EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

More documents

Recommendations

Info

Vacuum Gas Oils, Hydrocracked Gas Oils, and Distillate Fuels 9.9. Use of Gas Oils (vacuum, hydrocracked & distillate fuels) R20, R38, R40, R65, R51/53 in Lubricants – Industrial 9.9.1. Exposure Scenario Section 1 Exposure Scenario Title Gas Oils (vacuum, hydrocracked & distillate fuels) R20, R38, R40, R65, R51/53 Title Lubricants Use Descriptor Sector(s) of Use 3 Process Categories 1, 2, 3, 4, 7, 8a, 8b, 9, 10, 13, 17, 18 Further information on the mapping and allocation of PROC codes is contained in Table 9.1 Environmental Release Categories 4, 7 Specific Environmental Release Category ESVOC SpERC 4.6a.v1 Processes, tasks, activities covered Covers the use of formulated lubricants in closed and open systems including material transfers operations, operation of machinery/engines and similar articles, reworking on reject articles, equipment maintenance and disposal of wastes. Assessment Method See Section 3. Section 2 Operational conditions and risk management measures Section 2.1 Control of worker exposure Product characteristics Physical form of product Liquid Vapour pressure (kPa) Liquid, vapour pressure
Vacuum Gas Oils, Hydrocracked Gas Oils, and Distillate Fuels which are likely to lead to substantial aerosol release, e.g. spraying. E4 General exposures (Closed Handle substance within a closed system E47. systems) CS15 General exposures (Open Provide extract ventilation to points where emissions occur. E54 systems) CS16 Bulk transfers CS14 Handle substance within a closed system E47 Wear suitable gloves tested to EN374 PPE15 Filling preparation of Wear gloves tested to EN374 PPE15 equipment from drums or containers CS45 Initial factory fill of Wear suitable gloves tested to EN374 PPE15 equipment CS75 Operation and lubrication of Provide extract ventilation to points where emissions occur E54 Restrict high energy open area of openings to equipment E68 equipment CS17 Manual roller application or Wear suitable gloves tested to EN374 with specific employee training brushing CS13 PPE17 Treatment of articles by Wear chemically resistant gloves (tested to EN374) PPE15 dipping and pouring CS35 Spraying CS10 Maintenance (of larger plant items) and machine set up CS77 Minimise exposure by enclosing the operation or equipment and provide extract ventilation at openings E60 Wear suitable gloves tested to EN374, coveralls and eye protection PPE23 Ensure material transfers are under containment or extract ventilation E66 Provide extract ventilation to emission points when contact with warm (>50oC) lubricant is likely E67 Wear suitable gloves tested to EN374 PPE15 Wear chemically resistant gloves (tested to EN374) in combination with ‘basic’ employee training PPE16 Wear chemically resistant gloves (tested to EN374) in combination with ‘basic’ employee training PPE16 Maintenance of small items CS18 Re-manufacture of reject articles CS19 Storage CS67 Store substance within a closed system. E84 Additional information on the basis for the allocation of the identified OCs and RMMs is contained in Appendices 2 to 3 Section 2.2 Control of environmental exposure Product