- Page 1 and 2: DIFFUSION INTERACTIONS FOR A PAIR O
- Page 3 and 4: Nyrée McDonald bispherical coordin
- Page 5 and 6: TABLE OF CONTENTS FIGURES………
- Page 7 and 8: FIGURES 1.1 Two spheres of radius a
- Page 9 and 10: 3.3 Dimensionless consumption rate
- Page 11 and 12: 3.12 Constant concentration 0 c c c
- Page 13 and 14: 5.5 Reaction probability Pint for a
- Page 15 and 16: B.1 The bispherical coordinates (μ
- Page 17 and 18: a Radius of sphere 1 1 a Radius of
- Page 19 and 20: K Matrix elements for the probabili
- Page 21 and 22: η Bispherical coordinate θ1 θ2 S
- Page 23 and 24: CHAPTER 1 HISTORICAL REVIEW OF DIFF
- Page 25 and 26: compounds (Siebel and Charcklis, 19
- Page 27 and 28: the end, Tsao (2001) claimed that t
- Page 29 and 30: 1990), permeable (Torquato and Avel
- Page 31 and 32: 4 that for site volumes fractions 1
- Page 33 and 34: internal reaction in sphere 1 and c
- Page 35 and 36: directly to the concentration and t
- Page 37 and 38: CHAPTER 2 DIFFUSION REACTION FOR A
- Page 39 and 40: 2.2 Mutualism Interaction Between a
- Page 41 and 42: P 2πa Dc 2 π 1 0 = ⎡∂u ⎤ si
- Page 43 and 44: P ( cosΘ1) n ( n+ 1) r1 1 = n d 1
- Page 45: 2.4 Mutualism-like Problem: Analyti
- Page 49 and 50: where and ( 2) ( 2) h = Q + h K , n
- Page 51 and 52: They can be calculated exactly for
- Page 53 and 54: Similarly, the coefficient h can be
- Page 55 and 56: coefficients f1n. Since h1n was act
- Page 57 and 58: G ( 1) n ( 0) ( 0) G0 K = Gn + , (2
- Page 59 and 60: probability P (2.55), and the conce
- Page 61 and 62: ate constant λ 50 . The figures 2.
- Page 63 and 64: Figure 2.2 - 2.4 shows the monotoni
- Page 65 and 66: Θ1 d Figure 2.1: Two spheres of ra
- Page 67 and 68: Figure 2.3: Reaction probability P
- Page 69 and 70: Figure 2.5: Constant concentration
- Page 71 and 72: CHAPTER 3 COMPETITIVE INTERACTION B
- Page 73 and 74: a2, respectively. Any point externa
- Page 75 and 76: The overall reaction rate at sphere
- Page 77 and 78: where Λ kn ⎛ ak = ⎜ ⎝ d n
- Page 79 and 80: ∑( ) ∞ − j ⎛ j + n⎞⎛ j
- Page 81 and 82: and ( ) 1 − 1− L ( i+ 1) () i (
- Page 83 and 84: i→∞ ( n+ i) ( ∞) v1 n = lim M
- Page 85 and 86: 1953). The reaction rate for this c
- Page 87 and 88: a1 sinh μ1 h μ = , (3.47) cosh μ
- Page 89 and 90: ispherical coordinate system holds
- Page 91 and 92: eaction rate remains virtually unch
- Page 93 and 94: on the x = 0 line with the larger s
- Page 95 and 96: contact (d=a1+a2) to far apart (d>>
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Figure 3.1: Dimensionless consumpti
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Figure 3.3: Dimensionless consumpti
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Figure 3.5: Dimensionless consumpti
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Figure 3.7: Dimensionless consumpti
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Figure 3.9: Dimensionless consumpti
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Figure 3.11: Constant concentration
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CHAPTER 4 EXACT SOLUTION FOR THE CO
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for all points external to the sink
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R 1 π π ⎡ ⎤ , ⎢⎣ ∂r1
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and −1⎛ f ⎞ μ = ⎜ ⎟ 1 si
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and the small number of infinite su
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4.4 Results and Discussion Bispheri
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4.5 Summary and Conclusions Exact a
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Figure 4.2: Dimensionless consumpti
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CHAPTER 5 DIFFUSION FROM A SPHERICA
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more concise expression for the int
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across the interface where the para
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This Pint is the ratio of the amoun
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integral is reduced to 2 π times t
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( cosθ 1) Pn 1 m ⎛ m + n⎞⎛ r
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′ i particularly for n = 0, n ′
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where int D D = ε , Γ ( φ ) = I
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T ( i+ 1) ( i) n = T n ( ) ( i) ( i
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where ε is the ratio of external t
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equation (5.14) and u the external
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Figure (5.7) where ( γ = 0. 1 and
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approach [ d a + a ) = 1], small Th
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Figure 5.2: Reaction probability Pi
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Figure 5.4: Reaction probability Pi
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Figure 5.6: Reaction probability Pi
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Figure 5.8: Reaction probability Pi
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Figure 5.10: Reaction probability P
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APPENDIX A ANALYTICAL FORMS OF Fnm
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APPENDIX B TWO SPHERES IN BISPHERIC
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with center at the origin, and the
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c ( r ) = c (r far from either sphe
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B.3 Reaction Rate The reaction rate
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where c is the concentration of the
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and dP d cos ∑( ) ≥ − − m 2
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The rate is scaled by the Smoluchow
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Sphere 2 μ =−μ2 y u φ x η= η
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[11] Clesceri, L., A. E. Greenberg,
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[37] Lifshitz, E. M. and L.P. Pitae
- Page 183 and 184:
[60] Regalbuto, M. C., Strieder, W.
- Page 185 and 186:
[84] Torquato, S., “Diffusion and