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Foamed seals in one-component polyurethane - Ceracon

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A. S. Kreissl, S. Hoof*<br />

<strong>Foamed</strong> <strong>seals</strong> <strong>in</strong><br />

<strong>one</strong>-comp<strong>one</strong>nt <strong>polyurethane</strong><br />

The Pengu<strong>in</strong> foam system with the Foamply application technology produces foamed <strong>seals</strong><br />

<strong>in</strong> <strong>one</strong>-comp<strong>one</strong>nt elastomers directly onto the comp<strong>one</strong>nt to be sealed (FIPG seal<strong>in</strong>g technology<br />

= form-<strong>in</strong>-place gaskets). Complex seal shapes can also be achieved. Foam<strong>in</strong>g<br />

takes place by ventilation of the liquid plastic with conventional compressed air. Cur<strong>in</strong>g<br />

time amounts to only a few m<strong>in</strong>utes. The applied seal is characterised by closed cells with<br />

even pore distribution, result<strong>in</strong>g <strong>in</strong> a waterproof foam.<br />

1. Introduction<br />

Elastomer <strong>seals</strong> are currently used <strong>in</strong> numerous<br />

applications that require seal<strong>in</strong>g aga<strong>in</strong>st<br />

dust or water. Conventional foam processes<br />

often fail <strong>in</strong> seal<strong>in</strong>g aga<strong>in</strong>st water, as open<br />

cell <strong>seals</strong> arise <strong>in</strong> the chemical foam<strong>in</strong>g<br />

process. Very high water absorption can be<br />

observed particularly when the seal’s sk<strong>in</strong> is<br />

damaged. S<strong>in</strong>gle comp<strong>one</strong>nt physically foamed<br />

<strong>seals</strong> are becom<strong>in</strong>g <strong>in</strong>creas<strong>in</strong>gly accepted<br />

for waterproof solutions. The Pengu<strong>in</strong><br />

foam process offers particular advantages<br />

<strong>in</strong> this area. The system and its associated<br />

Foamply application technology has been<br />

developed by Sunstar <strong>in</strong> Japan and has been<br />

used there successfully <strong>in</strong> the automotive<br />

and electronics <strong>in</strong>dustries for more than<br />

10 years (Fig. 1). The company<br />

CeraCon <strong>in</strong> Weikersheim,<br />

Germany,<br />

has been supply<strong>in</strong>gre-<br />

Fig. 1:<br />

Comp<strong>one</strong>nt with<br />

foamed sealant bead<br />

* Andreas S. Kreissl<br />

Manag<strong>in</strong>g Director of CeraCon GmbH, Weikersheim<br />

Stephan Hoof<br />

Technical Service Eng<strong>in</strong>eer at Sunstar, Weikersheim<br />

PU MAGAZINE – VOL. 2, NO. 2 – APRIL 2005<br />

nowned customers <strong>in</strong> Europe with foam<br />

plants and the associated automation systems<br />

dur<strong>in</strong>g the last 5 years. The <strong>one</strong>-comp<strong>one</strong>nt<br />

foams are based on <strong>polyurethane</strong> or<br />

silic<strong>one</strong>. Cold and hot cur<strong>in</strong>g versions of the<br />

material are available.<br />

2. Physical <strong>in</strong>stead<br />

of chemical foam<strong>in</strong>g<br />

Two basically different processes are possible<br />

for foam<strong>in</strong>g of <strong>seals</strong>: chemical and mechanical<br />

foam<strong>in</strong>g. The former produces a bubble<br />

structure by means of a chemical reaction,<br />

<strong>in</strong> which two highly reactive comp<strong>one</strong>nts<br />

have to be precisely dosed and homogenously<br />

mixed together. The high reactivity (chemical<br />

cur<strong>in</strong>g reaction) <strong>in</strong> the materials mix<strong>in</strong>g<br />

