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Handbook of Exploration Geochemistry<br />

VOLUME 2<br />

Statistics and Data Analysis<br />

in Geochemical Prospecting<br />

Edited by<br />

R.J. HOWARTH<br />

Reader in Mathematical Geology,<br />

Department of Geology,<br />

Imperial College of Science and Technology, London, U.K.<br />

ELSEVIER SCIENTIFIC PUBLISHING COMPANY<br />

Amsterdam - Oxford - New York '1983


EDITOR'S FOREWORD<br />

The objective of the Handbook of Exploration Geochemistry series is to<br />

present specific aspects of exploration geochemistry in separate volumes in a<br />

form that will be immediately useful to the field geologist practising geochemistry<br />

and, at the same time, to provide a comprehensive review of the<br />

subject that will be a source of reference for research workers. Other titles in<br />

the series presently being prepared are: Rock Geochemistry in Mineral<br />

Exploration; Drainage Geochemistry in Mineral Exploration; Soil Geochemistry<br />

in Mineral Exploration; Biogeochemistry and Geobotany in<br />

Mineral Exploration; and Volatile Elements in Mineral Exploration.<br />

In the editor's foreword to the first volume of the Handbook of Exploration<br />

Geochemistry - Analytical Methods in Geochemical Prospecting - I<br />

stated that the greatest impetus for the progress of exploration geochemistry<br />

had come from the contemporaneous development of rapid, cheap, and<br />

reliable multi-element analytical techniques, coupled with the ready availability<br />

of computers to handle the vastly increased flow of analytical data.<br />

This, the second volume in the series, is devoted entirely to exploration<br />

geochemical data processing and interpretation.<br />

The processing and the interpretation of geochemical data is one of the<br />

most difficult - and one of the most important - stages in the successful<br />

application of exploration geochemistry. Although there are a bewildering<br />

variety of statistical texts that catalogue a vast range of data treatment<br />

techniques, the non-specialist is faced with making a decision concerning<br />

which procedures are appropriate to an individual geochemical problem.<br />

Furthermore, specific geochemical papers in various journals often assume<br />

specialist knowledge, and detailed explanations of actual procedures are<br />

limited. This volume - the only English language book specifically dealing<br />

with exploration geochemical data processing and interpretation - is<br />

intended to overcome these problems. I am pleased that Dr. Richard<br />

Howarth agreed to undertake the rather awesome task of producing this<br />

book, and I am delighted with his success in bringing together so many wellknown<br />

experts in the field.<br />

Adequate space is provided in this volume to digress upon procedures. The<br />

chapters are necessarily of varying degrees of mathematical difficulty, but


VI<br />

the book as a whole should be comprehensible to the modestly numerate<br />

geologist. The step-by-step approach adopted in many chapters, with<br />

extensive illustrations of the effects of various statistical treatments of data,<br />

should allow the exploration geologist to choose an appropriate technique<br />

for most situations.<br />

The organization in Part I takes the reader logically and sequentially<br />

through the normal data handling procedures - from data storage and<br />

retrieval, through control procedures in analysis, univariate analysis, sampling<br />

procedures, and mapping techniques - to the most complicated aspects<br />

of multivariate analysis. Part II consists of reviews of specific techniques and<br />

procedures currently used in various parts of the world. The use of the<br />

computer, an essential practical aid to large data sets and complex statistical<br />

manipulations, is described in detail, but simpler techniques are also<br />

discussed. The graphical aids in the Appendix are unique.<br />

Far too little attention has been devoted in the past to the interpretation<br />

of the geochemical data produced during exploration surveys. This book<br />

should overcome one of the major reasons for this deficiency - the geologist's<br />

lack of the requisite knowledge to use the data. Its pUblication at a<br />

time when microcomputers are becoming widely available should result in a<br />

major increase in the scope and success of geochemical data interpretation,<br />

hopefully with a consequent increase in the discovery rate of mineral<br />

deposits through the use of exploration geochemistry.<br />

G. J. S. GOVETT<br />

Sydney, N.S.W., Australia


CONTENTS<br />

Editor's Foreword . ............. , ........ ~ . . . . . . . . . . . . . . . . . . . . V<br />

Preface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. VII<br />

List of Contributors. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . IX<br />

PART 1. TECHNIQUES OF GEOCHEMICAL DATA PROCESSING AND<br />

INTERPRETATION<br />

Chapter 1. Data storage and retrieval. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 .<br />

T. Mattiske<br />

Introduction. . . . . . . . . . . . . . . . " . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3<br />

Data storage and retrieval systems. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4<br />

Data storage media . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6<br />

Punched cards. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7<br />

Magnetic tape. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7<br />

Disk and drum (mass or random access storage). . . . . . . . . . . . . . . . . . . . . . . 8<br />

Mixed media. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9<br />

Types of data. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 10<br />

Regional reconnaissance data . ....................... , . . . . . . . . .. 10<br />

Local data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 11<br />

Geological data. . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . .. 11<br />

Data.organization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 12<br />

Record types . . . . . . . . . • . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 13<br />

