MATERIAL SAFETY DATA SHEET - Reckitt Benckiser

Print date: 

21-Jan-2010 02-Oct-2009 

MATERIAL SAFETY DATA SHEET 

According to US Regulation ANSI Z400.1-2004 

1. PRODUCT AND COMPANY IDENTIFICATION 

MSDS Number 

Commercial Product Name 

D0224581 

Finish QuantuMatic 

Formula Number: #0249927 

(1616-016) 

NA Formula #1616-016 

UPC Code(s) and Size: Starter Kit: 51700-82402 

051700 1 

Starter Refill12Kit 0 51700 + 24ct: 82403 51700-83298 8 

Starter Refill24Kit 0 51700 + 36ct: 82404 51700-83222 5 

Refill36 0 51700 82411 3 

Refill 12ct: 51700-82403 

Refill 24ct: 51700-82404 

Refill 36ct: 51700-82411 

Refill 48ct: 51700-83318 

Recommended / Intended Use: 

Manufacturer 

Detergent for use in domestic automatic dishwashers - multi-dosage gadget 

Reckitt Benckiser (Poland) SA 

UL Okunin 1, 

05-100 Nowy Dwor, 

Mazowiecki, POLAND. 

Telephone:+48(0)227659500 

FAX: +48 (0) 22 76 59 984 

Distributor: 

Reckitt Benckiser Inc. 

Morris Corporate Center IV 

399 Interpace Parkway (P.O. Box 225) 

Parsippany, New Jersey 07054-0225 

Telephone: +1 973 404 2600 

Reckitt Benckiser (Canada) Inc. 

1680 Tech Avenue, Unit #2 

Mississauga, Ontario L4W 5S9 

CANADA 

Emergency Telephone Number: 

1-800-228-4722 (U.S.) 

1-800-338-6167 (Canada) 

MSDS 

Numbe r 

D0224581 

Version No.: 2 Page 1 of 11

Transportation Emergencies: 



1-800-424-9300 (U.S. & Canada) CHEMTREC 

Outside U.S. and Canada (North America), call Chemtrec:703-527-3887 

2. HAZARDS IDEN TIFICATION 

Emergency Overview 

CAUTION! 

EYE AND SKIN IRRITANT 

MAY BE HARMFUL IF SWALLOWED 

Avoid contact with skin and eyes. 

DO NOT ingest. 

KEEP OUT OF REACH OF CHILDREN 

Contains: Sodium Carbonate, Sodium Silicate, Oxygen based bleaching agents, Carboxylate, Non-ionic surfactants, 

Enzymes 

3. COMPOSITION / IN FORMATION ON IN GREDIEN TS 

Contains: 

Sodium Carbonate 

Sodium Silicate 

Oxygen based bleaching agents 

Carboxylate 

Non-ionic surfactants 

Enzymes 

Chemical Name 

Proportion 

(% w/w) 

ACGIH - Occupational Exposure 

Limits - TWAs 

OSHA PEL 

N,N-bis(carboxymethyl)-alanine, trisodium salt 

164462-16-2 

1,3-Dihydro-1,3-dioxo-2H-isoindole-2- 

hexaneperoxoic acid 

128275-31-0 

Acrylic acid sodium salt polymer, sodium sulfonate 

terminated 

68479-09-4 

Sodium carbonate 

497-19-8 

CETEARETH-25 

68439-49-6 

Sodium Silicate, molar ratio >1.6 -



4. FIRST AID MEASURES 

Inhalation 

Skin Contact 

Eye Contact 

Ingestion 

Notes to Physician 

Protection of First-aiders 

Aggravated Medical Conditions: 

Move to fresh air. If symptoms persist, call a physician. 

If skin irritation persists, call a physician. Rinse immediately with plenty of water for at least 

15 minutes. 

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if 

present and easy to do. Continue rinsing. Consult a physician. 

DO NOT INDUCE VOMITING. Never give anything by mouth to an unconscious person. 

Clean mouth with water and afterwards drink plenty of water. If symptoms persist, call a 

physician or Poison Control Centre immediately. 

Treat symptomatically 

Use personal protective equipment. 

No information available. 

5. FIRE-FIGHTIN G MEASURES 

Flash point: 

Suitable Extinguishing Media: 

Extinguishing media which must not 

be used for safety reasons: 

Unusual hazards: 

>212°F(100°C) 

The product is not flammable. 

All extinguishing media can be used. 

No information available 

None known. 

