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Operational guidelines and code of practice for stainless steel

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OGCP - Stainless Steel Products – DWI Ref 56.4.477 – APPENDIX<br />

In<strong>for</strong>mation on Stainless Steels<br />

A brief description <strong>of</strong> the nature <strong>and</strong> properties <strong>of</strong> <strong>stainless</strong> <strong>steel</strong>s follows.<br />

What is <strong>stainless</strong> <strong>steel</strong>?<br />

Families <strong>of</strong> <strong>stainless</strong> <strong>steel</strong>s<br />

Why is <strong>stainless</strong> <strong>steel</strong> "<strong>stainless</strong>"?<br />

Corrosion <strong>and</strong> oxidation resistance <strong>of</strong> <strong>stainless</strong> <strong>steel</strong>s<br />

Benefits <strong>and</strong> properties <strong>of</strong> <strong>stainless</strong> <strong>steel</strong>s<br />

Stainless <strong>steel</strong> <strong>and</strong> the environment<br />

More about <strong>stainless</strong> <strong>steel</strong><br />

What is <strong>stainless</strong> <strong>steel</strong>?<br />

"Stainless" is a term coined early in the development <strong>of</strong> these <strong>steel</strong>s <strong>for</strong> cutlery applications. It was<br />

adopted as a generic name <strong>for</strong> these <strong>steel</strong>s <strong>and</strong> now covers a wide range <strong>of</strong> <strong>steel</strong> types <strong>and</strong> grades <strong>for</strong><br />

corrosion or oxidation resistant applications.<br />

Stainless <strong>steel</strong>s are iron alloys with a minimum <strong>of</strong> 10.5% chromium. Other alloying elements are added<br />

to enhance their structure <strong>and</strong> properties such as <strong>for</strong>mability, strength <strong>and</strong> cryogenic toughness. These<br />

include metals such as nickel <strong>and</strong> molybdenum.<br />

The main requirement <strong>for</strong> <strong>stainless</strong> <strong>steel</strong>s is that they should be corrosion resistant <strong>for</strong> a specified<br />

application or environment. The selection <strong>of</strong> a particular "type" <strong>and</strong> "grade" <strong>of</strong> <strong>stainless</strong> <strong>steel</strong> must<br />

initially meet the corrosion resistance requirements. Additional mechanical or physical properties may<br />

also need to be considered to achieve the overall service per<strong>for</strong>mance requirements.<br />

Families <strong>of</strong> <strong>stainless</strong> <strong>steel</strong>s<br />

There are several families <strong>of</strong> <strong>stainless</strong> <strong>steel</strong>: FERRITIC, MARTENSITIC, AUSTENITIC <strong>and</strong><br />

DUPLEX. These names are derived from the crystal structure <strong>of</strong> the <strong>steel</strong>s, which governs their<br />

metallurgical behaviour.<br />

FERRITIC <strong>stainless</strong> <strong>steel</strong>s are magnetic, have a low carbon content <strong>and</strong> contain chromium as the main<br />

alloying element, typically between 13% <strong>and</strong> 17%.. They are not hardenable by heat treatment.<br />

MARTENSITIC <strong>stainless</strong> <strong>steel</strong>s are magnetic, containing typically 12% chromium with a higher carbon<br />

content than the ferritic types. They are hardenable by quenching <strong>and</strong> tempering like plain carbon <strong>steel</strong>s<br />

<strong>and</strong> find their main application in cutlery, aerospace <strong>and</strong> general engineering.<br />

AUSTENITIC <strong>stainless</strong> <strong>steel</strong>s are non-magnetic <strong>and</strong>, in addition to chromium typically around 18%,<br />

contain nickel. This enhances their corrosion resistance <strong>and</strong> modifies the structure from ferritic to<br />

SCI©2002 31<br />

January 2002: Issue 1

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