Data files. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 14<br />

Sequential files. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 15<br />

Direct or random access files. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 15<br />

Indexed sequential files . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 16<br />

Inverted files . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 17<br />

Multiple-index files . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 19<br />

Structure of a data storage and retrieval system. . . . . . . . . . . . . . . . . . . . . . . .. 19<br />

Data input and validation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 19<br />

Data storage. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 21<br />

Data retrieval . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 22<br />

Programming considerations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 24<br />

Programming languages. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 24<br />

Aspects of processing and programming. . . . . . . . . . . . . . . . . . . . . . . . . . .. 25<br />

Generalized databa&e systems ... ...................... -. . . . . . . . . . .. 29<br />

Elements of a database system. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 29<br />

The choice of a database package . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 31<br />

Database sytem examples. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 32


XIV<br />

Summary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37<br />

References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 37<br />

Chapter 2. Control procedures in geochemical analysis . . . . . . . . . . . . . . . . . .. 39<br />

M. Thompson<br />

Introduction. • . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39<br />

Geochemical analysis and data quality. . . . . . . . . . . . . . . . . . . . . . . . . . . .. 39<br />

The statistical basis of analytical quality control. . . . . . . . . . . . . . . . . . . . . . . . 41<br />

Definitions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41<br />

Deviations from the Normal distribution. . . . . . . . . . . . . . . . . . . . . . . . . .. 44<br />

Variations of accuracy and precision. . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 46<br />

Laboratory control procedures. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 48<br />

Factors that need to be controlled .............................. 48<br />

Control methods that utilize standards . . . . . . . . . . . . . . . . . . . . . . . . . . .. 50<br />

The "statistical series" method. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 52<br />

A scheme for the use of standards. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 53<br />

Methods that do not require special standards. . . . . . . . . . . . . . . . . . . . . . .. 54<br />

Special problems in multi-element analysis. . . . . . . . . . . . . . . . . . . . . . . . .. 57<br />

References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 58<br />

Chapter 3. Univariate analysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 59<br />

A. J. Sinclair<br />

Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 59<br />

Central tendency and dispersion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 59<br />

Histograms. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 61<br />

Density distribution. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 62<br />

Fitting a Normal distribution. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 65<br />

Confidence limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 66<br />

Chi-square (X 2 ) goodness-of-fit test. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 66<br />

F- and t-tests. __ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 68<br />

Analysis of variance. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 69<br />

Fixed analysis of variance. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 69<br />

Random analysis of variance (with hierarchical levels of variation) . . . . . . . . .. 71<br />

Group separation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 74<br />

Probability graphs. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 75<br />

References ............... : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 80<br />

Chapter 4. Sampling methodology. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 83<br />

R. G. Garrett<br />

Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 83<br />

Target and sampled populations. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 83<br />

Aims of the sampling programme. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 84<br />

Covariance. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 85<br />

Search techniques . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 88<br />

Grid search. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 88<br />

Random stratified search . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 89<br />

Analysis of variance. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 92<br />

Balanced sampling designs. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 93<br />

Unbalanced sampling designs. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 94<br />

Computational methods for analysis of variance . . . . . . . . . . . . . . . . . . . . .. 95


xv<br />

Strategies for optimum sampling design. . . . . . . . . . , . . . . . . . . . . . . . . . . . .. 100<br />

Pseudo-stratified random sampling. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 102<br />

Map reliability factor. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 102<br />

Number of samples required for anomaly detection. . . . . . . . . . . . . . . . . . .. 104<br />

Conclusion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 105<br />

References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 107<br />

Chapter 5. Mapping . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 111<br />

R. J. Howarth<br />

Introduction .............................................. " 111<br />

Types of map ............................................. " 112<br />

Class selection techniques ..................................... " 113<br />

Externally controlled classes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 114<br />

Data-specific classes ....................................... " 114<br />

Serial classes ............................................ " 115<br />

Summary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 119<br />

Point-symbol maps . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 124<br />

Contour maps ............................................. " 127<br />

Trend surface analysis ..................................... " 130<br />

Locally-fitted surfaces. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 135<br />

Zone partitioning methods ............................. ' ..... " 136<br />

Gridding methods. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ... . . .. 136<br />

Three-dimensional views. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 167<br />

Map filtering techniques ...................................... " 169<br />

Low-pass filters. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 171<br />

High-pass filters. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 174<br />

Picture frame filters. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 175<br />

Kolmogorov-Smirnov filter. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 175<br />

Comparison of filters ...................................... " 176<br />

Example applications ...................................... " 178<br />

Discussion ............................................. " 185<br />

Cross-correlation maps ....................................... " 187<br />

Multi-element maps. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 190<br />

Pie diagram . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 191<br />

Proportional line symbols. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 192<br />

Triangular diagrams . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ... 194<br />

Colour theory ........................................... " 196<br />

References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 200<br />

Chapter 6. Multivariate analysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 207<br />

R. J. Howarth and R. Binding-Larsen<br />

Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . •. 207<br />

Case study data. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 209<br />

Cluster analysis. . . . . . . . . . . . . . . . . . . . • . . . . . . . . . . . . . . . . . . . . . . . .. 214<br />

