13-4 Ligands in Organometallic Chemistry

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13-4 Ligands in Organometallic Chemistry ; carbonyl (CO) complexes Experimental evidence Free CO vs M-CO Infrared spectroscopy and X-ray crystallography Free CO has a C-O stretch at 2143 cm -1 Cr(CO) 6 has a C-O stretch at 2000 cm -1 C-O distance 112.8 pm Metal complexes 115 pm
13-4 Ligands in Organometallic Chemistry ; carbonyl (CO) complexes In general, the more negative the charge on the organometallic species, the greater the tendency of the metal to donate electrons to the π* orbitals of CO and the lower the energy of the C-O stretching vibrations.
Page 1 and 2: Chapter 13 Organometallic Chemistry
Page 3 and 4: 13-1 Historical Background Other ex
Page 5 and 6: 13-1 Historical Background In attem
Page 7 and 8: 13-2 Organic Ligands and Nomenclatu
Page 9 and 10: 13-3 The 18-Electron Rule ; countin
Page 11 and 12: 13-3 The 18-Electron Rule ; why 18
Page 13 and 14: 13-3 The 18-Electron Rule ; square-
Page 15: 13-4 Ligands in Organometallic Chem
Page 19 and 20: 13-4 Ligands in Organometallic Chem
Page 33 and 34: 13-4 Bonding between Metal Atoms an
Page 37 and 38: olecular orbital nergy levels of er
Page 43 and 44: 13-5 Fullerene Complexes As ligands
Page 45 and 46: 13-5 Fullerene Complexes Encapsulat
Page 47 and 48: 13-6 Complexes Containing M-C, M=C
Page 53 and 54: 13-6 Spectral Analysis and Characte
Page 59: 13-6 Spectral Analysis and Characte

13-4 Ligands in Organometallic Chemistry

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