Detection of halogen radicals by millimetre – wave spectroscopy

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CH22I CH I radical radical CH 3I most most abundant abun ant iodo compound in the atmosphere Natural atural source : pelagic ocean, ocean surface waters, volcanic production Previous studies studies Only nly low resolution studies studies Photoelectron spectra pectra (L.Adrews L.Adrews et t al,1984 al,1984) Matrix infrared spectrum (D.W.Smith D.W.Smith and L.Adrews,1973 L.Adrews,1973)
How How to to detect detect CH22I? CH I? Based on high level ab initio calculations calculation A = 279413,0 MHz B = 8806,1 MHz C = 8537,1 MHz → calculated spectrum → graph
Page 1 and 2: Detection of of halogen radicals by
Page 3 and 4: From October 2006 in Lille 1 Univer
Page 5 and 6: 2. 2. Part Part of of my my work wo
Page 7 and 8: 2) 2) Spectroscopic interest • CH
Page 9: What What about about CH CH22I I ??
Page 13 and 14: CH2I CH I in glow el. discharge ?
Page 15 and 16: • Secondary reaction: F + CH 2I I
Page 17 and 18: Wish Wish We have seen few paramag
Page 19 and 20: FCO 2 Probably produced during the
Page 21 and 22: Thanks Thanks to to my my superviso

Detection of halogen radicals by millimetre – wave spectroscopy

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