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Sour gas - A history of expertise - Total.com

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2<br />

Processing <strong>of</strong> hydrocarbons from the Lacq field<br />

raw <strong>gas</strong><br />

desulfurization sulfur recovery unit<br />

sweet<br />

<strong>gas</strong><br />

Condensate<br />

removal<br />

lacq crude oil stabilization<br />

thiochemicals<br />

ethane<br />

steam cracker<br />

sulfur<br />

thio<br />

products<br />

<strong>com</strong>mercial <strong>gas</strong><br />

lpg<br />

(butane, propane)<br />

Ethylene<br />

light hydrocarbons<br />

condensates<br />

petroleum products<br />

the drilling assembly and plug the well. When the drill string was pulled<br />

out, the engineers discovered an unusual phenomenon – the <strong>gas</strong> had<br />

altered the molecular <strong>com</strong>position <strong>of</strong> the steel and caused cracking in<br />

all the welded parts.<br />

sUlfide Corrosion CrACKinG<br />

The explanation for this phenomenon lies in the <strong>com</strong>position <strong>of</strong> sour<br />

<strong>gas</strong>. Containing 10% carbon dioxide (CO2) and 16% hydrogen sulfide<br />

(H2S), as in the case <strong>of</strong> Lacq, the <strong>gas</strong> causes “sulfide corrosion<br />

cracking.” No one at the time knew how to produce sour <strong>gas</strong> with very<br />

high levels <strong>of</strong> sulfur, and experts considered the Lacq discovery a<br />

“write-<strong>of</strong>f.” That was no deterrent for <strong>Total</strong>. The Group set out fully<br />

determined to develop the field, which promised to be a major discovery<br />

(over 240 billion cubic meters).<br />

Two wells were drilled to appraise the size <strong>of</strong> the reservoir – one<br />

1,500 m north <strong>of</strong> the initial well, the other 1,500 m to the south.<br />

Both encountered <strong>gas</strong>, as recorded in 1953. A major research effort<br />

then got under way to define the materials and processes needed<br />

to develop the <strong>gas</strong>. In 1955, after two years <strong>of</strong> work, the Pompey<br />

steelworks presented a type <strong>of</strong> steel that was resistant to H2S.<br />

1. Aerial view <strong>of</strong> the Lacq <strong>com</strong>plex,<br />

France.<br />

11<br />

2. <strong>Total</strong> has developed a control<br />

system that adjusts the activity<br />

<strong>of</strong> reagents in real time to guarantee<br />

specified <strong>com</strong>position <strong>of</strong> the<br />

treated <strong>gas</strong>.

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