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SAFETY DATA SHEET - Reckitt Benckiser

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Print date:<br />

16-Jun-2011<br />

<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

According to US Standard ANSI Z400.1-2004<br />

1. PRODUCT AND COMPANY IDENTIFICATION<br />

SDS Number:<br />

Commercial Product Name:<br />

D0351165<br />

Resolve All Stains<br />

Formula Number: 0315031<br />

Recommended use<br />

Manufacturer:<br />

Fabric Treatment<br />

<strong>Reckitt</strong> <strong>Benckiser</strong><br />

30 Arrowhead Industrial Blvd.<br />

St. Peters, Missouri 63376<br />

USA<br />

Distributor:<br />

<strong>Reckitt</strong> <strong>Benckiser</strong> LLC.<br />

Morris Corporate Center IV<br />

399 Interpace Parkway (P.O. Box 225)<br />

Parsippany, New Jersey 07054-0225<br />

Telephone: +1 973 404 2600<br />

Emergency Telephone Number:<br />

Transportation Emergencies:<br />

1-800-228-4722 (U.S)<br />

1-800-424-9300 (U.S. & Canada) CHEMTREC<br />

Outside U.S. and Canada (North America), call Chemtrec:703-527-3887<br />

SDS Number: D0351165<br />

Version No.: 1 Page 1 of 9


<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

According to US Standard ANSI Z400.1-2004<br />

2. HAZARDS IDENTIFICATION<br />

Emergency Overview<br />

- DANGER!<br />

Corrosive<br />

to eyes<br />

May be harmful if swallowed<br />

Irritating to skin<br />

KEEP OUT OF REACH OF CHILDREN<br />

3. COMPOSITION/INFORMATION ON INGREDIENTS<br />

Chemical Name<br />

Proportion<br />

(% w /w )<br />

ACGIH - Occupational<br />

Exposure Limits - TWAs<br />

OSHA PEL<br />

Alcohol C12-16 Ethoxylates 7EO<br />

68551-12-2<br />

Sodium 2-dodecylbenzenesulfonate<br />

25155-30-0<br />

Hydrogen peroxide<br />

7722-84-1<br />

Alcohols, C12-16, ethoxylated 3EO<br />

68551-12-2<br />

10 - 15 %<br />

5 - 10 %<br />

1 - 5 % = 1 ppm TWA 1 322 1<br />

Hydrogen peroxide<br />

< 2.5 %<br />

TWA: 1 ppm<br />

TWA: 1.4 mg/m3<br />

4. FIRST AID MEASURES<br />

Inhalation<br />

Move to fresh air.<br />

Skin Contact<br />

Eye Contact<br />

Ingestion<br />

Notes to Physician<br />

Protection of First-aiders<br />

Wash off immediately with soap and plenty of water removing all contaminated clothes and<br />

shoes. If skin irritation persists, call a physician.<br />

If in eyes, IMMEDIATELY rinse eyes with water. Remove any contact lenses and continue<br />

rinsing eyes for at least 15 minutes. Call a physician immediately.<br />

If swallowed, promptly drink a large quantity of water. DO NOT induce vomiting! Contact a<br />

Physician or Poison Control Center immediately.<br />

Treat symptomatically<br />

Use personal protective equipment.<br />

Validation/Revision Date<br />

16-Jun-2011<br />

SDS Number:<br />

D0351165<br />

Version No.:<br />

1<br />

Commercial Product Name:<br />

Resolve All Stains<br />

Page 2 of 9


<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

According to US Standard ANSI Z400.1-2004<br />

5. FIRE-FIGHTING MEASURES<br />

Flash point: See section 9<br />

Suitable Extinguishing Media:<br />

Unsuitable Extinguishing media:<br />

Special protective equipment for firefighters<br />

Precautions for fire-fighting<br />

As suitable for surrounding fire.<br />

No information available<br />

In the event of fire, wear self-contained breathing apparatus.<br />

Standard procedure for chemical fires.<br />

NFPA:<br />

Health Hazard: 2<br />

Flammability: 0<br />

Instability / Reactivity 0<br />

Special: --<br />

HMIS: Health Hazard: 2 Flammability: 0<br />

Key: (Also see Sections 3 & 8)<br />

Physical Hazard: 0<br />

Personal Protection: A<br />

6. ACCIDENTAL RELEASE MEASURES<br />

Personal Precautions:<br />

Environmental Precautions:<br />

Methods for Cleaning Up:<br />

Methods for Containment:<br />

Use personal protective equipment.<br />

Evacuate personnel to safe areas<br />

Keep people away from and upwind of spill/leak<br />

Do not flush with water. Local authorities should be advised if significant spillages cannot be<br />