chamber requires that the process parame-<br />

Fig. 2:<br />

Diagram of distribution<br />

of bubbles through shear<br />

force.<br />

▲<br />

Initial velocity ; 6.0 cm/sec<br />

Bubble; φ 3.0 mm<br />

ters are carried out with<strong>in</strong> very narrow tolerances.<br />

The technical requirements set upon<br />

the plant for this are very complex and the<br />

process management problematic. Fluctuations<br />

<strong>in</strong> the quality of the <strong>seals</strong> cannot be<br />

excluded and are generally associated with<br />

changes <strong>in</strong> ambient conditions (air humidity,<br />

temperature). Signifi cant variations <strong>in</strong> the<br />

chemical foam seal are common.<br />

In contrast, when foam<strong>in</strong>g <strong>seals</strong> with the<br />

Pengu<strong>in</strong> foam system, air and <strong>one</strong>-comp<strong>one</strong>nt<br />

<strong>polyurethane</strong> are homogenised and divided up<br />

<strong>in</strong>to fi ne bubbles. It is through this mechanical<br />

foam<strong>in</strong>g at room temperature that a closed<br />

cell foam structure arises. The way <strong>in</strong> which<br />

it works can be described as follows (Fig. 2):<br />

after the <strong>in</strong>troduction of a defi ned volume of<br />

air to liquid elastomer, a tw<strong>in</strong> phase fl ow is<br />

stream is produced on a conveyor system.<br />

This way, the gas is distributed evenly <strong>in</strong>to the<br />

liquid by shear force. Once ventilated, the<br />

process makes use of the specifi c fl ow properties<br />

of highly viscous polymers to fi nely<br />

distribute and homogenise the material. As<br />

soon as the tw<strong>in</strong> phase liquid relaxes aga<strong>in</strong><br />

under atmospheric pressure, the air expands<br />

and it forms the desired foam. No cur<strong>in</strong>g reaction<br />

takes place <strong>in</strong> the plant, so that the<br />

system never has to be r<strong>in</strong>sed or cleaned.<br />

3. The foam plant<br />

The material and the plant are developed <strong>in</strong><br />

harmony. A plant that is ready for production<br />

Time = 0.001sec<br />

Time = 0.100 sec<br />

Time = 0.360 sec<br />

Tubu diameter ; 10 mm, length ; 100 mm<br />

93


consists of the Foamply application technology<br />

with <strong>in</strong>tegrated control technology and<br />

a handl<strong>in</strong>g robot that applies the sealant<br />

bead to the comp<strong>one</strong>nt, followed by passage<br />

through an oven for a short period if a heat<br />

cur<strong>in</strong>g material version has been chosen.<br />

Figure 3 shows the arrangement of the<br />

plant without the “Thermo” oven cure sys-<br />

Fig. 4: Degree of foam<strong>in</strong>g as a function of the<br />

ventilation pressure<br />

▼<br />

Foam<strong>in</strong>g Magnification<br />

3,5<br />

3,0<br />

2,5<br />

2,0<br />

1,5<br />

#3150<br />

#3160<br />

1,0<br />

0,00 0,05 0,10 0,15 0,20<br />

Gas Pressure (MPa)<br />

tem. A feed<strong>in</strong>g pump and a conventional<br />

compressed air system (max. 6 bar) provide<br />

material and air to the mach<strong>in</strong>e. The foam<br />

volume can be varied very easily up to a<br />

factor of 3.5:1 (Fig. 4). The essential advantages<br />

of the process are:<br />

Over 95 % plant availability (no r<strong>in</strong>s<strong>in</strong>g<br />

agents, no special waste)<br />

Stable runn<strong>in</strong>g of the process, also under<br />

tough work<strong>in</strong>g conditions (wide tolerance<br />

to comp<strong>one</strong>nt temperature and ambient<br />

conditions)<br />

Inl<strong>in</strong>e capability and direct modifi cation<br />

after only several m<strong>in</strong>utes (cur<strong>in</strong>g with<strong>in</strong><br />

