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nanoscience and society - IAP/TU Wien

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468 Nanoelectronics<br />

or bottom up. The present-day route to the fabrication<br />

of nanelectronics devices relies on the top-down approach,<br />

utilizing high-throughput optical lithography<br />

for feature sizes down to 180 nm, <strong>and</strong> electron beam<br />

lithography for feature sizes down to 30 nm with a low<br />

throughput (for masks).<br />

The top-down approach is the extension of established<br />

methods of engineering <strong>and</strong> microelectronics<br />

processing that relies on a selective patterning process,<br />

often described in terms of depositing, patterning, <strong>and</strong><br />

etching layers of material to define the circuitry <strong>and</strong> active<br />

elements. This approach continues with the miniaturization<br />

of electronic components by the development<br />

of strongly improved production processes <strong>and</strong> materials,<br />

starting from current practices. These methods are<br />

amenable to mass manufacturing, which has resulted in<br />

reduced costs (per transistor) for high-end electronics<br />

products. This approach enables developers to profit<br />

from the low-cost mass manufacturing expertise already<br />

acquired with silicon-based systems. However, exponentially<br />

increasing fabrication costs <strong>and</strong> fundamental<br />

physical limitations remain significant challenges for<br />

continued top-down miniaturization over the next decade.<br />

Top-down approaches rely on control of damage,<br />

<strong>and</strong> as the structures become smaller, the defects make<br />

device operation increasingly problematic.<br />

In addition to the top-down approach of fabricating<br />

nanoelectronics devices, nanoscientists are also<br />

employing a bottom-up approach that is based on the<br />

self-assembly techniques of atoms <strong>and</strong> molecules. Self<strong>and</strong><br />

directed-assembly mechanisms are phenomena<br />

often found in nature, from the growth of crystals to<br />

the formation of complex functional biological systems,<br />

including the cells of the human body. Therefore, in attempting<br />

the bottom-up method, nature was used as a<br />

model, <strong>and</strong> the assembly of complex structures was approached<br />

by starting with single atoms <strong>and</strong> molecules.<br />

However, the mechanisms of such processes are still not<br />

well understood <strong>and</strong> research <strong>and</strong> development in this<br />

field represents a formidable challenge.<br />

Bottom-up nanofabrication refers to device fabrication<br />

on an atom-by-atom basis. Bottom-up processes<br />

use chemically or biologically inspired routes for synthesis<br />

<strong>and</strong> assembly of nanoscale building blocks into complex<br />

nanoarchitectures with novel electronic or optical<br />

properties. Molecules, which are prefabricated arrangements<br />

of atoms in a functional form, are also appealing<br />

for bottom-up fabrication. The advantage of the bottom-up<br />

approach lies in the design <strong>and</strong> chemical synthesis<br />

of functional molecules by the billions, which can<br />

then be assembled into nanoelectronic devices. Such an<br />

approach will drastically reduce fabrication costs. However,<br />

development of controlled assembly strategies for<br />

integration of bottom-up nanostructures <strong>and</strong> nanoarchitectures<br />

into electronic devices <strong>and</strong> circuits remains<br />

a significant long-term challenge. In the medium-term,<br />

development of hybrid top-down/bottom-up fabrication<br />

strategies for electronics represents a key opportunity.<br />

Progress along both of these avenues will entail a<br />

massive amount of research effort <strong>and</strong> investment in resources.<br />

Expert opinion is that eventually the top-down<br />

<strong>and</strong> bottom-up approaches can both be combined into<br />

a single nanoelectronics manufacturing process, where<br />

certain manufacturing steps can then be carried out using<br />

the top-down approach <strong>and</strong> others using the bottomup<br />

approach. Such a hybrid method has the potential to<br />

lead to a more economical nanomanufacturing process.<br />

Emerging Devices<br />

A single-electron transistor (SET) is a three-terminal<br />

device that has switching properties controlled by the<br />

addition or subtraction of one electron, or through<br />

which only one electron may be transported at a time.<br />

The single-electron transistor is an example of a threeterminal<br />

device in which the charge of a single electron<br />

is sufficient to switch the source-to-drain current. SET<br />

devices are perceived by some to be the natural successor<br />

to the metal-oxide semiconductor field-effect transistor<br />

(MOSFET) although the research is also perceived<br />

by some companies as a method to investigate the ultimate<br />

limits of the MOSFET itself, as single electron<br />

effects will limit normal transistor action at the smallest<br />

length scales. SET devices are predominantly aimed at<br />

high-density, low-power applications.<br />

There are a number of designs for low-power SET<br />

logics, but they do not look very encouraging due to<br />

large time constants limiting the operation at very high<br />

speeds. The SET, however, shows promise for memory,<br />

probably not in the form of a single electron transistor,<br />

but more likely in the form of a nanoflash memory,<br />

since a number of the designs are a miniature version<br />

of conventional flash-type memory devices. The SET<br />

seems to be a natural extension for conventional flashtype<br />

memory devices, <strong>and</strong> may even take over for static<br />

r<strong>and</strong>om-access memory, possibly bridging the gap between<br />

more st<strong>and</strong>ard CMOS <strong>and</strong> the single-electron

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