Special protective equipment for firefighters 

As in any fire, wear self-contained breathing apparatus, pressure-demand, MSHA / NIOSH 

(approved or equivalent) and full protective gear. 

Precautions for fire-fighting 

Standard procedure for chemical fires. 

NFPA: Health Hazard: 2 

Flammability: 0 

Physical Hazard: 0 

HMIS: 

Health Hazard: 2 

Flammability: 0 

Physical Hazard: 0 

Personal Protection: B 

Key: (Also see Sections 3 & 8) 

Validation/Revision Date 

02-Oct-2009 

21-Jan-2010 

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D0224581 

Version No.: 

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6. ACCIDEN TAL RELEASE MEASURES 

Personal Precautions: 

Environmental Precautions: 

Methods for Cleaning Up: 

Methods for Containment: 

Avoidcontactwiththeskinandtheeyes. 

Use personal protective equipment. 

Local authorities should be advised if significant spillages cannot be contained. Do not flush 

with water. 

Clean-up methods - small spillage: 

Take up mechanically and collect in suitable container for disposal. 

Clean contaminated surface thoroughly. 

Clean-up methods - large spillage: 

Large spills should be diked, contained and collected for later disposal according to local, 

provincial, state or federal regulations. 

Prevent further leakage or spillage if safe to do so 

7. HANDLING AND STORAGE 

Handling: 

Storage: 

Wear personal protective equipment 

Ensure adequate ventilation 

Keep tightly closed in a dry and cool place. 

Keep in properly labeled containers. 

Keep away from direct sunlight. 

Keep at temperatures above 0 °C /32°F. 

Keep at temperatures below 40 °C /104°F. 

Protect from water. 

8. EXPOSURE CON TROLS/ PERSON AL PROTECTION 

Chemical Name ACGIH TLV OSHA PEL 

N,N-bis(carboxymethyl)-alanine, trisodium salt 

- - 

164462-16-2 

1,3-Dihydro-1,3-dioxo-2H-isoindole-2- 

- - 

hexaneperoxoic acid 

128275-31-0 

Acrylic acid sodium salt polymer, sodium sulfonate 

- - 

terminated 

68479-09-4 


- 

497-19-8 

CETEARETH-25 

- - 

68439-49-6 




Engineering Controls: 

Environmental exposure controls 

For occupational exposures, ensure adequate ventilation. 

Local authorities should be advised if significant spillages cannot be contained 

Personal Protective Equipment 

Respiratory Protection: 

Eye/Face Protection: 

Hand Protection: 

Skin and Body Protection: 

Hygiene Measures: 

None required under normal usage. 

Tightly fitting safety goggles 

PVC disposable gloves. 

Usual safety precautions while handling the product will provide adequate protection against 

injury or irritation. Follow product label instructions. 

Avoid contact with skin, eyes and clothing. 

9. PHYSICAL AN D CHEMICAL PROPERTIES 

Physical State: 

Appearance: 

Colour: 

Odour: 

Solid. 

Tablet (14 - 17g) - multi-dosage gadget 

White 

Characteristic. 

pH 10.2 -11.0 (10 %) 

Alkaline Reserve [g NaOH/100g] 3.8 

Flash Point: > 100°C / > 212°F 

Flammability Limits in Air: 

Autoignition Temperature: 

Specific Gravity / Density [g/mL]: 

Vapour Pressure: 

Solubility: 



No data available. 

Not determined. 

soluble in water (300g/L). 

- upper: No data available 

-lower: 

No data available 


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10. STABILITY AN D REACTIVITY 

Stability: 

Conditions to Avoid: 

Materials to Avoid: 

Stable under recommended storage conditions. 

Extremes of temperature and direct sunlight. 

Temperatures below 0 °C /32°Fabove40°C /104°F 

Protect against water 

Do not mix with other household chemicals 

Hazardous Decomposition Products: Oxides of carbon and unknown organic compounds. 

Polymerization: 

Hazardous polymerization does not occur. 


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11. TOXICOLOGICAL IN FORMATION 

PRODUCT TOXICITY DATA 

LD 50 Oral: 

LD50 Dermal: 

LC 50 Inhalation (Dust): 

LC 50 Inhalation (Vapor): 

2605 mg/kg (rat) estimated 

>2000 mg/kg (rat) estimated 



ACUTE EFFECTS:: 

Eye Irritation 

Skin Irritation 

Inhalation 

Ingestion 

Sensitization 

Severe eye irritation 

May cause skin irritation. 

None expected during normal conditions of use. 