Partitioning into k groups ..................................... ' 218<br />

Hierarchical clustering ....................................... ·220<br />

Non-linear mapping. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 222<br />

Goodness of clusters ....................................... , 225<br />

Correlation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 228<br />

Principal components and factor analysis. . . . . . . . . . . . . . . . . . . . . . . . . . . .. 232<br />

Principal components analysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 234


XVI<br />

Rotation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 243<br />

Factor analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . '. . . . . . . . . . . . . . . .. 245<br />

Biplotting methods. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 250<br />

Q-mode factor analysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 253<br />

Partial correlation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 254<br />

Regression. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 255<br />

Canonical correlation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 271<br />

Discriminant analysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 276<br />

Sources of programs. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 283<br />

References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 283<br />

PART II. A SELECTION OF GEOCHEMICAL DATA PROCESSING AND<br />

INTERPRETATION METHODS IN USE IN VARIOUS PARTS OF THE<br />

WORLD<br />

Chapter 7. Regression analysis applied to interpretation of geochemical data at the<br />

Geological Survey of Sweden. . . . . . . . . . . . . . . . . . . . . . . . . . . .. 293<br />

O. Selenius<br />

Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 293<br />

Method ................................................... 293<br />

Resulls . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 294<br />

References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 301<br />

Chapter 8. Use of pattern classification methods in till geochemistry . . . . . . . . .. 303<br />

N. Gustavsson<br />

Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 303<br />

<strong>Description</strong> of the problem. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 303<br />

Choice of method. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 304<br />

Graphical methods. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 306<br />

Example ............................................... : .. 308<br />

Discussion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 308<br />

Acknowledgements. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 309<br />

References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 309<br />

Chapter 9. Geochemical characterization of tin granites in northern Thailand . . .. 311<br />

S. Rehder and G. van den Boom<br />

Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 311<br />

Selection of useful elements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 311<br />

The classification problem ..... ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 314<br />

Definitions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 314<br />

Empirical discriminant analysis: PATREC1 ......................... 315<br />

Determination of an optimal sampling design . . . . . . . . . . . . . . . . . . . . . . . . .. 317<br />

The model. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 317<br />

Algorithms. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 319<br />

Target map calculation in practice . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 321<br />

References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 322<br />

Chapter 10. Statistical models for geochemical anomalies . ................. '- 325<br />

R. I. Dubov<br />

Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 325


XVII<br />

Types of models. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 325<br />

The simplest models. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 325<br />

Classification models. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 325<br />

Regression models ......................................... , 327<br />

Rank approximation: basis of the method. . . . . . . . . . . . . . . . . . . . . . . . . . .. 329<br />

Approximation of statistical distributions . . . . . . . . . . . . . . . . . . . . . . . . . . .. 332<br />

Multi-dimensional regression analysis ............................... , 335<br />

Additional remarks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 338<br />

Conclusions ............................................... , 338<br />

Acknowledgements. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 338<br />

References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 339<br />

Chapter 11. Mathematical and statistical activity in North America. . . . . . . . . . .. 341<br />

R. J. Garrett<br />

Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 341<br />

Data management. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 342<br />

Search theory. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 342<br />

Sampling and analytical variability. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 342<br />

Univariate statistics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ., 343<br />

Distribution types. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 344<br />

Background and threshold. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 344<br />

Surface fitting .............................................. , 344<br />

Multivariate analysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 345<br />

Regression. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 345<br />

Factor and principal components analysis . . . . . . . . . . . . . . . . . . . . . . . . .. 346<br />

Cluster analysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ., 347<br />

Discriminant analysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 348<br />

Deterministic models . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 348<br />

Discussion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ., 348<br />

References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 350<br />

Chapter 12. Geochemical data processing in Western Europe. . . . . . . . . . . . . . .. 361<br />

P. Le¥marie<br />

Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 361<br />

References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 365<br />

Chapter 13. Examples of geochemical data processing in Africa. . . . . . . . . . . . .. 369<br />

K. A. Viewing<br />

Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . • . . . . . . . . . . . . . . . . . .. 369<br />

Data processing and the interpretation of geochemical soil sampling results . . . . .. 375<br />

Multi .. lement high·density drainage sampling. . . . . . . . . . . . . . . . . . . . . . . . .. 376<br />

Multi-element drainage reconnaissance on a regional scale. . . . . . . . . . . • . . . . .. 378<br />

Processing and interpretation of airborne geochemical survey data ........... , 383<br />

Acknowledgements. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 384<br />

References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 385<br />

Chapter 14. Geochemical data processing in Eastern Europe. . . . . . . . . . . . . . .. 387<br />

V. Nemec<br />

Review ..............................................•.. '.' 387


XVIII<br />

Bibliography. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 388<br />

Appendix. Graphical aids for some statistical tests. . . . . . . . . . . . . . . . . . . . . .. 393<br />

R. J. Howarth<br />

<strong>Description</strong> . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 393<br />

References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 401<br />

References Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 403<br />

Subject Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 417

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