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Proceedings of International Conference On Innovations, Recent Trends And Challenges In<br />

Mechatronics, Mechanical Engineering And New High-Tech Products Development –<br />

MECAHITECH’10, vol. 2, year: 2010<br />

New Technologies for Building Complex Prosthetic Elements<br />

from Biocompatible Metals<br />

Dan Ciobota 1 , Comsa Stanca 1 , Adrian Pacioga 1 , Doina Gheorghiu 1 , Deniz Demirtas 2<br />

1 National Institute of Research & Development for Mechatronics and Measurement Technique,<br />

6-8 Str. Pantelimon, Bucharest, Romania,<br />

dan_ciobota@yahoo.com<br />

2 EOS - Electro Optical Systems GmbH, Germany<br />

ABSTRACT<br />

This research paper is based on the national project “Studies on complex therapeutic<br />

alternatives (including Prosthetics Prototypes) for patients with respiratory disorders during sleep in<br />

order to improve quality of life and socio-professional reintegration” financed by National Centre for<br />

Programme Management (CNMP) accepted under the acronym of the project: SASPROT and contract<br />

number: 61-033/2007. The NIRDMMT-National Institute of Research and Development for<br />

Mechatronics and Measurement Technique, Bucharest, Romania develop a mandibular advancement<br />

device for the treatment of snoring and sleep apnea. It is a custom-made that snaps firmly and<br />

comfortably over the upper and lower teeth. The new technologies based on rapid prototyping<br />

techniques allow the high degree of customization for each patient.<br />

Keywords: respiratory disorders during sleep, prosthetic prototypes, rapid prototyping &<br />

manufacturing, selective laser sintering, 3D design.<br />

SELECTIVE LASER SINTERING<br />

Selective laser sintering (SLS) (fig.1) is an additive manufacturing technique that uses a high<br />

power laser (for example, a carbon dioxide laser) to fuse small particles of plastic, metal (Direct Metal<br />

Laser Sintering), ceramic, or glass powders into a mass representing a desired 3-dimensional object.<br />

The laser selectively fuses powdered material by scanning cross-sections generated from a 3-D digital<br />

description of the part (for example from a CAD file or scan data) on the surface of a powder bed.<br />

After each cross-section is scanned, the powder bed is lowered by one layer thickness, a new layer of<br />

material is applied on top, and the process is repeated until the part is completed.<br />

Compared to other methods of additive manufacturing, SLS can produce parts from a<br />

relatively wide range of commercially available powder materials. These include polymers such as<br />

nylon, (neat, glass-filled or with other fillers) or polystyrene, metals including steel, titanium, alloy<br />

mixtures, and composites and green sand. The physical process can be full melting, partial melting, or<br />

liquid-phase sintering. And, depending on the material, up to 100% density can be achieved with<br />

material properties comparable to those from conventional manufacturing methods. In many cases<br />

large numbers of parts can be packed within the powder bed, allowing very high productivity.<br />

Fig. 1 Synthetic representation of a SLS system and final product build through selective laser<br />

sintering<br />

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Proceedings of International Conference On Innovations, Recent Trends And Challenges In<br />

Mechatronics, Mechanical Engineering And New High-Tech Products Development –<br />

MECAHITECH’10, vol. 2, year: 2010<br />

SLS is performed by machines called SLS systems. SLS technology is in wide use around the<br />

world due to its ability to easily make very complex geometries directly from digital CAD data. While it<br />

began as a way to build prototype parts early in the design cycle, it is increasingly being used in<br />

limited-run manufacturing to produce end-use parts. One less expected and rapidly growing<br />

application of SLS is its use in art. The main use of Rapid Prototyping systems are presented in fig.2.<br />

Fig. 2 Main use of Rapid Prototyping systems<br />

SLS was developed and patented by Dr. Carl Deckard at the University of Texas at Austin in<br />

the mid-1980s, under sponsorship of DARPA. A similar process was patented without being<br />

commercialized by R.F. Housholder in 1979.<br />

DIRECT METAL LASER SINTERING<br />

Direct metal laser sintering (DMLS) is an additive metal fabrication technology developed by<br />

EOS out of Munich, Germany. The process involves use of a 3D CAD model whereby a .stl file is<br />

created and sent to the machine‟s software. A technician works with this 3D model to properly orient<br />

the geometry for part building and adds supports structure as appropriate. Once this „build file‟ has<br />

been completed, it is „sliced‟ into the layer thickness the machine will build in and downloaded to the<br />

DMLS machine allowing the build to begin. The DMLS machine uses a high-powered 200 Watt Ybfiber<br />

optic laser. Inside the build chamber area, there is a material dispensing platform and a build<br />

platform along with a recoater blade used to move new powder over the build platform. The<br />

technology fuses metal powder into a solid part by melting it locally using the focused laser beam<br />

