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Corn Oil Extraction Optimization - Nalco

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Essential Expertise for Water, Energy and Air SM<br />

<strong>Corn</strong> <strong>Oil</strong> <strong>Extraction</strong> <strong>Optimization</strong><br />

Essential Expertise for Water, Energy and Air SM<br />

1


COE <strong>Optimization</strong> - Overview<br />

• Technology review – TSC & GR 8109<br />

• Product development<br />

• Chemistry – Not an equipment solution.<br />

• Production improvements<br />

– Both centrifuge types benefit from additive<br />

• Regulatory needs and requirements.<br />

• Market drivers – If commodity prices come down<br />

will additive continue to be cost effective?<br />

Essential Expertise for Water, Energy and Air SM<br />

2


Thin Stillage Clarification with <strong>Corn</strong> <strong>Oil</strong> Recovery<br />

Designed to increase the separation of thin stillage suspended<br />

solids at dry grind corn ethanol plants<br />

Thin Stillage<br />

Increased ethanol production through backset quality improvement<br />

Energy savings through improved evaporator & Dryer performance<br />

Improved co-product recovery - DDGS and concentration of corn fats,<br />

oils, and greases<br />

Flocculants<br />

Essential Expertise for Water, Energy and Air SM<br />

Patent Issued March 3, 2009<br />

US Patent 7497955<br />

Separation<br />

Equipment<br />

<strong>Nalco</strong> has over 60 years experience in separation technologies<br />

