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Vacuum Gas Oils, Hydrocracked Gas Oils, and Distillate Fuels 9.3. Distribution of Gas Oils (vacuum, hydrocracked & distillate fuels) R20, R38, R40, R65, R51/53 – Industrial 9.3.1. Exposure Scenario Section 1 Exposure Scenario Title Gas Oils (vacuum, hydrocracked & distillate fuels) R20, R38, R40, R65, R51/53 Title Distribution of Substance Use Descriptor Sector(s) of Use 3 Process Categories 1, 2, 3, 4, 8a, 8b, 9, 15 Further information on the mapping and allocation of PROC codes is contained in Table 9.1 Environmental Release Categories 1, 2, 3, 4, 5, 6a, 6b, 6c, 6d, 7 Specific Environmental Release Category ESVOC SpERC 1.1b.v1 Processes, tasks, activities covered Bulk loading (including marine vessel/barge, rail/road car and IBC loading) and repacking (including drums and small packs) of substance, including its sampling, storage, unloading, maintenance and associated laboratory activities. Assessment Method See Section 3. Section 2 Operational conditions and risk management measures Section 2.1 Control of worker exposure Product characteristics Physical form of product Liquid Vapour pressure (kPa) Liquid, vapour pressure
Vacuum Gas Oils, Hydrocracked Gas Oils, and Distillate Fuels General exposures (Open systems) CS16 Process sampling CS2 Laboratory activities CS36 Bulk closed loading and unloading CS501 Bulk open loading and unloading CS503 Drum and small pack filling CS6 Equipment cleaning and maintenance CS39 Wear suitable gloves tested to EN374 PPE15 No other specific measures identified EI20 No other specific measures identified EI20 Handle substance within a closed system E47 Wear suitable gloves tested to EN374 PPE15 Wear suitable gloves tested to EN374 PPE15 Wear suitable gloves tested to EN374 PPE15 Drain down system prior to equipment break-in or maintenance. E65. Wear chemically resistant gloves (tested to EN374) in combination with ‘basic’ employee training. PPE16 Storage CS67 Handle substance within a closed system. E84 Additional information on the basis for the allocation of the identified OCs and RMMs is contained in Appendices 2 to 3 Section 2.2 Control of environmental exposure Product characteristics Substance is complex UVCB [PrC3]. Predominantly hydrophobic [PrC4a]. Amounts used Fraction of <strong>EU</strong> tonnage used in region 0.1 Regional use tonnage (tones/year) 2.8e7 Fraction of Regional tonnage used locally 0.002 Annual site tonnage (tonnes/year) 5.6e4 Maximum daily site tonnage (kg/day) 1.9e5 Frequency and duration of use Continuous release [FD2]. Emission days (days/year) 300 Environmental factors not influenced by risk management Local freshwater dilution factor 10 Local marine water dilution factor 100 Other given operational conditions affecting environmental exposure Release fraction to air from process (initial release prior to RMM) 1.0e-3 Release fraction to wastewater from process (initial release prior to 1.0e-6 RMM) Release fraction to soil from process (initial release prior to RMM) 0.00001 Technical conditions and measures at process level (source) to prevent release Common practices vary across sites thus conservative process release estimates used [TCS1]. Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil Risk from environmental exposure is driven by human via indirect exposure (primarily ingestion) [TCR1j] Prevent discharge of undissolved substance to or recover from onsite wastewater [TCR14].No wastewater treatment required [TCR6]. Treat air emission to provide a typical removal efficiency of (%) 90 Treat onsite wastewater (prior to receiving water discharge) to provide 0 the required removal efficiency (%) If discharging to domestic sewage treatment plant, provide the required 0 onsite wastewater removal efficiency of (%) Organisation measures to prevent/limit release from site Prevent discharge of undissolved substance to or recover from wastewater [OMS1]. Do not apply industrial sludge to natural soils [OMS2]. Sludge should be incinerated, contained or reclaimed [OMS3]. Conditions and measures related to municipal sewage treatment plant 2010-07-30 CSR 118
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Gas Oils (Vacuum) 4 DNEL (inhalatio
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Industrial - Tabletting, CS100 Indo
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Combined Professional - Manual spra
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Industrial - Bulk transfers CS14 Da
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Professional - Maintenance and CS77
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Note: differentiated Industrial -SU
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Professional - Treatment and dispos
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Industrial - operation of open CS16
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Gas Oils (Vacuum) 4 DNEL (inhalatio
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Industrial - Tabletting, CS100 Indo
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Combined Professional - Manual spra
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Industrial - Bulk transfers CS14 Da
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Professional - Maintenance and CS77
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Note: differentiated Industrial -SU
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Professional - Treatment and dispos
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Industrial - operation of open CS16
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This tool is provided for informati
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An Evaluation of the Persistence, B
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Table of Contents Executive Summary