(fig.3). Parts are built up additively layer by layer, typically using 20 micron layers. This process allows<br />

for highly complex geometries to be created directly from the 3D CAD data, fully automatically, in<br />

hours and without any tooling. DMLS is a net-shape process, producing parts with high accuracy and<br />

detail resolution, good surface quality and excellent mechanical properties. The controlled dosing mini<br />

equipment, allows a wide use like portable ambulatory mini equipment variant and as monitoring mini<br />

equipment for research and implementation of a new treatment in medical departments.<br />

Fig. 3 Schematic representation of the three phases of the process: powder laser sintering final<br />

part<br />

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Proceedings of International Conference On Innovations, Recent Trends And Challenges In<br />

Mechatronics, Mechanical Engineering And New High-Tech Products Development –<br />

MECAHITECH’10, vol. 2, year: 2010<br />

A number of different materials are available for use with EOSINT M systems, offering a broad<br />

range of e-Manufacturing applications. EOS CobaltChrome MP1 is a multi-purpose cobaltchromemolybdenum-based<br />

superalloy powder which has been optimized especially for processing on<br />

EOSINT M 270 systems. Other materials are also available for EOSINT M systems, including a<br />

special-purpose cobalt-chrome-molybdenum-based superalloy for dental veneering application, and<br />

further materials are continuously being developed.<br />

EOS CobaltChrome MP1 for EOSINT M 270<br />

Description, application<br />

EOS CobaltChrome MP1 is a fine powder mixture for processing on EOSINT M 270 systems,<br />

which produces parts in a cobalt-chrome-molybdenum-based superalloy. This class of superalloy is<br />

characterized by having excellent mechanical properties (strength, hardness etc.), corrosion<br />

resistance and temperature resistance. Such alloys are commonly used in biomedical applications<br />

such as dental and medical implants (note: widely used in Europe but much less so in North America),<br />

and also for high-temperature engineering applications such as in aero engines.<br />

The chemistry of EOS CobaltChrome MP1 conforms to the composition UNS R31538 of high<br />

carbon CoCrMo alloy. Parts built from this material are nickel-free (


Proceedings of International Conference On Innovations, Recent Trends And Challenges In<br />

Mechatronics, Mechanical Engineering And New High-Tech Products Development –<br />

MECAHITECH’10, vol. 2, year: 2010<br />

[1] Based on users' experience of dimensional accuracy for typical geometries, e.g. ± 20 μm when<br />

parameters can be optimized for a certain class of parts or ± 50 μm when building a new kind of<br />

geometry for the first time.<br />

[2] For larger parts the accuracy can be improved by post-process stress-relieving at 1150 ºC for 6<br />

hours.<br />

[3] Mechanical stability is dependent on geometry (wall height etc.) and application<br />

[4] Volume rate is a measure of build speed during laser exposure. The total build speed depends on<br />

the average volume rate, the recoating time (related to number of layers) and other factors such as<br />

DMLS-Start settings.<br />

Fig. 4 The software used for solid modelling<br />

Solid Works (SW) is used of solid modelling techniques that allows for the automation of several<br />

difficult engineering calculations that are carried out as a part of the design process (fig.4). Simulation,<br />

planning, and verification of processes such as machining and assembly were one of the main<br />

catalysts for the development of solid modelling. More recently, the range of supported manufacturing<br />

applications has been greatly expanded to include sheet metal manufacturing, injection moulding,<br />

welding, pipe routing etc.<br />

Beyond traditional manufacturing, solid modelling techniques serve as the foundation for rapid<br />

prototyping, digital data archival and reverse engineering by reconstructing solids from sampled points<br />

on physical objects, mechanical analysis using finite elements, motion planning and Numerical Control<br />

(NC) path verification, kinematic and dynamic analysis of mechanisms, and so on. A central problem<br />

in all these applications is the ability to effectively represent and manipulate 3 dimensional geometry,<br />

in a fashion that is consistent with the physical behaviour of real artifacts. Solid modelling research<br />

and development has effectively addressed many of these issues, and continues to be a central focus<br />

of computer aided engineering.<br />

Fig. 5 Parts build on SolidWorks<br />

Building a model in SolidWorks usually starts with a 2D sketch (although 3D sketches are<br />

available for power users). The sketch consists of geometry such as points, lines, arcs, conics (except<br />

105


Proceedings of International Conference On Innovations, Recent Trends And Challenges In<br />

Mechatronics, Mechanical Engineering And New High-Tech Products Development –<br />

