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Saving the Ozone Layer: Every Action Counts

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chlorine or bromine atoms. These take part in a complex series of<br />

reactions leading to ozone depletion. A simplified version of <strong>the</strong> main<br />

steps in <strong>the</strong> ozone depletion process follows:<br />

* Free chlorine or bromine atoms react with ozone to form chlorine<br />

or bromine monoxide, stealing one oxygen atom and converting<br />

<strong>the</strong> ozone molecule into oxygen.<br />

* Chlorine or bromine monoxide molecules react with free oxygen<br />

atoms, giving up <strong>the</strong>ir ‘stolen’ oxygen atom to form more molecular<br />

oxygen and free chlorine or bromine atoms.<br />

The newly-freed chlorine or bromine atoms start <strong>the</strong> process afresh by<br />

attacking ano<strong>the</strong>r ozone molecule. In this way, every one of <strong>the</strong>se<br />

atoms can destroy thousands of ozone molecules, which is why very<br />

low levels of chlorine and bromine (<strong>the</strong> concentration of chlorine in<br />

<strong>the</strong> stratosphere in 1985 was 2.5 parts per billion) can break down<br />

sufficient ozone to deplete significantly <strong>the</strong> vast ozone layer.<br />

Which chemicals destroy ozone?<br />

A number of man-made chemicals are capable of destroying stratospheric<br />

ozone. They all have two features in common: in <strong>the</strong> lower<br />

atmosphere <strong>the</strong>y are remarkably stable, being largely insoluble in<br />

water and resistant to physical and biological breakdown; and <strong>the</strong>y<br />

contain chlorine or bromine (elements that are extremely reactive<br />

when in a free state) and can <strong>the</strong>refore attack ozone.<br />

For <strong>the</strong>se reasons, ozone-depleting chemicals remain in <strong>the</strong> air for<br />

long periods, and are gradually diffused to all parts of <strong>the</strong> atmosphere,<br />

including <strong>the</strong> stratosphere. Here <strong>the</strong>y are broken down, by<br />

intense high-energy radiation from <strong>the</strong> Sun, freeing ozonedestroying<br />

chlorine or bromine atoms.<br />

Chlorofluorocarbons (CFCs) are <strong>the</strong> most important ozonedestroying<br />

chemicals. CFCs have been used in many ways<br />

since <strong>the</strong>y were first syn<strong>the</strong>sized in 1928. Some examples<br />

are: as a refrigerant in refrigerators and air conditioners;<br />

as a propellant in aerosol spray cans; as a blowing agent<br />

■ 10 ■<br />

<strong>Saving</strong> <strong>the</strong> <strong>Ozone</strong> <strong>Layer</strong>: <strong>Every</strong> <strong>Action</strong> <strong>Counts</strong>

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