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2.0 Outline of PBT/vPvB Assessment
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3.0 Persistence Assessment of Petro
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100.0 Half-life predicted (days) 10
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2,3-dimethylheptane 9 7.7 6.2 7.4 2
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ioHCwin half-life (days) 10000.0 10
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criterion. It can be concluded that
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Hydrocarbon C nr BioHCwin Predicted
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ioHCwin half-life (days) 1000000.0
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Hydrocarbon C nr BioHCwin Predicted
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enzo[a]pyrene 20 421.6 16.5 Table 1
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(see Appendix 2). Since BCF predict
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10000 BCF (Arnot) 1000 100 10 1 n-P
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exhibit BMFs near unity (Figure 28)
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2,2,4,4,6,8,8- heptamethyl nonane 1
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Hydrocarbon C BMF BCF (Arnot) Dieta
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BCF (regression) 100000 10000 1000
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4.5 Polynaphthenic hydrocarbons Reg
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Experimental BMF 10 1 Polynaphth. D
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enzene n-octylbenzene 14 0.034 403
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10000 1000 BCF (Arnot) 100 10 1 NMA
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and appears to be an outlier. This
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4-ethylbiphenyl 14 863 1039 C Yakat
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100000 BCF (regression) 10000 1000
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10 Experimental BMF 1 0.1 NDiAr Die
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Hydrocarbon C BMF Arnot BCF Dietary
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Hydrocarbon C BMF Arnot BCF Dietary
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Acenaphthene Acenaphthylene Benz(a)
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5.0 Summary of Persistence and Bioa
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lower water solubility, it is possi
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properties of petroleum hydrocarbon
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8.0 References Anonymous (2004). Fi
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EMBSI (2007c). Fish, dietary bioacc
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Prince RC, Walters CC. (2007). Biod
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Appendix 1. Hydrocarbon structures
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iP 14 2,4,10-Trimethylundecane CC(C
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MN 7 1,2-Dimethylcyclopentane CC1C(
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MN 14 n-Nonylcyclopentane CCCCCCCCC
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MN 29 MN 29 MN 30 n-Tetracosylcyclo
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hexahydroindane DN 20 2,4-dimethylo
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PN 27 Phenanthrene 2,6-dimethylhept
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MAr 13 1-Methyl-3-hexylbenzene Cc1c
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NMAr 12 n-Propylindan c1ccc2CC(CCC)
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NMAr 24 c1cc(CC(C)CCCC(C)CCCCC)c2CC
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NMAr 29 NMAr 29 NMAr 29 NMAr 29 NMA
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DAr 16 2-Hexylnaphthalene CCCCCCc1c
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NDAr 16 n-Butylacenaphthene c12cccc
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NDAr 26 Dimethyloctyl-1,2,3,6,7,8-
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PAr 19 Ethylbenzo(a)fluorene C3c1cc
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PAr 22 n-Pentylbenzo(a)fluorene C3c
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PAr 28 Isohexyl-octadecahydro-picen
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Appendix 3. CONCAWE Position Paper
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probabilities are adjusted to best
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1.2.2 OASIS LMC Models: Toxicologic
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environmental chemicals (database o
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dihydrodiol. These dihydroxylated i
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Table 1 : PBT assessment of C15 str
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1: The following structures were pr
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Dimitrov SD, Dimitrova N, Mekenyan
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hydrocarbons and azaarenes original
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Verhaar HJM, van Leeuwen CJ, Hermen
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CONCAWE AQUATIC TOXICITY PREDICTION
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CONTENTS (Continued) Section Page 1
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1-2 The model predictions include m
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2-1 SECTION 2 2 SUMMARY OF COMPOSIT
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10-1 SECTION 10 10 SUMMARY OF COMPO
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