contained.<br />

Soak up with inert absorbent material<br />

Dam up<br />

Pick up and transfer to properly labeled containers<br />

Prevent further leakage or spillage if safe to do so<br />

7. HANDLING AND STORAGE<br />

Handling:<br />

Storage:<br />

Handle in accordance with good industrial hygiene and safety practice<br />

Avoid contact with skin and eyes<br />

Keep out of the reach of children.<br />

Keep at temperatures below 40°C<br />

Keep container tightly closed in a dry and well-ventilated place<br />

8. EXPOSURE CONTROLS/PERSONAL PROTECTION<br />

Chemical Name ACGIH TLV OSHA PEL<br />

Alcohol C12-16 Ethoxylates 7EO<br />

- -<br />

68551-12-2<br />

Sodium 2-dodecylbenzenesulfonate<br />

- -<br />

25155-30-0<br />

Hydrogen peroxide<br />

7722-84-1<br />

TWA: 1 ppm<br />

TWA: 1 ppm<br />

TWA: 1.4 mg/m3<br />

Alcohols, C12-16, ethoxylated 3EO<br />

68551-12-2<br />

- -<br />

Validation/Revision Date<br />

16-Jun-2011<br />

SDS Number:<br />

D0351165<br />

Version No.:<br />

1<br />

Commercial Product Name:<br />

Resolve All Stains<br />

Page 3 of 9


<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

According to US Standard ANSI Z400.1-2004<br />

Engineering Controls:<br />

Environmental exposure controls<br />

For occupational exposures, ensure adequate ventilation.<br />

Local authorities should be advised if significant spillages cannot be contained<br />

Personal Protective Equipment<br />

Respiratory Protection:<br />

Eye/Face Protection:<br />

Hand Protection:<br />

Skin and Body Protection:<br />

Hygiene Measures:<br />

None required under normal usage.<br />

Tightly fitting safety goggles<br />

Face-shield<br />

Long sleeved clothing<br />

Apron<br />

Impervious gloves.<br />

Usual safety precautions while handling the product will provide adequate protection against<br />

injury or irritation. Follow product label instructions.<br />

Avoid contact with eyes, skin, and clothing.<br />

9. PHYSICAL AND CHEMICAL PROPERTIES<br />

Physical State:<br />

Appearance:<br />

Colour:<br />

Odour:<br />

Liquid.<br />

Liquid.<br />

Blue<br />

Characteristic.<br />

pH 3.5 +/- 0.3<br />

Flammability Limits in Air:<br />

Autoignition Temperature:<br />

No information available<br />

No information available.<br />

Specific Gravity / Density [g/mL]: 1.02 +/- 0.05<br />

Vapour pressure:<br />

Solubility:<br />

not determined.<br />

No information available.<br />

- upper: Not available<br />

- lower: Not available<br />

Validation/Revision Date<br />

16-Jun-2011<br />

SDS Number:<br />

D0351165<br />

Version No.:<br />

1<br />

Commercial Product Name:<br />

Resolve All Stains<br />

Page 4 of 9


<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

According to US Standard ANSI Z400.1-2004<br />

10. STABILITY AND REACTIVITY<br />

Stability:<br />

Conditions to Avoid:<br />

Materials to Avoid:<br />

Stable under recommended storage conditions.<br />

Store away from excessive heat and moisture<br />

Do not mix with bleach or other household chemicals. Incompatible with strong acids and<br />

bases.<br />

Hazardous Decomposition Products: Oxides of carbon and unknown organic compounds.<br />

