Detection of halogen radicals by millimetre – wave spectroscopy

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Change to to hydrogen abstraction with with fluorine • Atomic tomic fluorine produced in micro<strong>wave</strong> discharge: Primary reaction: CH3I CH I + F → CH2I+ CH I+ HF ??? • Test at first on CH2Br CH Br radical CH2Br CH Br only observed using F 2 !!!
• Secondary reaction: F + CH 2I I → [CH CH2FI FI] * → CH 2F F + I ??? • Test to detect CH 2F F → Detected !!! CH 3I I + F → CH 3F F + I → CH 2F F + HI • Test to detect CH 3F F → Detected!!!
Page 1 and 2: Detection of of halogen radicals by
Page 3 and 4: From October 2006 in Lille 1 Univer
Page 5 and 6: 2. 2. Part Part of of my my work wo
Page 7 and 8: 2) 2) Spectroscopic interest • CH
Page 9 and 10: What What about about CH CH22I I ??
Page 11 and 12: How How to to detect detect CH22I?
Page 13: CH2I CH I in glow el. discharge ?
Page 17 and 18: Wish Wish We have seen few paramag
Page 19 and 20: FCO 2 Probably produced during the
Page 21 and 22: Thanks Thanks to to my my superviso

Detection of halogen radicals by millimetre – wave spectroscopy

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