Detection of halogen radicals by millimetre – wave spectroscopy
Detection of halogen radicals by millimetre – wave spectroscopy
Detection of halogen radicals by millimetre – wave spectroscopy
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What What about about CH CH22I<br />
I ??? ???<br />
Difficultiies<br />
Difficult es with with producing and and<br />
detecting<br />
No experimental data <strong>of</strong> rotational rotational<br />
constants constant<br />
How ow to produce ?<br />
CH3Br CH Br + Cl → CH2Br CH Br ...exotherm<br />
... exothermic ic reaction<br />
CH3I CH I + Cl → CH2I CH I ...exo ... exo, , endo... endo...<br />
Not clear<br />
according to papers<br />
Fine and hyperfine splitting: splitting:<br />
II I (5/2)>IBr (5/2)>IBr(3/2)<br />
(3/2)<br />
Lines ines <strong>of</strong> CH 2I I are expected weaker than lines<br />
<strong>of</strong> CH2Br CH Br:<br />
= 0,8 < µ (CH2Br ) = 1<br />
: µ( ( CH2I ) =<br />
< µ(CH2Br )
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