Sour gas - A history of expertise - Total.com
Sour gas - A history of expertise - Total.com
Sour gas - A history of expertise - Total.com
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2<br />
Processing <strong>of</strong> hydrocarbons from the Lacq field<br />
raw <strong>gas</strong><br />
desulfurization sulfur recovery unit<br />
sweet<br />
<strong>gas</strong><br />
Condensate<br />
removal<br />
lacq crude oil stabilization<br />
thiochemicals<br />
ethane<br />
steam cracker<br />
sulfur<br />
thio<br />
products<br />
<strong>com</strong>mercial <strong>gas</strong><br />
lpg<br />
(butane, propane)<br />
Ethylene<br />
light hydrocarbons<br />
condensates<br />
petroleum products<br />
the drilling assembly and plug the well. When the drill string was pulled<br />
out, the engineers discovered an unusual phenomenon – the <strong>gas</strong> had<br />
altered the molecular <strong>com</strong>position <strong>of</strong> the steel and caused cracking in<br />
all the welded parts.<br />
sUlfide Corrosion CrACKinG<br />
The explanation for this phenomenon lies in the <strong>com</strong>position <strong>of</strong> sour<br />
<strong>gas</strong>. Containing 10% carbon dioxide (CO2) and 16% hydrogen sulfide<br />
(H2S), as in the case <strong>of</strong> Lacq, the <strong>gas</strong> causes “sulfide corrosion<br />
cracking.” No one at the time knew how to produce sour <strong>gas</strong> with very<br />
high levels <strong>of</strong> sulfur, and experts considered the Lacq discovery a<br />
“write-<strong>of</strong>f.” That was no deterrent for <strong>Total</strong>. The Group set out fully<br />
determined to develop the field, which promised to be a major discovery<br />
(over 240 billion cubic meters).<br />
Two wells were drilled to appraise the size <strong>of</strong> the reservoir – one<br />
1,500 m north <strong>of</strong> the initial well, the other 1,500 m to the south.<br />
Both encountered <strong>gas</strong>, as recorded in 1953. A major research effort<br />
then got under way to define the materials and processes needed<br />
to develop the <strong>gas</strong>. In 1955, after two years <strong>of</strong> work, the Pompey<br />
steelworks presented a type <strong>of</strong> steel that was resistant to H2S.<br />
1. Aerial view <strong>of</strong> the Lacq <strong>com</strong>plex,<br />
France.<br />
11<br />
2. <strong>Total</strong> has developed a control<br />
system that adjusts the activity<br />
<strong>of</strong> reagents in real time to guarantee<br />
specified <strong>com</strong>position <strong>of</strong> the<br />
treated <strong>gas</strong>.