MECAHITECH’10, vol. 2, year: 2010<br />

the hyperbola), and splines. Dimensions are added to the sketch to define the size and location of the<br />

geometry. Relations are used to define attributes such as tangency, parallelism, perpendicularity, and<br />

concentricity. The parametric nature of SolidWorks means that the dimensions and relations drive the<br />

geometry, not the other way around. The dimensions in the sketch can be controlled independently, or<br />

by relationships to other parameters inside or outside of the sketch. Some elements for mandibular<br />

advancement device draw in this program are presented in fig. 5.<br />

SolidWorks pioneered the ability of a user to roll back through the history of the part in order to<br />

make changes, add additional features, or change the sequence in which operations are performed.<br />

Later feature-based solid modeling software has copied this idea.<br />

In an assembly, the analog to sketch relations are mates. Just as sketch relations define<br />

conditions such as tangency, parallelism, and concentricity with respect to sketch geometry, assembly<br />

mates define equivalent relations with respect to the individual parts or components, allowing the easy<br />

construction of assemblies. SolidWorks also includes additional advanced mating features such as<br />

gear and cam follower mates, which allow modeled gear assemblies to accurately reproduce the<br />

rotational movement of an actual gear train.<br />

Finally, drawings can be created either from parts or assemblies. Views are automatically<br />

generated from the solid model, and notes, dimensions and tolerances can then be easily added to<br />

the drawing as needed. The drawing module includes most paper sizes and standards (ANSI, ISO,<br />

DIN, GOST, JIS, BSI and GB).<br />

SUPPORT GENERATION (SG) MODULE<br />

Support generation is crucial to correctly build your rapid prototypes made with stereo<br />

lithography or metal sintering. Support structures are needed to prevent distortion, to keep everything<br />

in place and to easy remove the part from the platform. Magics Support Generation module is a<br />

proven solution that allows quick, easy and automated creation and editing of support structures. This<br />

software effectively narrows the gap between part design and part production as it transforms the<br />

design directly to ready-to-produce data. Reliability, part integrity and ease of removal of support<br />

structures – key issues in rapid prototyping – are maximised by Magics Support Generation (fig.6).<br />

Fig. 6 The software used for SG and STL generation/verification<br />

New features in Magics 12.1<br />

For the SG – Support Generation:<br />

- Option to synchronize upper and lower teeth<br />

- Full teeth option at the end of a line support<br />

The build parts in SW are verified in Magics and ready for send to RP process (fig.7)<br />

Fig. 7 The previous build parts in SW now verified in Magics and sending to RP process<br />

106


Proceedings of International Conference On Innovations, Recent Trends And Challenges In<br />

Mechatronics, Mechanical Engineering And New High-Tech Products Development –<br />

MECAHITECH’10, vol. 2, year: 2010<br />

STL<br />

STL is the abbreviation of Standard Triangulation Language. The principle of this file-type is<br />

simple. Each surface (an object = collection of surfaces) can be described as a collection of triangles.<br />

In the same way, the outside of the Space Shuttle is covered with (square) Heat Shields.<br />

A square can be described with 2 triangles. A cube with 6 x 2= 12 triangles. Curved surfaces<br />

need more triangles. When the tolerance of the surface is high, i.e. when the surface should be very<br />

smooth, you need more triangles. Conclusion: the more detailed, the heavier files will be. Small STLfiles<br />

will give rougher descriptions. STL is used especially in rapid prototyping and most of the CAD<br />

systems can export STL-files. More and more applications begin to use STL-files. This software is an<br />

example of the expansion of the use of STL-files. The software has originally been developed for use<br />

in RP-applications. The Tooling Module has made it possible to design Moulds out of the STLdescription<br />

of an object.<br />

Shells<br />

A shell is a collection of triangles that are correctly connected with each other. A shell can be<br />

closed, describing one volume, or it can be open, describing an open surface. A triangle is part of a<br />

shell when the direction of rotation of the vectors of two adjacent triangles is opposite.<br />

LAYER PRINCIPLE<br />

Most of the RP machines build an object layer by layer like the pyramids were built (fig.8).<br />

Fig. 8 Typical layers build on RP&M machines<br />

Each layer has a certain thickness that is inherent to the material used. In RP applications you<br />

have several layers in 1 mm. Smaller layers allow the user to have smoother surfaces but will also<br />

require longer build times. The layer principle results in 2.5 dimensional objects, i.e. in the XY-plane<br />

each curve can be drawn but in the Z-direction you will always have an approximation of the curved<br />

shape of the object.<br />

Material data sheet<br />

Physical and chemical properties of parts<br />

- Material composition: Co: 60 - 65 %<br />

Cr: 26 - 30 %<br />

Mo: 5 - 7 %<br />

Si: max. 1.0 %<br />

Mn: max. 1.0 %<br />

Fe: max. 0.75 %<br />

C: max. 0.16 %<br />

Ni: max. 0.10 %<br />

- Relative density with standard parameters: Approx. 100 %<br />

- Density with standard parameters: 8.3 g/cm³<br />

107


Proceedings of International Conference On Innovations, Recent Trends And Challenges In<br />