Health injuries are not known or expected under normal use. 

Not expected to be a skin sensitiser. 

Specific Effects 

Carcinogenic Effects: 

Mutagenic Effects 

Reproductive Toxicity: 

Additional Toxicity Information: 

Not listed as carcinogenic by OSHA, NTP or IARC. 



Information is based on available component data and toxicity result of similar products. 

COMPONENT TOXICITY DATA 

Chemical Name CAS-No LD50 Oral - with units 

-Rat-mg/kg 

LD50 Dermal - With 

Units - Rat/Rabbit - 

mg/kg 

N,N-bis(carboxymethyl)-alanine, trisodium salt 164462-16-2 >2000mg/kg (rat) 

Sodium carbonate 497-19-8 4090 mg/kg ( Rat ) 

CETEARETH-25 68439-49-6 1260 mg/kg ( Rat ) 




12. ECOLOGICAL INFORMATION 

PRODUCT TOXICITY DATA 

Ecotoxicity effects 

Aquatic toxicity: 


COMPONENT TOXICITY DATA 


497-19-8 (5 - 10 %) 

Freshwater Algae 

Freshwater Fish 

Water Flea 

EC50 = 242 mg/L 120 h 

LC50 = 300 mg/L Lepomis macrochirus 96 h 

EC50 = 265 mg/L 48 h 


General remarks 

DOT 

TDG 

MEX 

ICAO 

IATA 

IMDG/IMO 

RID 

ADR 

ADN 



14. TRANSPORT INFORMATION 

Not classified as dangerous in the meaning of transport regulations. For long distance 

transport of bulk material or shrunk pallet take into consideration sections 7 and 10. 

Not regulated 

Not regulated 

Not applicable. 

Not regulated 

Not regulated 

Not regulated 




15. REGULATORY IN FORMATION 

Chemical Name PICCS TSCA DSL NDSL ENCS CHINA AICS EINECS/ 

ELINCS 

N,N-bis(carboxymethyl)-alanine, 

P X X None 

trisodium salt 

1,3-Dihydro-1,3-dioxo-2H-isoindole- 

confidential x X X 410-850-8 

2-hexaneperoxoic acid 

Acrylic acid sodium salt polymer, 

XU X X X not 

sodium sulfonate terminated 

available 

Sodium carbonate Present Present X X X X 207-838-8 

CETEARETH-25 XU X X X not 

available 

Sodium Silicate, molar ratio >1.6 - 

Present X X X X 215-687-4 



U.S. Regulations: 

N,N-bis(carboxymethyl)-alanine, trisodium salt - 164462-16-2 

NJRTK 

Not Listed. 

Appearance 

None. 

SARA313 

None 

California Prop. 65 

Not Listed 

1,3-Dihydro-1,3-dioxo-2H-isoindole-2-hexaneperoxoic acid - 128275-31-0 

NJRTK 

Not Listed. 

Appearance 

None. 

SARA313 

None 


Not Listed 

Acrylic acid sodium salt polymer, sodium sulfonate terminated - 68479-09-4 

NJRTK 

Not Listed. 

Appearance 

None. 

SARA313 

None 


Not Listed 

Sodium carbonate - 497-19-8 

NJRTK 

Not Listed. 

Appearance 

Grayish-w hite pow der or lumps 

SARA313 

None 


Not Listed 

CETEARETH-25 - 68439-49-6 

NJRTK 

Not Listed. 

Appearance 

None. 

SARA313 

None 


Not Listed 




16. OTHER INFORMATION 

National Fire 

Protection Association 

(U.S.A.): 

HMIS (U.S.A.): 

Health Hazard 

Flammability: 

2 

0 

Physical hazards 0 

PERSONAL PROTECTION 

B 

Reason for revision: 

Additional advice: 

Prepared by: 

Inclusion of UPC codes 

This product should only be used as directed on the label and for the purpose intended. 

Regulatory, Department Safety and Environmental Services 

RSE Dishwashing 

Reckitt Benckiser Produktions GmbH 

Benckiserplatz 1 

D-67059 Ludwigshafen am Rhein 

Germany 

Phone: +49 (0) 621 59146-0 

Fax: +49 (0) 621 59146-398 

eMail: rse-lu@reckittbenckiser.com 

To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of 

its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final 

determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and 

should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards 

that exist. 


21-Jan-2010 

02-Oct-2009 

MSDS Numbe r 

D0224581 

Version No.: 

2 



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MATERIAL SAFETY DATA SHEET - Reckitt Benckiser

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