13-4 Ligands in Organometallic Chemistry

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13-3 The 18-Electron Rule ; why 18 electrons? s 2 p 6 vs s 2 p 6 d 10 Have to consider types of ligand Strong σ–donor ability of CO Strong π–acceptor ability of CO Good for 18- electron rule
13-3 The 18-Electron Rule ; why 18 electrons? [Zn(en) 3 ] 2+ ; ?? Electron species good σ-donor not as strong as CO e g orbitals are not sufficiently antibonding TiF 6 2- ; ?? Electron species σ-donor π-donor What happen?
Page 1 and 2: Chapter 13 Organometallic Chemistry
Page 3 and 4: 13-1 Historical Background Other ex
Page 5 and 6: 13-1 Historical Background In attem
Page 7 and 8: 13-2 Organic Ligands and Nomenclatu
Page 9: 13-3 The 18-Electron Rule ; countin
Page 13 and 14: 13-3 The 18-Electron Rule ; square-
Page 15 and 16: 13-4 Ligands in Organometallic Chem
Page 33 and 34: 13-4 Bonding between Metal Atoms an
Page 37 and 38: olecular orbital nergy levels of er
Page 43 and 44: 13-5 Fullerene Complexes As ligands
Page 45 and 46: 13-5 Fullerene Complexes Encapsulat
Page 47 and 48: 13-6 Complexes Containing M-C, M=C
Page 53 and 54: 13-6 Spectral Analysis and Characte
Page 59: 13-6 Spectral Analysis and Characte

13-4 Ligands in Organometallic Chemistry

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