektrisk opvarmningVed elekt
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opnå en jordtemperatur i oprensnin
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temperaturer mellem 260 og 427 °C,
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• Fri fase udskiller• En 45-50
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Tabel 2.2: Oprensningsmekanismer ve
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Kogepunktet for størstedelen af pr
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Tabel 2.5 Halveringstid for malathi
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PCE, men sådanne beskrivelser kan
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Endvidere kan der ske en opadrettet
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2.7.3 Cheminovas erfaringerI forbin
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aTherm har fra andre termiske proje
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af, at de oppumpede gasser var bran
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Som nævnt skal der som led i detai
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2.10.1 Injektion/cirkulation af var
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ekstraherede luft. Fordi depotet ho
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opbevaret i hver sin kraftige plast
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3.2.5 HydrolyseforsøgFire 1-liters
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Prøven blev lukket med tæt låg o
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De to batches uden NaOH-tilsætning
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Bemærk, at en LEL på 100 % betyde
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Tabel 3.8 Koncentrationen af Hg i s
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3.4.1 Oprensningsprocesser og effek
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Tabel 3.10 Opsummering af risiko fo
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I [NIRAS, 2005] er det endvidere es
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Tabel 4.4 Resultat af screenings-ma
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4.3.4 Opvarmning til 300 o C (ISTD
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5 Termiske afværgeforanstaltninger
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Figur 5.2 Konceptuelt tværsnit med
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5.1.3 Boringsdetaljer og placeringD
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Figur 5.7 Foreløbig boringsplaceri
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5.2 Masse- og energibalancerTabel 5
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• 3 måneder med trykcyklusser ti
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5.4 Forventede oprensningseffektivi
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5.5.4 Pneumatisk kontrol og lugtgen
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6 Anbefalinger til fase 2I dette af
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Figur 6.1 Skitse af pilotforsøg. E
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Figur 6.3 Skitse af injektions- og
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Tabel 6.4 Energibalance og estimat
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Tabel 6.6 Forslag til monitering og
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Den endelige pris på anlægget afh
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Tabel 7.1 Sammenligning af pilotfor
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112
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Recalcitrant Compounds—2004. Proc
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Jacobsen, C.S., S. Elmholt, C.B. Je
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on Remediation of Chlorinatetd and
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1 Fuldskalaoprensning med ISTDI det
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Figur 1.2. Konceptuelt tværsnit me
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Figur 1.4. Skitse af anlæg til beh
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Figur 1.5. Skitseret layout af ISTD
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ISTD varmeboringerne forventes plac
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Tabel 1.3 Vandbalance for fuldskala
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4. Installation af varmeboringer, e
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Klargøring af oprensningsområde o
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1.5.2 Behandling og afledning af sp
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2 Pilotforsøg med ISTDI dette afsn
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Anlægget til behandling af ekstrah
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1. Der etableres hydraulisk og pneu
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I tabel 2.4 er den beregnede energi
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Tabel 2.6. Forslag til monitering o
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I pilotprojektet forudsættes gæng
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Abbas, B. 1995, "Input of DDT into
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Andrus, V.E., Nanny, M.A. & Philp,
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Bang, S. 1997, "Molecular analysis
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PCT Reg. Des. States: Designated St
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Exposition, 74th, Atlanta, GA, Unit
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Cho, Y.G., Lee, S.T., Park, Y.H. &
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and Recalcitrant Compounds, 1st, Mo
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Dott, W., Feidieker, D., Steiof, M.
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Farrell, R., Lamar, R. & White, R.
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systems.", Transp.React.Processes A
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C02F., PCT Designated States: Desig
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Ho, S.V., Athmer, C.J., Brackin, J.
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Hunt, J. 1999, "Thermal and base-ca
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Biosorption Process.", Water, Air,
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Kokkalis, E., Kouimtzis, T., Samara
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Laha, S. & Petrova, K.P. 1998, "Bio
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Lipczynska-Kochany, E., Sprah, G. &
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Matin, M.A., Malek, M.A., Amin, M.R
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Muller, R.H., Muller, R.A., Jahn, Y
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Nurzhanova, A., Kulakow, P., Turner
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Okazaki, S., Michizoe, J., Goto, M.