characteristics Substance is complex UVCB [PrC3]. Predominantly hydrophobic [PrC4a]. Amounts used Fraction of <strong>EU</strong> tonnage used in region 0.1 Regional use tonnage (tonnes/year) 2.7e4 Fraction of Regional tonnage used locally 0.0036 Annual site tonnage (tonnes/year) 1.0e2 Maximum daily site tonnage (kg/day) 5.0e3 Frequency and duration of use Continuous release [FD2]. Emission days (days/year) 20 Environmental factors not influenced by risk management Local freshwater dilution factor 10 Local marine water dilution factor 100 Other given operational conditions affecting environmental exposure Release fraction to air from process (initial release prior to RMM) 5.0e-3 Release fraction to wastewater from process (initial release prior to 3.0e-6 RMM) Release fraction to soil from process (initial release prior to RMM) 0.001 Technical conditions and measures at process level (source) to prevent release Common practices vary across sites thus conservative process release estimates used [TCS1]. 2010-07-30 CSR 138
Page 1 and 2: EU-SICHERHEITSDATENBLATT gemäß Ve
Page 15 and 16: Vacuum Gas Oils, Hydrocracked Gas O
Page 43: Vacuum Gas Oils, Hydrocracked Gas O
Page 95 and 96:
Vacuum Gas Oils, Hydrocracked Gas O
Page 97 and 98:
Page 99 and 100:
Page 101 and 102:
Page 103 and 104:
Page 105 and 106:
Page 107 and 108:
Page 109 and 110:
Page 111 and 112:
Page 113 and 114:
Page 115 and 116:
Page 117 and 118:
Page 119 and 120:
Page 121 and 122:
Page 123 and 124:
Gas Oils (Vacuum) 4 DNEL (inhalatio
Page 125 and 126:
Industrial - Tabletting, CS100 Indo
Page 127 and 128:
Combined Professional - Manual spra
Page 129 and 130:
Industrial - Bulk transfers CS14 Da
Page 131 and 132:
Professional - Maintenance and CS77
Page 133 and 134:
Note: differentiated Industrial -SU
Page 135 and 136:
Professional - Treatment and dispos
Page 137 and 138:
Industrial - operation of open CS16
Page 139 and 140:
Page 141 and 142:
Page 143 and 144:
Page 145 and 146:
Gas Oils (Vacuum) 4 DNEL (inhalatio
Page 147 and 148:
Industrial - Tabletting, CS100 Indo
Page 149 and 150:
Combined Professional - Manual spra
Page 151 and 152:
Industrial - Bulk transfers CS14 Da
Page 153 and 154:
Professional - Maintenance and CS77
Page 155 and 156:
Note: differentiated Industrial -SU
Page 157 and 158:
Professional - Treatment and dispos
Page 159 and 160:
Industrial - operation of open CS16
Page 161 and 162:
Page 163 and 164:
Page 165 and 166:
This tool is provided for informati
Page 167 and 168:
An Evaluation of the Persistence, B
Page 169 and 170:
Table of Contents Executive Summary
Page 171 and 172:
2.0 Outline of PBT/vPvB Assessment
Page 173 and 174:
3.0 Persistence Assessment of Petro
Page 175 and 176:
100.0 Half-life predicted (days) 10
Page 177 and 178:
2,3-dimethylheptane 9 7.7 6.2 7.4 2
Page 179 and 180:
ioHCwin half-life (days) 10000.0 10
Page 181 and 182:
criterion. It can be concluded that
Page 183 and 184:
Page 185 and 186:
Hydrocarbon C nr BioHCwin Predicted
Page 187 and 188:
ioHCwin half-life (days) 1000000.0
Page 189 and 190:
Page 191 and 192:
Hydrocarbon C nr BioHCwin Predicted
Page 193 and 194:
enzo[a]pyrene 20 421.6 16.5 Table 1
Page 195 and 196:
(see Appendix 2). Since BCF predict
