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Handbook of Exploration Geochemistry<br />
VOLUME 2<br />
Statistics and Data Analysis<br />
in Geochemical Prospecting<br />
Edited by<br />
R.J. HOWARTH<br />
Reader in Mathematical Geology,<br />
Department of Geology,<br />
Imperial College of Science and Technology, London, U.K.<br />
ELSEVIER SCIENTIFIC PUBLISHING COMPANY<br />
Amsterdam - Oxford - New York '1983
EDITOR'S FOREWORD<br />
The objective of the Handbook of Exploration Geochemistry series is to<br />
present specific aspects of exploration geochemistry in separate volumes in a<br />
form that will be immediately useful to the field geologist practising geochemistry<br />
and, at the same time, to provide a comprehensive review of the<br />
subject that will be a source of reference for research workers. Other titles in<br />
the series presently being prepared are: Rock Geochemistry in Mineral<br />
Exploration; Drainage Geochemistry in Mineral Exploration; Soil Geochemistry<br />
in Mineral Exploration; Biogeochemistry and Geobotany in<br />
Mineral Exploration; and Volatile Elements in Mineral Exploration.<br />
In the editor's foreword to the first volume of the Handbook of Exploration<br />
Geochemistry - Analytical Methods in Geochemical Prospecting - I<br />
stated that the greatest impetus for the progress of exploration geochemistry<br />
had come from the contemporaneous development of rapid, cheap, and<br />
reliable multi-element analytical techniques, coupled with the ready availability<br />
of computers to handle the vastly increased flow of analytical data.<br />
This, the second volume in the series, is devoted entirely to exploration<br />
geochemical data processing and interpretation.<br />
The processing and the interpretation of geochemical data is one of the<br />
most difficult - and one of the most important - stages in the successful<br />
application of exploration geochemistry. Although there are a bewildering<br />
variety of statistical texts that catalogue a vast range of data treatment<br />
techniques, the non-specialist is faced with making a decision concerning<br />
which procedures are appropriate to an individual geochemical problem.<br />
Furthermore, specific geochemical papers in various journals often assume<br />
specialist knowledge, and detailed explanations of actual procedures are<br />
limited. This volume - the only English language book specifically dealing<br />
with exploration geochemical data processing and interpretation - is<br />
intended to overcome these problems. I am pleased that Dr. Richard<br />
Howarth agreed to undertake the rather awesome task of producing this<br />
book, and I am delighted with his success in bringing together so many wellknown<br />
experts in the field.<br />
Adequate space is provided in this volume to digress upon procedures. The<br />
chapters are necessarily of varying degrees of mathematical difficulty, but
VI<br />
the book as a whole should be comprehensible to the modestly numerate<br />
geologist. The step-by-step approach adopted in many chapters, with<br />
extensive illustrations of the effects of various statistical treatments of data,<br />
should allow the exploration geologist to choose an appropriate technique<br />
for most situations.<br />
The organization in Part I takes the reader logically and sequentially<br />
through the normal data handling procedures - from data storage and<br />
retrieval, through control procedures in analysis, univariate analysis, sampling<br />
procedures, and mapping techniques - to the most complicated aspects<br />
of multivariate analysis. Part II consists of reviews of specific techniques and<br />
procedures currently used in various parts of the world. The use of the<br />
computer, an essential practical aid to large data sets and complex statistical<br />
manipulations, is described in detail, but simpler techniques are also<br />
discussed. The graphical aids in the Appendix are unique.<br />
Far too little attention has been devoted in the past to the interpretation<br />
of the geochemical data produced during exploration surveys. This book<br />
should overcome one of the major reasons for this deficiency - the geologist's<br />
lack of the requisite knowledge to use the data. Its pUblication at a<br />
time when microcomputers are becoming widely available should result in a<br />
major increase in the scope and success of geochemical data interpretation,<br />
hopefully with a consequent increase in the discovery rate of mineral<br />
deposits through the use of exploration geochemistry.<br />
G. J. S. GOVETT<br />
Sydney, N.S.W., Australia
CONTENTS<br />
Editor's Foreword . ............. , ........ ~ . . . . . . . . . . . . . . . . . . . . V<br />
Preface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. VII<br />
List of Contributors. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . IX<br />
PART 1. TECHNIQUES OF GEOCHEMICAL DATA PROCESSING AND<br />
INTERPRETATION<br />
Chapter 1. Data storage and retrieval. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 .<br />
T. Mattiske<br />
Introduction. . . . . . . . . . . . . . . . " . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3<br />
Data storage and retrieval systems. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4<br />
Data storage media . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6<br />
Punched cards. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7<br />
Magnetic tape. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7<br />
Disk and drum (mass or random access storage). . . . . . . . . . . . . . . . . . . . . . . 8<br />
Mixed media. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9<br />
Types of data. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 10<br />
Regional reconnaissance data . ....................... , . . . . . . . . .. 10<br />
Local data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 11<br />
Geological data. . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . .. 11<br />
Data.organization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 12<br />
Record types . . . . . . . . . • . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 13<br />
Data files. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 14<br />
Sequential files. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 15<br />
Direct or random access files. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 15<br />
Indexed sequential files . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 16<br />
Inverted files . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 17<br />
Multiple-index files . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 19<br />
Structure of a data storage and retrieval system. . . . . . . . . . . . . . . . . . . . . . . .. 19<br />
Data input and validation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 19<br />
Data storage. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 21<br />
Data retrieval . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 22<br />
Programming considerations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 24<br />
Programming languages. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 24<br />
Aspects of processing and programming. . . . . . . . . . . . . . . . . . . . . . . . . . .. 25<br />
Generalized databa&e systems ... ...................... -. . . . . . . . . . .. 29<br />
Elements of a database system. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 29<br />
The choice of a database package . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 31<br />