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laboratory incubation studies in so
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Rhykerd, R.L., Sen, D., McInnes, K.
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Sakagami, A., Ito, K., Ogino, S. &
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Sethunathan, N. 1973, "Organic matt
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Petroleum Hydrocarbons and Organic
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Association, vol. 87th, no. Vol. 9,
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Traister, M. 1997, "Field verificat
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FI, GB, GD, GE, GH, GM, HR, HU, ID,
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WANG, T.C. & HOFFMAN, M.E. 1991, "D
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Wroblewski, D.M., Brayack, D.D. & D
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212
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Kogepunkt[°C]Densitet 1)[ g/ml]Hen
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Bilag CStof pH Temperatur[°C ]T ½
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Bilag DHealth and safety Plan, Rock
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Bilag D___ OrdnanceLowNot expected,
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Bilag DThe following competent pers
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Bilag D13. DECONTAMINATIONRequired
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Bilag D16. TRAININGThe following tr
Page 228 and 229: Bilag DIf an emergency situation de
Page 230 and 231: Bilag DATTACHMENT AACTIVITY HAZARD
Page 232 and 233: 232Bilag D
Page 234 and 235: Bilag ETerraTherm, Inc. - Standard
Page 236 and 237: Bilag Ephysician or other licensed
Page 238 and 239: 238Bilag E
Page 240 and 241: Bilag FBilag F: Internationale ISTD
Page 242 and 243: Bilag FUS Patents Pending:U.S. Seri
Page 244 and 245: Bilag GBilag G: Væsentligste paten
Page 246 and 247: Bilag GTitle: Thermally Enhanced So
Page 248 and 249: Bilag GTitle: Remediation of Mercur
Page 250 and 251: 250Bilag G
Page 252 and 253: Bilag HTHERMAL PESTICIDE STUDYFOR T
Page 254 and 255: Bilag Hplaced on a laboratory magne
Page 256 and 257: Bilag Hconnect will be attached to
Page 258 and 259: Bilag HIn addition to off-gas monit
Page 260 and 261: Bilag HThe test set-up will include
Page 262 and 263: Bilag H262CHEMINOVA - TERRATHERM Pa
Page 264 and 265: DENMARK THERMAL PESTICIDE STUDYHARB
Page 266 and 267: Denmark Thermal Pesticide StudyHarb
Page 280 and 281: REACTOR SETUPPARAMETER10 °C - no p
Page 282 and 283: KEMRON ENVIRONMENTAL SERVICES, INC.
Page 284 and 285: Figure 1 - 70 oCKEMRON ENVIRONMENTA
Page 286 and 287: Figure 3 - 100 oC286120.0110.0100.0
Page 288 and 289: APPENDIX ACHAIN OF CUSTODY288Data c
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Page 292 and 293: APPENDIX BLABORATORY REPORTS292Data
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Page 298 and 299: 156 Starlite Drive, Marietta, OH 45
Page 300 and 301: ID: 37863KEMRON ENVIRONMENTAL SERVI
Page 302 and 303: Report Number:L0607075Report Date :
Page 304 and 305: WORKGROUP SUMMARY BY METHODKEMRON F
Page 306 and 307: Kemron Environmental ServicesAnalys
Page 308 and 309: KEMRON Environmental ServicesMETHOD
Page 310 and 311: KEMRON Environmental ServicesLABORA
Page 312 and 313: 312Page 15
Page 318 and 319: 2960 Foster Creighton Road Nashvill
Page 320 and 321: 2960 Foster Creighton Road Nashvill
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Page 326 and 327: 326REACTOR WITH DISTRIBUTION "T"
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328REACTOR SITUATED IN OVEN
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33070 C, 90 C, AND 100 C TEST SET-U
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332
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