5 m<strong>in</strong>. at 80 °C)<br />

Fig. 5: Shore A hardness as a function of the<br />

foam<strong>in</strong>g ratio<br />

▼<br />

Shore A<br />

80<br />

70<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

0<br />

▲<br />

Fig. 3:<br />

Plant arrangement<br />

It is also <strong>in</strong>terest<strong>in</strong>g that this technology can<br />

operate reliably irrespective of comp<strong>one</strong>nt<br />

temperature. This enables cold metal parts<br />

to be sealed without pre-heat<strong>in</strong>g, or warm<br />

<strong>in</strong>jection moulded parts without cool<strong>in</strong>g. The<br />

Foamply plant technology has been specially<br />

developed for Pengu<strong>in</strong> foam materials, but<br />

it also operates <strong>in</strong> pr<strong>in</strong>ciple with other <strong>one</strong>comp<strong>one</strong>nt<br />

thixotropic elastomers.<br />

4. Properties and<br />

application possibilities<br />

The foam quality is entirely reproducible. This<br />

is a signifi cant advantage, bear<strong>in</strong>g <strong>in</strong> m<strong>in</strong>d<br />

the usual certifi ed quality assurance systems.<br />

A further important aspect is the much<br />

shorter cur<strong>in</strong>g times of the products. The hot<br />

cur<strong>in</strong>g material version cures at 80 °C <strong>in</strong> just<br />

fi ve m<strong>in</strong>utes. The foamed comp<strong>one</strong>nts can<br />

therefore be assembled already after fi ve to<br />

1 2 2.5 3<br />

Foam<strong>in</strong>g ratio<br />

94 PU MAGAZINE – VOL. 2, NO. 2 – APRIL 2005<br />

#3151<br />

#3160<br />

ten m<strong>in</strong>utes, compared with several hours<br />

with conventional two-comp<strong>one</strong>nt foams. As<br />

only <strong>one</strong> comp<strong>one</strong>nt is dosed, very small<br />

<strong>seals</strong> can also be reliably produced. The<br />

hardness values of the <strong>seals</strong> <strong>in</strong> relation to the<br />

degree of foam<strong>in</strong>g are shown <strong>in</strong> Figure 5.<br />

The <strong>in</strong>terest<strong>in</strong>g applications <strong>in</strong>clude the automotive<br />

<strong>in</strong>dustry (door modules, lights, control<br />

equipment), the household appliance <strong>in</strong>dustry<br />

(wash<strong>in</strong>g and dishwash<strong>in</strong>g mach<strong>in</strong>es, irons)<br />

and all types of hous<strong>in</strong>gs (control cab<strong>in</strong>ets,<br />

fl uorescent light fi tt<strong>in</strong>gs, electrical distribution<br />

cab<strong>in</strong>ets, fi lters).<br />

5. Conclusion<br />

The Foamply <strong>one</strong>-comp<strong>one</strong>nt foam technology<br />

enables the application of waterproof<br />

elastomer <strong>seals</strong> with the highest degree of<br />

reliability and plant availability, us<strong>in</strong>g simple<br />

operation and m<strong>in</strong>imum ma<strong>in</strong>tenance. Further<br />

additional benefi ts are the very fast cur<strong>in</strong>g of<br />

the <strong>seals</strong>, the environmentally benefi cial<br />

pr<strong>in</strong>ciple of elim<strong>in</strong>ation of r<strong>in</strong>s<strong>in</strong>g cycles and<br />

the <strong>in</strong>sensitivity to fl uctuations <strong>in</strong> room temperature<br />

and air humidity. Optimum harmonisation<br />

of plant technology and materials<br />

enables cost-effective and fast production of<br />

highest quality elastomer <strong>seals</strong> that are optimally<br />

suited for the application.<br />

■<br />

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Don't Don't hesitate hesitate to contact: contact:<br />

Ph<strong>one</strong>: +49 (0) 2102 93 45-0<br />

Fax: +49 (0) 2102 93 45-20<br />

Email: ads@pu-magaz<strong>in</strong>e.com

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