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Detection of halogen radicals by millimetre – wave spectroscopy

Detection of halogen radicals by millimetre – wave spectroscopy

Detection of halogen radicals by millimetre – wave spectroscopy

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Change to to hydrogen<br />

abstraction with with fluorine<br />

• Atomic tomic fluorine produced in micro<strong>wave</strong> discharge:<br />

Primary reaction:<br />

CH3I CH I + F → CH2I+ CH I+ HF ???<br />

• Test at first on CH2Br CH Br radical<br />

CH2Br CH Br only observed using F 2 !!!

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