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Turbomachinery for Nitric Acid Plants - MAN Diesel & Turbo

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This procedure ensures optimum,<br />

gentle cleaning of the flow channel and<br />

has little influence on the process mass<br />

flow rate as only small quantities of<br />

water are injected.<br />

The poisonous effect of nitrous gas<br />

makes it necessary to prevent any escape<br />

of gas from the compressor. This<br />

requirement is met as folIows:<br />

Double sealing chambers are provided<br />

at the main shaft in the casing.<br />

The inboard chambers are fed with<br />

sealing air (from the discharge of<br />

the air compressor), while the outboard<br />

chambers are provided with a<br />

connection to atmosphere. This is led<br />

outside the machine house in case<br />

any leakage does arise. The ingress<br />

of NO-gas into the lube-oil circuit is<br />

prevented by an additional sealing<br />

chamber in each bearing housing<br />

of the machine train.<br />

A special sealing agent is applied<br />

at the horizontal joint flanges of the<br />

casing. In addition, the casing joint<br />

bolts are tightened at an exactly<br />

defined <strong>for</strong>ce by means of a hydraulic<br />

tightening device.<br />

All parts in contact with the gas are<br />

made of acid resistant CrNi steel to<br />

counteract the corrosive effect of the<br />

nitrous gases. The chemical reactions<br />

that occur during compression have to<br />

be taken into account when designing<br />

such a compressor. These reactions<br />

are the dissociation of N2O4 to NO2 and<br />

to a much lesser degree and the<br />

oxidation of NO to NO2. The latter<br />

reaction causes heat to be released,<br />

whereas <strong>for</strong> dissociation considerable<br />

amounts of heat are needed. In<br />

designing the compressor, these heat<br />

quantities/temperature changes are<br />

determined stage by stage and considered<br />

when sizing the flow channel<br />

sections.<br />

Nitrous-gas compressor<br />

11

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