Polymerization:<br />

Hazardous polymerization does not occur.<br />

11. TOXICOLOGICAL INFORMATION<br />

PRODUCT TOXICITY <strong>DATA</strong><br />

LD50 Oral:<br />

LD50 Dermal:<br />

LC50 Inhalation (Dust):<br />

LC50 Inhalation (Vapor):<br />

ACUTE EFFECTS<br />

Eye Irritation<br />

Skin Irritation<br />

Inhalation<br />

Ingestion<br />

Sensitization<br />

>2000 mg/kg (rat) estimated<br />

>2000 mg/kg (rat) estimated<br />

No information available<br />

8 ml/m 3 (vapor) estimated<br />

None expected during normal conditions of use.<br />

Corrosive liquid.<br />

Irritating to skin.<br />

None expected during normal conditions of use.<br />

May be harmful if swallowed.<br />

Not expected to be a skin sensitiser.<br />

Specific Effects<br />

Carcinogenic Effects:<br />

Mutagenic Effects<br />

Reproductive Toxicity:<br />

Additional Toxicity Information:<br />

Not listed as carcinogenic by OSHA, NTP or IARC.<br />

No information available.<br />

No information available.<br />

Information is based on available component data and toxicity result of similar products.<br />

COMPONENT TOXICITY <strong>DATA</strong><br />

Chemical Name CAS-No LD50 Oral - w ith units<br />

- Rat - mg/kg<br />

LD50 Dermal - With<br />

Units - Rat/Rabbit -<br />

mg/kg<br />

LC50 Inhalation -<br />

With units -<br />

Rat/Rabbit<br />

Alcohol C12-16 Ethoxylates 7EO 68551-12-2 no data available no data available no data available<br />

Sodium 2-dodecylbenzenesulfonate 25155-30-0 438 mg/kg ( Rat ) no data available no data available<br />

Hydrogen peroxide 7722-84-1 801 mg/kg ( Rat ) 4060 mg/kg ( Rat ) 2 mg/L ( Rat ) 4 h<br />

Alcohols, C12-16, ethoxylated 3EO 68551-12-2 no data available no data available no data available<br />

Validation/Revision Date<br />

16-Jun-2011<br />

SDS Number:<br />

D0351165<br />

Version No.:<br />

1<br />

Commercial Product Name:<br />

Resolve All Stains<br />

Page 5 of 9


<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

According to US Standard ANSI Z400.1-2004<br />

12. ECOLOGICAL INFORMATION<br />

PRODUCT TOXICITY <strong>DATA</strong><br />

Aquatic toxicity:<br />

No information available<br />

COMPONENT TOXICITY <strong>DATA</strong><br />

Sodium 2-dodecylbenzenesulfonate<br />

25155-30-0 (5 - 10 %)<br />

Freshwater Fish<br />

Hydrogen peroxide<br />

7722-84-1 (1 - 5 %)<br />

Freshwater Algae<br />

Freshwater Fish<br />

Water Flea<br />

LC50 96 h Oncorhynchus mykiss 10.8 mg/L<br />

EC50 72 h 2.5 mg/L<br />

LC50 96 h Pimephales promelas 16.4 mg/L<br />

LC50 96 h Lepomis macrochirus 18-56 mg/L<br />

LC50 96 h Oncorhynchus mykiss 10.0-32.0 mg/L<br />

EC50 24 h 7.7 mg/L<br />

EC50 48 h 18 - 32 mg/L<br />

Other Information<br />

Ozone depletion potential; ODP;<br />

(R-11 = 1)<br />

Global Warming Potential (GWP):<br />

Additional Ecological Information:<br />

No information available.<br />

No information available.<br />

Information given is based on data on the components and the<br />

ecotoxicology of similar products.<br />

13. DISPOSAL CONSIDERATIONS<br />

Waste from residues / unused<br />

products:<br />

Contaminated Packaging:<br />

Dispose of in accordance with local regulations.<br />

Empty container can be disposed of as household trash or rinsed and recycled where<br />

appropriate.<br />

Waste Disposal:<br />

Dispose of according to Local, State, Provincial and / or Federal regulations.<br />