Database sytem examples. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 32
XIV<br />
Summary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37<br />
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 37<br />
Chapter 2. Control procedures in geochemical analysis . . . . . . . . . . . . . . . . . .. 39<br />
M. Thompson<br />
Introduction. • . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39<br />
Geochemical analysis and data quality. . . . . . . . . . . . . . . . . . . . . . . . . . . .. 39<br />
The statistical basis of analytical quality control. . . . . . . . . . . . . . . . . . . . . . . . 41<br />
Definitions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41<br />
Deviations from the Normal distribution. . . . . . . . . . . . . . . . . . . . . . . . . .. 44<br />
Variations of accuracy and precision. . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 46<br />
Laboratory control procedures. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 48<br />
Factors that need to be controlled .............................. 48<br />
Control methods that utilize standards . . . . . . . . . . . . . . . . . . . . . . . . . . .. 50<br />
The "statistical series" method. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 52<br />
A scheme for the use of standards. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 53<br />
Methods that do not require special standards. . . . . . . . . . . . . . . . . . . . . . .. 54<br />
Special problems in multi-element analysis. . . . . . . . . . . . . . . . . . . . . . . . .. 57<br />
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 58<br />
Chapter 3. Univariate analysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 59<br />
A. J. Sinclair<br />
Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 59<br />
Central tendency and dispersion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 59<br />
Histograms. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 61<br />
Density distribution. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 62<br />
Fitting a Normal distribution. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 65<br />
Confidence limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 66<br />
Chi-square (X 2 ) goodness-of-fit test. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 66<br />
F- and t-tests. __ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 68<br />
Analysis of variance. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 69<br />
Fixed analysis of variance. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 69<br />
Random analysis of variance (with hierarchical levels of variation) . . . . . . . . .. 71<br />
Group separation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 74<br />
Probability graphs. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 75<br />
References ............... : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 80<br />
Chapter 4. Sampling methodology. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 83<br />
R. G. Garrett<br />
Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 83<br />
Target and sampled populations. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 83<br />
Aims of the sampling programme. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 84<br />
Covariance. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 85<br />
Search techniques . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 88<br />
Grid search. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 88<br />
Random stratified search . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 89<br />
Analysis of variance. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 92<br />
Balanced sampling designs. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 93<br />
Unbalanced sampling designs. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 94<br />
Computational methods for analysis of variance . . . . . . . . . . . . . . . . . . . . .. 95
xv<br />
Strategies for optimum sampling design. . . . . . . . . . , . . . . . . . . . . . . . . . . . .. 100<br />
Pseudo-stratified random sampling. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 102<br />
Map reliability factor. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 102<br />
Number of samples required for anomaly detection. . . . . . . . . . . . . . . . . . .. 104<br />
Conclusion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 105<br />
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 107<br />
Chapter 5. Mapping . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 111<br />
R. J. Howarth<br />
Introduction .............................................. " 111<br />
Types of map ............................................. " 112<br />
Class selection techniques ..................................... " 113<br />
Externally controlled classes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 114<br />
Data-specific classes ....................................... " 114<br />
Serial classes ............................................ " 115<br />
Summary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 119<br />
Point-symbol maps . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 124<br />
Contour maps ............................................. " 127<br />
Trend surface analysis ..................................... " 130<br />
Locally-fitted surfaces. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 135<br />
Zone partitioning methods ............................. ' ..... " 136<br />
Gridding methods. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ... . . .. 136<br />
Three-dimensional views. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 167<br />
Map filtering techniques ...................................... " 169<br />
Low-pass filters. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 171<br />
High-pass filters. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 174<br />
Picture frame filters. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 175<br />
Kolmogorov-Smirnov filter. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 175<br />
Comparison of filters ...................................... " 176<br />
Example applications ...................................... " 178<br />
Discussion ............................................. " 185<br />
Cross-correlation maps ....................................... " 187<br />
Multi-element maps. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 190<br />
Pie diagram . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 191<br />
Proportional line symbols. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 192<br />
Triangular diagrams . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ... 194<br />
Colour theory ........................................... " 196<br />
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 200<br />
Chapter 6. Multivariate analysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 207<br />
R. J. Howarth and R. Binding-Larsen<br />
Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . •. 207<br />
Case study data. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 209<br />
Cluster analysis. . . . . . . . . . . . . . . . . . . . • . . . . . . . . . . . . . . . . . . . . . . . .. 214<br />
Partitioning into k groups ..................................... ' 218<br />
Hierarchical clustering ....................................... ·220<br />
Non-linear mapping. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 222<br />
Goodness of clusters ....................................... , 225<br />