3


Essential Expertise for Water, Energy and Air SM<br />

Product Development<br />

• Experiences from TSC with COE allowed for product<br />

formulations to met regulatory for animal feed and<br />

allow for higher oil recovery on existing corn oil<br />

centrifuges spinning syrup (concentrated thin<br />

stillage).<br />

• <strong>Nalco</strong> studied products for years while conducting<br />

whole stillage and thin stillage research.<br />

• In the last 6-9 months, the use of these products has<br />

finally become economically favorable.<br />

• The need to meet hurdle rates on capital invested<br />

has also increased plants awareness of higher oil<br />

yields.<br />

4


Essential Expertise for Water, Energy and Air SM<br />

Production Improvements<br />

• Many of todays corn oil recovery systems are<br />

under performing.<br />

– Some producers may have seen oil yield (lbs oil/bushel)<br />

drop when compared to last years oil yield numbers.<br />

• Today plants can recover 0.1 – 0.6 lbs/bushel<br />

without any chemical additive.<br />

• Additive can help the producer increase yield by<br />

adding 0.2 – 0.4 lbs/bushel.<br />

• Net return to the plant is very dosage dependant.<br />

– Some plants return a net $6 in oil revenue/$1 spent on<br />

additive, others may return net $2 in oil revenue/$1 on<br />

additive.<br />

– It all depends on your starting point.<br />

5


Essential Expertise for Water, Energy and Air SM<br />

Production Improvements<br />

• No matter where your oil yield starts, additive can<br />

help;<br />

– Improve oil quality –<br />

– Reduce Variability in COE operation.<br />

– Increase oil yield.<br />

One<br />

Pound<br />

Syrup<br />

lb/bu 0.24 0.4 0.44 0.46<br />

6


Essential Expertise for Water, Energy and Air SM<br />

Production Improvements<br />

• Additive helps both disk stack and tricanter<br />

designs.<br />

• Important to determine optimum dosage of<br />

additive to get the highest return on your<br />

investment.<br />

7


Essential Expertise for Water, Energy and Air SM<br />

Production Improvements<br />

• ROI and Net return needs to be considered with<br />

using any additive.<br />

• Feeding highest dosages to recover highest gpm of<br />

oil is not always best.<br />

• Sometimes additive cost consumes extra oil<br />

revenue.<br />

GR-8109<br />

PPM<br />

GR-8109 <strong>Oil</strong><br />

Produced<br />

GPM<br />

Base <strong>Oil</strong><br />

Produced<br />

GPM<br />

<strong>Oil</strong> Gain<br />

GPM<br />

Net Increase<br />

$/day ROI/Day<br />

Lbs oil/bu<br />

w/GR-8109<br />

100 2.2 1.75 0.45 $ 1,781 262% 0.48<br />

200 2.5 1.75 0.75 $ 2,742 201% 0.55<br />

300 2.9 1.75 1.15 $ 4,249 208% 0.64<br />

400 3 1.75 1.25 $ 4,115 151% 0.66<br />

500 3.1 1.75 1.35 $ 3,981 117% 0.68<br />

lbs oil/bu<br />

Baseline<br />

0.38<br />

0.38<br />

0.38<br />

0.38<br />

0.38<br />

Lbs oil/bu<br />

Net Gain<br />

0.10<br />

0.16<br />

0.25<br />

0.27<br />

0.30<br />

8


Essential Expertise for Water, Energy and Air SM<br />

Production Improvements<br />

• When additives are used, you can see large<br />

incremental gains in oil production to a point and<br />

then gains begin to level off.<br />

9


Regulatory Requirements – You are what you eat!<br />

• Ethanol plants need to be aware of process contact with animal<br />

feed<br />

• Chemical products needs to be safe for animal feed<br />

– GRAS (Generally Recognized As Safe) Currently listed in<br />

CFR as GRAS for animal feed 21 CFR 582 or 584.<br />

– Self certified GRAS<br />

• <strong>Nalco</strong> uses Keller & Heckman as third party verification<br />

– CVM (FDA review- not required for compliance with feed<br />

regulations)<br />

• Not all animal rations are created equal (dietary exposure as a<br />

determination of safety is dependent on % use in animal feed, and<br />

the feed consumption factor for individual animal species)<br />

• Approvals are application specific<br />

– It is the intended use of a substance, rather than the substance<br />

itself, that is eligible for GRAS. If a product is GRAS for one<br />

use, it is not necessarily GRAS for all uses.<br />

– Application influences concentration in the final feed due to<br />

varied chemical usage levels, points of application, end<br />

product feed rations.<br />

– Cumulative exposure is also considered.<br />

Essential Expertise for Water, Energy and Air SM<br />

10


How does <strong>Nalco</strong> Determine Safety<br />

• Use the principles set forth in the Title 21 Code of Federal<br />

Regulations part 570.30 to establish GRAS status for<br />

process aids.<br />

– Outside consultants act as our Scientific Panel of Experts<br />

per 21 CFR 570.30(a)<br />

– Each and every component of the product is reviewed for<br />

compliance status as well as the suitable purity of the<br />

additive for said use.<br />

– Conservative (worst-case) assumptions are applied for end<br />

use and process parameters to estimate maximum<br />

concentration of chemical in final feed component.<br />

– Review of the component hazards in relation to the dietary<br />

exposure for all livestock animals is evaluated to ultimately<br />

determine safe use.<br />

• Assumptions and allowable maximum dosage levels are<br />

clearly communicated on product literature to ensure safe<br />

use at the customer level<br />

Essential Expertise for Water, Energy and Air SM<br />

11


Communication – Product Safety<br />

In Section 15 of the MSDS<br />

Essential Expertise for Water, Energy and Air SM<br />

12


Communication – Product Safety<br />

Information on product label.<br />

Essential Expertise for Water, Energy and Air SM<br />

13


<strong>Corn</strong> <strong>Oil</strong> <strong>Extraction</strong> <strong>Optimization</strong><br />

• If you decide additive is something you want to<br />

try, please remember:<br />

– All species of animals that may include your corn<br />

oil or DDGS in their diets need to be covered under<br />

GRAS.<br />

– All mechanical, operational, and chemical aspects<br />

of your COE system need to be optimized.<br />

– ????<br />

Essential Expertise for Water, Energy and Air SM<br />

14


• Questions ??<br />

Essential Expertise for Water, Energy and Air SM<br />

15

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