Turbomachinery for Nitric Acid Plants - MAN Diesel & Turbo
Turbomachinery for Nitric Acid Plants - MAN Diesel & Turbo
Turbomachinery for Nitric Acid Plants - MAN Diesel & Turbo
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This procedure ensures optimum,<br />
gentle cleaning of the flow channel and<br />
has little influence on the process mass<br />
flow rate as only small quantities of<br />
water are injected.<br />
The poisonous effect of nitrous gas<br />
makes it necessary to prevent any escape<br />
of gas from the compressor. This<br />
requirement is met as folIows:<br />
Double sealing chambers are provided<br />
at the main shaft in the casing.<br />
The inboard chambers are fed with<br />
sealing air (from the discharge of<br />
the air compressor), while the outboard<br />
chambers are provided with a<br />
connection to atmosphere. This is led<br />
outside the machine house in case<br />
any leakage does arise. The ingress<br />
of NO-gas into the lube-oil circuit is<br />
prevented by an additional sealing<br />
chamber in each bearing housing<br />
of the machine train.<br />
A special sealing agent is applied<br />
at the horizontal joint flanges of the<br />
casing. In addition, the casing joint<br />
bolts are tightened at an exactly<br />
defined <strong>for</strong>ce by means of a hydraulic<br />
tightening device.<br />
All parts in contact with the gas are<br />
made of acid resistant CrNi steel to<br />
counteract the corrosive effect of the<br />
nitrous gases. The chemical reactions<br />
that occur during compression have to<br />
be taken into account when designing<br />
such a compressor. These reactions<br />
are the dissociation of N2O4 to NO2 and<br />
to a much lesser degree and the<br />
oxidation of NO to NO2. The latter<br />
reaction causes heat to be released,<br />
whereas <strong>for</strong> dissociation considerable<br />
amounts of heat are needed. In<br />
designing the compressor, these heat<br />
quantities/temperature changes are<br />
determined stage by stage and considered<br />
when sizing the flow channel<br />
sections.<br />
Nitrous-gas compressor<br />
11