30. Furan-Based Adhesives

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furfuryl alcohol as raw materials for binders for coating different surfaces, namely: (i) The storage and the transport of hot and highly corrosive fluids such as chlorinated solvents, acids, and bases. For this purpose, the vessels (e.g., tanks, pipes, or towers) are coated with a composite material based on filled and/or glass fiber reinforced furanic matrix. (ii) The molding of liquid metals. In this context, foundry molds are produced from furan derivatives, or in combination with phenolic resins, and are utilized because of their excellent fire resistance and thermal stability. (iii) The preparation of highly resistant cements and concretes which are employed when the object is used as a container for chemicals and/or exposed to corrosive cleaning agents. (iv) The preparation of grinding wheels in which furan resins are used to bond abrasive grains. In addition to these well known applications, different studies dealing with the use of furan derivatives as wood adhesives and other miscellaneous applications are presented and discussed. REFERENCES 1. A. Gandini and M. N. Belgacem, in Polymeric Materials Encyclopedia (J. Salamone, ed.), Vol. 11, CRC Press, Boca Raton, FL, 1996, pp. 8518–8549. 2. A. Gandini and M. N. Belgacem, Progress Polym. Sci. 22: 1203 (1997). 3. W. J. McKillip and E. Sherman, in Kirk-Othmer Encyclopedia of Chemical Technology (M. Grayson, ed.), Vol. 11, John Wiley and Sons, New York, 1981, pp. 499–527. 4. A. Gardziella, L. A. Pilato, and A. Knop, Phenolic Resins, 2nd ed., Springer-Verlag, Berlin, 2000, 560 p. 5. N. Galego and A. Gandini, Revista CENIC, Sci. Fis. 6: 163 (1976). 6. A. Gandini, Adv. Polym. Sci. 25: 47 (1977). 7. M. Choura, M. N. Belgacem, and A. Gandini, Macromolecules 29: 3839 (1996). 8. M. Choura, M. N. Belgacem, and A. Gandini, Macromol. Symp. 122: 263 (1997). 9. J. B. Barr and S. B. Wallon, J. Appl. Polym. Sci. 15: 1079 (1971). 10. E. M. Wewerka, J. Polym. Sci., Part A-1 9: 2703 (1971). 11. A. H. Fawcett and W. Dadamba, Macromol. Chem. 183: 2799 (1982). 12. A. P. Dunlop and F. N. Peters, The Furans, Reinhold, New York, 1953. 13. C. N. Bye, in Handbook of Adhesives (I. Skeist, ed.), Von Nostrand Reinhold, New York, 1990, p. 148. 14. W. J. McKillip, in Adhesives from Renewable Resources (R. W. Hemingway, A. H. Conner, and S. J. Branham, eds.), ACS Symposium Series 385, American Chemical Society, Washington DC, 1989, pp. 408–423. 15. R. C. Schmitt, Polym.-Plast. Technol. Eng. 3: 121 (1974). 16. O. H. Fenner and J. E. Callaham, Mater. Perform. 16: 37 (1977). 17. A. Gardziella, A. Kwasniok, and L. Cobos, Modern Casting 86(3): 39 (1996). 18. G. F. Baxter and D. V. Redfern, U. S. Patent 2,861,977 (1958). 19. A. Pizzi, E. Orovan, and F. A. Cameron, Holz Roh Werkst. 42: 467 (1984). 20. A. J. Stamm, in Wood Technology, ACS Symposium Series 43 (I. S. Goldstein, ed.), American Chemical Society, Washington DC, 1977, pp. 141–149. 21. C. P. Dhamaney, Paintindia 28(10): 27 (1978). 22. W. E. Johns, H. D. Layton, T. Nguyen, and J. K. Woo, Holzforschung 32: 162 (1978). 23. R. C. Gupta, M. S. Rajawat, and P. P. Gupta, Holzforsch. Holzverwert. 31: 87 (1979). Copyright © 2003 by Taylor & Francis Group, LLC
