Synthesis, Structure and Catalytic Activity of ... - Jacobs University

3.4.1 Ti-{P 2W 16} compound, Polyanion 8 83
3.4.1.1 Synthetic procedure 85
3.4.1.2 FT-IR Data 85
3.4.1.3 Single crystal X-ray data 87
3.4.1.4 Thermogravimetric analysis data 89
3.4.1.5 Nuclear magnetic resonance studies 90
3.4.1.6 Conclusion 93
3.5 Disordered structures 94
3.5.1 [Ti 9.3 As 6 W 59.7 O 244 (H 2O) 4] 82- , Polyanion 9 94
3.5.2 {Ti 4P 8W 48}, Polyanion 10 96
3.6 References 98
Chapter IV Catalytic Results
4.1 Heterogeneous catalysis with Ru-POMs 101
4.1.1 Synthetic procedures, FT-IR and NMR spectroscopy data 103
4.1.2 Structure discussion 109
4.1.3 Catalytic experiments 112
4.1.4 Catalytic results 113
4.2 Homogeneous catalysis with Zr/Hf-POMs 116
4.2.1 Synthetic procedures, FT-IR and NMR spectroscopy data 117
4.2.2 Structure discussion 120
viii