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NSF Forms - Ridge 2000 Program

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There is thus a rich array of problems that can be addressed by detailed study of ELSC samples<br />

that (1) are sampled with the benefit of high resolution side scan and bathymetry and therefore are<br />

very likely to be young and the best candidates to preserve U-series disequilibria; (2) exhibit large<br />

and systematic variations in fluid signature as recorded by U/Th, Ba/La and Pb isotopes, all<br />

pertinent to the investigation and interpretation of U-series data; and (3) have as large variations in<br />

( 238 U/ 232 Th) that correlate with water contents in the northernmost ridge segment ELSC 1, as are<br />

present in the south. Specific problems we will be able to elucidate include:<br />

• Do 226 Ra excesses correlate with Ba/La and Ba/Th for our sample suite? Is the spike in Ba<br />

observed at 21°S associated with an increase in 226 Ra excess? If found, this would be evidence of<br />

control of Ra excess by a subduction component, even in the back-arc. This would provide a new<br />

constraint on the timing hypotheses for Ra excesses, because the back-arc is much farther from a<br />

source of fluids that would lead to correlated Ra and Ba excesses. If such a correlation exists, then<br />

one needs to imagine very rapid transport independent of distance from the volcanic front, which<br />

would be problematic, possibly necessitating alternative models for the Ra excess occurring just<br />

beneath the sites of magmatism. Thus we can test the hypothesis that the Ba- 226 Ra/ 230 Th correlation<br />

should disappear in the back-arc setting, and that back-arc 226 Ra excesses would be associated with<br />

melting column effects as at open ocean ridges.<br />

• U-excesses for the Tonga volcanic front are interpreted as reflecting a processing age in the<br />

mantle wedge of 30,000years. We have a large variation in U/Th in ELSC 1, much farther from the<br />

arc. Do these samples lie on the same trend as the arc, suggesting a mixing origin for all of the<br />

data? Do they show an older apparent age, which might be expected for a longer fluid residence<br />

time with increasing distance form the trench? Are they instead dominated by melting column<br />

processes, and hence show no correlation between U-excess and other indicators of a slab<br />

component, or possibly even show Th excess at the same time as the U-enrichment from a slab<br />

component? Depending on the results, these data will impact the understanding and interpretation of<br />

the apparent ages of fluid transport inferred from arc U-series studies.<br />

• For samples in the north with no apparent slab component, are Th and Ra excesses<br />

consistent with the melting column processes of open ocean ridges, or do they differ, suggesting a<br />

different melting regime environment? This will test the arguments of Kelley et al., [in press] and<br />

Langmuir et al., [in press] for differences in the melting regime in the back-arc as compared to open<br />

ocean environment.<br />

All these interpretations will be furthered by the extensive geochemical data sets obtained on the<br />

same samples. Our sample set combines exceptional spatial and tectonic control with high quality<br />

data from our on-going studies of major elements [Bezos et al., 2004], trace elements [Bezos et al.,<br />

2005], radiogenic isotopes [Escrig et al., 2005], helium isotopes [Goddard et al., 2005] and volatiles<br />

[Michael et al., 2005]. Our proposed work will provide the most exhaustive and complete data set in<br />

a back-arc environment, and may lead to significant new constraints on the interpretation of U-<br />

series data at convergent margins, and our understanding of the nature and timing of formation and<br />

delivery of subduction components to the surface.<br />

We are well aware that one of these questions requires very young samples that preserve their<br />

eruptive 226 Ra disequilibria. Such recent volcanism has often been the case at ocean spreading<br />

centers, and simple geological considerations are supportive of this possibility for our samples as<br />

well. Based on the high-resolution side scan and bathymetry, the precise and short dredge tracks,<br />

and existence of many very well located rock core samples with sufficient glass, we believe that<br />

most sample locations are within the zone of youngest volcanism. Certainly within the areas where<br />

we have SM<strong>2000</strong> bathymetry and where Jason samples were collected, we are within such a very<br />

D-10<br />

0649641

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