Mechatronics, Mechanical Engineering And New High-Tech Products Development –<br />

MECAHITECH’10, vol. 2, year: 2010<br />

Final parts on the plate just after finish the RP process are presented in figure 9, and after their<br />

taking from the plate and sanding presented in figure 10.<br />

Fig. 9 Final parts on the plate just after finish the RP process<br />

Fig. 10 The final parts just after few hours from starting the job<br />

Mechanical properties of the parts realized with this technology are presented in tables 1 and 2.<br />

Table 1 Mechanical properties of parts at 20 °C<br />

Properties<br />

As processed<br />

High temp.stress<br />

relieved<br />

6 hours at 1150ºC<br />

Ultimate tensile strengh In horizontal direction (XY) 1200 ±150 MPa 1100 ±100 MPa<br />

(SR EN ISO 6892-1:2010) In vertical direction (Z) 1200 ±150 MPa 1100 ±100 MPa<br />

Yield strength (Rp 0.2 %) In horizontal direction (XY) 950 ±100 MPa 600 ±50 MPa<br />

(SR EN ISO 6892-1:2010) In vertical direction (Z) 800 ±100 MPa 600 ±50 MPa<br />

Elongation at break<br />

In horizontal direction (XY) Min 8% Min 20%<br />

(SR EN ISO 6892-1:2010) In vertical direction (Z) Min 8% Min 20%<br />

Young‟s Modulus<br />

(MPIF 10)<br />

Fatigue life (ASTM E466:1996)<br />

Hardness (DIN EN ISO6508-1)<br />

Table 2 Thermal properties of parts<br />

Properties<br />

Coefficient of thermal<br />

expansion, as processed:<br />

Thermal conductivity, as<br />

processed:<br />

In horizontal direction (XY) 190 ±20 MPa 200 ±20 MPa<br />

In vertical direction (Z) 190 ±20 MPa 200 ±20 MPa<br />

In vertical direction (Z) at<br />

0-440MPa load and 45Hz<br />

>10 million cycles<br />

35-45 HRC<br />

Value<br />

- over 20-500 ºC 13.6 x 10 -6 m/m ºC<br />

- over 20-500 ºC 15.1 x 10 -6 m/m ºC<br />

- at 20 ºC 13 W/m ºC<br />

- at 300 ºC 18 W/m ºC<br />

- at 500 ºC 22 W/m ºC<br />

- at 1000 ºC 33 W/m ºC<br />

Maximum operating temperature 1150 ºC<br />

Melting range 1350-1430 ºC<br />

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Proceedings of International Conference On Innovations, Recent Trends And Challenges In<br />

Mechatronics, Mechanical Engineering And New High-Tech Products Development –<br />

MECAHITECH’10, vol. 2, year: 2010<br />

The quoted values from the tables refer to the use of these materials with EOSINT M270<br />

systems according to current specifications (including the latest released process software PSW and<br />

any hardware specified for the relevant material) and operating instructions. All values are<br />

approximate. Unless otherwise started, the quoted mechanical and physical proprieties refer to<br />

standard building parameters and test samples built in horizontal orientation. They depend on the<br />

building parameters and strategies used, which can be varied by the user according to the application.<br />

Measurements of the same proprieties using different test methods (e.g. specimen geometrics) can<br />

give different results.<br />

CONCLUSION<br />

We were the first Romanian entity which installs DMLS equipment. The team who work on<br />

RP&M machine is presented in figure 11.<br />

Since 2007, INCDMTM work to identify product applications and introduce our systems to the<br />

manufacturing industry.<br />

With the purchase of the new titanium-based system, INCDMTM stays among the leading<br />

suppliers who are willing to explore DMLS (Direct Metal Laser Sintering) and the breakthroughs it<br />

holds for innovative companies. How yearly demand for laser-sintering services has increased we<br />

expect interest in titanium parts to follow the same strong demand curve.<br />

Fig. 11 The TEAM who work on RP&M machine (EOSINT M 270 Xtended machine)<br />

As new technology and innovative production methodology develop, our company will become<br />

more important in the manufacture of specialized prosthetic components, working to improve quality of<br />

life and socio-professional reintegration.<br />

Thus, we aim to grow the ERA – European Research Area by following the EU directives for<br />

improving the quality of life of EU citizens.<br />

REFERENCES<br />

[1] EOS CobaltChrome MP1 - MS / 11-08 - EOS GmbH - Electro Optical Systems – WWW.eos.info<br />

[2] Materialise MAGICS Manual – 12.1 English version – www.materialise.com<br />

[3] EOSINT M 270 Xtended – Operation Manual<br />

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