Page 197 and 198:
10000 BCF (Arnot) 1000 100 10 1 n-P
Page 199 and 200:
exhibit BMFs near unity (Figure 28)
Page 201 and 202:
2,2,4,4,6,8,8- heptamethyl nonane 1
Page 203 and 204:
Hydrocarbon C BMF BCF (Arnot) Dieta
Page 205 and 206:
BCF (regression) 100000 10000 1000
Page 207 and 208:
4.5 Polynaphthenic hydrocarbons Reg
Page 209 and 210:
Experimental BMF 10 1 Polynaphth. D
Page 211 and 212:
enzene n-octylbenzene 14 0.034 403
Page 213 and 214:
10000 1000 BCF (Arnot) 100 10 1 NMA
Page 215 and 216:
and appears to be an outlier. This
Page 217 and 218:
4-ethylbiphenyl 14 863 1039 C Yakat
Page 219 and 220:
100000 BCF (regression) 10000 1000
Page 221 and 222:
10 Experimental BMF 1 0.1 NDiAr Die
Page 223 and 224:
Hydrocarbon C BMF Arnot BCF Dietary
Page 225 and 226:
Hydrocarbon C BMF Arnot BCF Dietary
Page 227 and 228:
Acenaphthene Acenaphthylene Benz(a)
Page 229 and 230:
5.0 Summary of Persistence and Bioa
Page 231 and 232:
lower water solubility, it is possi
Page 233 and 234:
properties of petroleum hydrocarbon
Page 235 and 236:
8.0 References Anonymous (2004). Fi
Page 237 and 238:
EMBSI (2007c). Fish, dietary bioacc
Page 239 and 240:
Prince RC, Walters CC. (2007). Biod
Page 241 and 242:
Appendix 1. Hydrocarbon structures
Page 243 and 244:
iP 14 2,4,10-Trimethylundecane CC(C
Page 245 and 246:
MN 7 1,2-Dimethylcyclopentane CC1C(
Page 247 and 248:
MN 14 n-Nonylcyclopentane CCCCCCCCC
Page 249 and 250:
MN 29 MN 29 MN 30 n-Tetracosylcyclo
Page 251 and 252:
hexahydroindane DN 20 2,4-dimethylo
Page 253 and 254:
PN 27 Phenanthrene 2,6-dimethylhept
Page 255 and 256:
MAr 13 1-Methyl-3-hexylbenzene Cc1c
Page 257 and 258:
NMAr 12 n-Propylindan c1ccc2CC(CCC)
Page 259 and 260:
NMAr 24 c1cc(CC(C)CCCC(C)CCCCC)c2CC
Page 261 and 262:
NMAr 29 NMAr 29 NMAr 29 NMAr 29 NMA
Page 263 and 264:
DAr 16 2-Hexylnaphthalene CCCCCCc1c
Page 265 and 266:
NDAr 16 n-Butylacenaphthene c12cccc
Page 267 and 268:
NDAr 26 Dimethyloctyl-1,2,3,6,7,8-
Page 269 and 270:
PAr 19 Ethylbenzo(a)fluorene C3c1cc
Page 271 and 272:
PAr 22 n-Pentylbenzo(a)fluorene C3c
Page 273 and 274:
PAr 28 Isohexyl-octadecahydro-picen
Page 275 and 276:
Appendix 3. CONCAWE Position Paper
Page 277 and 278:
probabilities are adjusted to best
Page 279 and 280:
1.2.2 OASIS LMC Models: Toxicologic
Page 281 and 282:
environmental chemicals (database o
Page 283 and 284:
dihydrodiol. These dihydroxylated i
Page 285 and 286:
Table 1 : PBT assessment of C15 str
Page 287 and 288:
1: The following structures were pr
Page 289 and 290:
Dimitrov SD, Dimitrova N, Mekenyan
Page 291 and 292:
hydrocarbons and azaarenes original
Page 293 and 294:
Verhaar HJM, van Leeuwen CJ, Hermen
Page 295 and 296:
CONCAWE AQUATIC TOXICITY PREDICTION
Page 297 and 298:
CONTENTS (Continued) Section Page 1
Page 299 and 300:
1-2 The model predictions include m
Page 301 and 302:
2-1 SECTION 2 2 SUMMARY OF COMPOSIT
Page 303 and 304:
Page 305 and 306:
Page 307 and 308:
Page 309 and 310:
10-1 SECTION 10 10 SUMMARY OF COMPO
Page 311 and 312:
Page 313 and 314:
Page 315 and 316:
Page 317 and 318:
Page 319:
show all

EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

You also want an ePaper? Increase the reach of your titles

Delete template?

Save as template?