24. A. Pizzi, D. du T. Rossouw, and G. M. E. Daling, Holzforsch. Holzverwert. 32: 101 (1980). 25. K. Roczniak, in Phenolic Resins: Chemical Applications, Proc. Weyrhaeuser Sci. Symp., Vol. 2, June 6–8, 1979, Tacoma, Washington, 1981, pp. 213–222. 26. H. Krach and B. Gos, Ann. Warsaw Agric. Univ., Forest Wood Technol. 29: 57 (1982). 27. J. L. Philippou, W. E. Johns, and T. Nguyen, Holzforschung 38: 119 (1982). 28. J. L. Philippou, E. Zavarin, W. E. Johns, and T. Nguyen, Forest Prod. J. 32: 55 (1982). 29. J. L. Philippou, W. E. Johns, T. Nguyen, and E. Zavarin, Forest Prod. J. 32: 27 (1982). 30. R. H. Leitheiser, B. R. Bogner, F. C. Grant-Acquah, W. E. Johns, and W. Plagemann, J. Adhesion 14: 305 (1982). 31. S. S. Kelley, R. A. Young, R. M. Rammon, and R. H. Gillespie, J. Wood Chem. Technol. 2: 317 (1982). 32. R. V. Subramanian, W. M. Balaba, and K. N. Somasekharan, J. Adhesion 14: 295 (1982). 33. J. L. Philippou, and E. Zavarin, Holzforschung 38: 119 (1984). 34. W. M. Balaba and R. V. Subramanian, Holzforschung 39: 143 (1985). 35. J. W. Frink and H. D. Layton, Proc. Washington State Univ. Int. Particleboard/Composite Mater. Symp. 19, 1985, pp. 323–347. 36. T. Nguyen and E. Zavarin, J. Wood Chem. Technol. 6: 15 (1986). 37. T. Sellers, Jr., Forest Prod. J. 39: 53 (1989). 38. T. P. Schultz, Holzforschung 44: 467–468 (1990). 39. A. Pizzi, Holz Roh Werkst. 48: 376 (1990). 40. M. S. Holfinger, (1992). Wood adhesives from furfural-based diamines and diisocyanates, Ph.D. Dissertation, University of Wisconsin, Madison (available from Univ. Microfilms Int., Order No. DA9221915, Diss. Abstr. Int. B 1992, 53(6), 3022-3), 1992, 551 pp. 41. M. S. Holfinger, A. H. Conner, L. F. Lorenz, and C. G. Hill, J. Appl. Polym. Sci. 49: 337 (1993). 42. L. Joshi and S. P. Singh, J. Timber Dev. Assoc. India 39: 19 (1993). 43. A. M. Motawie, E. H. Hassan, and M. M. Kamel, Pigment Resin Technol. 22: 4 (1993). 44. S. Ellis and L. Paszner, Holzforschung 48(Suppl.): 82 (1994). 45. B. Gos, K. Jurkowska, and M. Fichtel, Ann. Warsaw Agric. Univ., Forest Wood Technol. 46: 115 (1995). 46. M. G. Kim, G. Boyd, and R. Strickland, Holzforschung 48: 262 (1994). 47. M. H. Schneider, Y. H. Chui, and S. B. Ganev, Forest Prod. J. 46: 79 (1996). 48. L. T. Dao, Furfuryl alcohol-based adhesives in wood bonding by chemical activation, Ph.D. Dissertation, University of California, Berkeley (available from Univ. Microfilms Int., Order No. DA9028795, Diss. Abstr. Int. B 1990, 51(5), 2152), 1989, 127 pp. 49. L. T. Dao and E. Zavarin, Holzforschung 50: 470 (1996). 50. F. F. Abd El Mohsen, R. M. Mohsen, and Y. M. A. Ayana, Pigment Resin Technol. 25: 17–20 (1996). 51. K. M. P. Coppock (1996), Durable wood adhesives from furfural-based diols, diamines, and diisocyanates, Ph.D. Dissertation, University of Wisconsin, Madison (available from Univ. Microfilms Int., Order No. DA9708820, Diss. Abstr. Int., B 1997, 57(12), 7625), 1996, 317 pp. 52. M. Suzuki, Y. Yamaga, T. Kitagima, S. Takehara, H. Nishiguchi, and M. Takemoto, Shinrin Kankyo Shigen Kagaku 35: 71 (1997). 53. E. Raknes, Holz Roh Werkst. 55: 83 (1997). 54. M. G. Kim, L. Wasson, M. Burris, Y. Wu, C. Watt, and R. Strickland, Wood Fiber Sci. 30: 238 (1998). 55. I. S. Mezhov, F. N. Karpunin, and S. A. Ugryumov, Derevoobrab. Prom-st. no. 2: 17 (1998). 56. I. S. Mezhov, F. F. Sokolov, and S. A. Ugryumov, Derevoobrab. Prom-st. no. 3: 24 (1998). 57. S. A. Ugryumov, Derevoobrab. Prom-st no. 1: 27 (2000). 58. S. A. Ugryumov, Derevoobrab. Prom-st. no. 2: 28 (2000). 59. I. S. Mezhov, S. A. Ugryumov, and A. I. Glushchenko, Derevoobrab. Prom-st. no. 4: 23 (1998). 60. R. H. Leitheiser, M. E. Londrigan, and C. A. Rude, in Plastic Mortars, Sealants, and Caulking Compounds, ACS Symposium Series 113 (R. B. Seymour, ed.), American Chemical Society, Washington DC, 1979, pp. 7–26. Copyright © 2003 by Taylor & Francis Group, LLC
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Page 5 and 6: laboratory [2,7,8]. The success of
Page 7 and 8: V. FURAN RESINS AS FOUNDRY BINDERS
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Page 11 and 12: polymerization of 2 catalyzed by th
Page 13 and 14: Recently, Schneider et al. [47] fab
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Page 17: Macro-diisocyanates based on the re

30. Furan-Based Adhesives

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