Validation/Revision Date<br />

16-Jun-2011<br />

SDS Number:<br />

D0351165<br />

Version No.:<br />

1<br />

Commercial Product Name:<br />

Resolve All Stains<br />

Page 6 of 9


General remarks<br />

DOT<br />

TDG<br />

MEX<br />

ICAO<br />

IATA<br />

IMDG / IMO<br />

RID<br />

ADR<br />

ADN<br />

<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

According to US Standard ANSI Z400.1-2004<br />

14. TRANSPORT INFORMATION<br />

For long distance transport of bulk material or shrunk pallet take into consideration<br />

sections 7 and 10.<br />

Not regulated<br />

Not regulated<br />

Not applicable.<br />

Not regulated<br />

Not regulated<br />

Not regulated<br />

Not applicable.<br />

Not applicable.<br />

Not applicable.<br />

15. REGULATORY INFORMATION<br />

Chemical Name PICCS TSCA DSL NDSL ENCS CHINA AICS EINECS/<br />

ELINCS<br />

Alcohol C12-16 Ethoxylates 7EO XU X X X None<br />

Sodium 2-dodecylbenzenesulfonate Present X X X X 246-680-4<br />

Hydrogen peroxide Present X X X X 231-765-0<br />

Alcohols, C12-16, ethoxylated 3EO XU X X X None<br />

South Africa<br />

STELs<br />

Validation/Revision Date<br />

16-Jun-2011<br />

SDS Number:<br />

D0351165<br />

Version No.:<br />

1<br />

Commercial Product Name:<br />

Resolve All Stains<br />

Page 7 of 9


<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

According to US Standard ANSI Z400.1-2004<br />

U.S. Regulations:<br />

Alcohol C12-16 Ethoxylates 7EO - 68551-12-2<br />

NJRTK<br />

Not Listed.<br />

Appearance<br />

None.<br />

SARA313<br />

None<br />

California Prop. 65<br />

Not Listed<br />

Sodium 2-dodecylbenzenesulfonate - 25155-30-0<br />

NJRTK<br />

X<br />

Appearance<br />

None.<br />

SARA313<br />

None<br />

California Prop. 65<br />

Not Listed<br />

Hydrogen peroxide - 7722-84-1<br />

NJRTK<br />

X<br />

Appearance<br />

Colorless liquid<br />

SARA313<br />

None<br />

California Prop. 65<br />

Not Listed<br />

Alcohols, C12-16, ethoxylated 3EO - 68551-12-2<br />

NJRTK<br />

Not Listed.<br />

Appearance<br />

None.<br />

SARA313<br />

None<br />

California Prop. 65<br />

Not Listed<br />

WHMIS (Canada)<br />

WHMIS Hazard Class<br />

Not determined<br />

Validation/Revision Date<br />

16-Jun-2011<br />

SDS Number:<br />

D0351165<br />

Version No.:<br />

1<br />

Commercial Product Name:<br />

Resolve All Stains<br />

Page 8 of 9


<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

According to US Standard ANSI Z400.1-2004<br />

16. OTHER INFORMATION<br />

National Fire<br />

Protection Association<br />

(U.S.A.):<br />

HMIS (U.S.A.):<br />

Health Hazard<br />

Flammability:<br />

2<br />

0<br />

Physical hazards 0<br />

Personal Protection<br />

A<br />

Reason for revision:<br />

Additional advice:<br />

Prepared by:<br />

Update or revision of the PSDS.<br />

This product should only be used as directed on the label and for the purpose intended.<br />

<strong>Reckitt</strong> Bencksier Italia SpA<br />

Via Spadolini 7, 20141 Milano<br />

Tel ++39 02 84475322<br />

Fax ++39 0284475493<br />

To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of<br />

its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final<br />

determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and<br />

should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards<br />

that exist.<br />

Validation/Revision Date<br />

16-Jun-2011<br />

SDS Number:<br />

D0351165<br />

Version No.:<br />

1<br />

Commercial Product Name:<br />

Resolve All Stains<br />

Page 9 of 9

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