Correlation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 228<br />
Principal components and factor analysis. . . . . . . . . . . . . . . . . . . . . . . . . . . .. 232<br />
Principal components analysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 234
XVI<br />
Rotation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 243<br />
Factor analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . '. . . . . . . . . . . . . . . .. 245<br />
Biplotting methods. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 250<br />
Q-mode factor analysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 253<br />
Partial correlation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 254<br />
Regression. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 255<br />
Canonical correlation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 271<br />
Discriminant analysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 276<br />
Sources of programs. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 283<br />
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 283<br />
PART II. A SELECTION OF GEOCHEMICAL DATA PROCESSING AND<br />
INTERPRETATION METHODS IN USE IN VARIOUS PARTS OF THE<br />
WORLD<br />
Chapter 7. Regression analysis applied to interpretation of geochemical data at the<br />
Geological Survey of Sweden. . . . . . . . . . . . . . . . . . . . . . . . . . . .. 293<br />
O. Selenius<br />
Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 293<br />
Method ................................................... 293<br />
Resulls . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 294<br />
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 301<br />
Chapter 8. Use of pattern classification methods in till geochemistry . . . . . . . . .. 303<br />
N. Gustavsson<br />
Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 303<br />
<strong>Description</strong> of the problem. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 303<br />
Choice of method. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 304<br />
Graphical methods. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 306<br />
Example ............................................... : .. 308<br />
Discussion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 308<br />
Acknowledgements. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 309<br />
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 309<br />
Chapter 9. Geochemical characterization of tin granites in northern Thailand . . .. 311<br />
S. Rehder and G. van den Boom<br />
Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 311<br />
Selection of useful elements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 311<br />
The classification problem ..... ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 314<br />
Definitions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 314<br />
Empirical discriminant analysis: PATREC1 ......................... 315<br />
Determination of an optimal sampling design . . . . . . . . . . . . . . . . . . . . . . . . .. 317<br />
The model. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 317<br />
Algorithms. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 319<br />
Target map calculation in practice . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 321<br />
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 322<br />
Chapter 10. Statistical models for geochemical anomalies . ................. '- 325<br />
R. I. Dubov<br />
Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 325
XVII<br />
Types of models. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 325<br />
The simplest models. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 325<br />
Classification models. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 325<br />
Regression models ......................................... , 327<br />
Rank approximation: basis of the method. . . . . . . . . . . . . . . . . . . . . . . . . . .. 329<br />
Approximation of statistical distributions . . . . . . . . . . . . . . . . . . . . . . . . . . .. 332<br />
Multi-dimensional regression analysis ............................... , 335<br />
Additional remarks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 338<br />
Conclusions ............................................... , 338<br />
Acknowledgements. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 338<br />
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 339<br />
Chapter 11. Mathematical and statistical activity in North America. . . . . . . . . . .. 341<br />
R. J. Garrett<br />
Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 341<br />
Data management. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 342<br />
Search theory. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 342<br />
Sampling and analytical variability. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 342<br />
Univariate statistics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ., 343<br />
Distribution types. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 344<br />
Background and threshold. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 344<br />
Surface fitting .............................................. , 344<br />
Multivariate analysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 345<br />
Regression. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 345<br />
Factor and principal components analysis . . . . . . . . . . . . . . . . . . . . . . . . .. 346<br />
Cluster analysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ., 347<br />
Discriminant analysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 348<br />
Deterministic models . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 348<br />
Discussion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ., 348<br />
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 350<br />
Chapter 12. Geochemical data processing in Western Europe. . . . . . . . . . . . . . .. 361<br />
P. Le¥marie<br />
Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 361<br />
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 365<br />
Chapter 13. Examples of geochemical data processing in Africa. . . . . . . . . . . . .. 369<br />
K. A. Viewing<br />
Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . • . . . . . . . . . . . . . . . . . .. 369<br />
Data processing and the interpretation of geochemical soil sampling results . . . . .. 375<br />
Multi .. lement high·density drainage sampling. . . . . . . . . . . . . . . . . . . . . . . . .. 376<br />
Multi-element drainage reconnaissance on a regional scale. . . . . . . . . . . • . . . . .. 378<br />
Processing and interpretation of airborne geochemical survey data ........... , 383<br />
Acknowledgements. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 384<br />
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 385<br />
Chapter 14. Geochemical data processing in Eastern Europe. . . . . . . . . . . . . . .. 387<br />
V. Nemec<br />
Review ..............................................•.. '.' 387
XVIII<br />
Bibliography. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 388<br />
Appendix. Graphical aids for some statistical tests. . . . . . . . . . . . . . . . . . . . . .. 393<br />
R. J. Howarth<br />
<strong>Description</strong> . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 393<br />
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 401<br />
References Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 403<br />
Subject Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 417