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Can base metal sulphides be used as a proxy for platinumgroup<br />

mineral flotation of UG2 ore?<br />

Lekgetho T.B. 1,2 , Chetty D. 2 , Tredoux M. 1<br />

1. Geology department, University of the Free State, P.O. Box 339, Bloemfontein, 9300, <strong>South</strong> <strong>Africa</strong>,<br />

thelmal@mintek.co.za<br />

2. Mineralogy division, Mintek, Private Bag x3015, Randburg, 2125, <strong>South</strong> <strong>Africa</strong>.<br />

ABSTRACT<br />

Exhaustion of shallow Merensky Reef (MR) resources led to increased attention towards the Upper Group 2<br />

chromitite (UG2), following the metallurgical advances in its processing by the 1970s. Both MR and UG2 are<br />

recovered by sulphide flotation regardless of their different compositions. In this research project, mineralogy was<br />

used to optimise the platinum group minerals (PGM) beneficiation of UG2 ore by investigating whether flotation<br />

of the base metal sulphides (BMS) can be used as a proxy to predict the flotation behaviour of the PGM as done<br />

conventionally in the industry. The mineralogy and chemical composition of the primary feed, various concentrator<br />

cells and primary tailings of a UG2 concentrator plant were analysed using a mineral liberation analyser (MLA),<br />

X-ray diffraction (XRD), wavelength dispersive-X ray fluorescence (WD-XRF), inductively coupled plasmaoptical<br />

emission spectroscopy (ICP-OES) and LECO combustion.<br />

The PGM (~80% PGE-sulphides), BMS and silicates showed positive response to sulphide flotation. However, the<br />

BMS and PGM indicated negative correlation in grain size distribution as well as significant difference in grain<br />

size range (BMS range from 1µm to >45µm, while the PGM range between 1µm and 15µm). Mineral association<br />

and liberation thus played a major role in the flotation of the PGM, as most of the PGM lost to the tailings in the<br />

samples studied were not fully liberated and were associated with the BMS that are attached to the gangue.<br />

The study has shown that BMS flotation cannot be used as a proxy to predict the PGM flotation, as the PGM<br />

appear not to be wholly dependent on the BMS flotation. Liberating the PGM by finer grinding and floating the<br />

material in particle size classes may optimise recovery of the PGM.<br />

KEYWORDS: Platinum-group minerals (PGM), base metal sulphides (BMS), UG2 flotation, mineral liberation<br />

analyser (MLA).<br />

41

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