Alpha Fenpropidin 750EC

U
MATERIAL SAFETY DATA SHEET
Page : 1 of 4
Revised edition no : 1
Date : 9/2/2006
Supersedes : 0/0/0
ALPHA FENPROPIDIN 750 EC R-18958
1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING
Trade name
Chemical formula
Chemical description
Use
Company identification
Emergency phone nr
: ALPHA FENPROPIDIN 750 EC
: Fenpropidin : C19H31N
: Fenpropidin : (RS)-1-[3-(4-tert-butylphenyl)-2-methylpropyl]piperidine
: Fungicide
: Makhteshim Chemical Works Ltd.
PO Box 60
Beer Sheva 84100 Israel.
Fax : +972-8-6296848
: 972-3-6106666 Subscription no. 36789 (Makhteshim)
2. COMPOSITION / INFORMATION ON INGREDIENTS
This product is considered to be hazardous and contains hazardous components.
Substance name Value(s) CAS No EC No Index No Classification
Fenpropidin : 70 - 90 % 67306-00-7 ----- ----- Xn; R20/22
Xi; R36/38
R43
N; R50-53
Tridecylalcoholethoxylatephosphate : < 10 % 73038-25-2 ----- ----- Xi; R38-41
Fatty alcohol ethoxylate : < 5 % 78330-21-9 ----- ----- Xn; R22
Xi; R41
Solvesso 200 : < 10 % 64742-94-5 265-198-5 649-424-00-3 Xn; R65
3. HAZARDS IDENTIFICATION
Human Health Hazards
Environmental hazard
: Harmful by inhalation, in contact with skin and if swallowed
Risk of serious damage to eyes.
: Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
4. FIRST AID MEASURES
First aid
Inhalation
Ingestion
Skin contact
Eye contact
Note to physician
: Remove victim to fresh air. Keep victim warm and at rest. If breathing is difficult,
give oxygen. If not breathing, give artificial respiration. Immediately get medical
attention.
: Do not induce vomiting. Wash out mouth with plenty of water. Never give anything
by mouth to an unconscious person. If breathing is difficult, give oxygen. If not
breathing, give artificial respiration. Immediately get medical attention.
: Remove contaminated clothing and shoes. Wash off with plenty of water and soap.
Consult a doctor in the event of any complaints.
: Wash out with plenty of water with the eyelid held wide open. Consult an eye
specialist.
: No specific antidote known. Treat symptomatically and give supportive therapy.
5. FIRE-FIGHTING MEASURES
Extinguishing media : Avoid use of water jet. Water spray , foam , CO2, dry chemical .
Special procedures
: Fight fires from a protected location . Dike fire control water for later disposal.
Special exposure hazards
: Thermal decomposition may generate : toxic fumes , carbon dioxide , carbon
monoxide , nitrogen oxides , NH3.
Protection against fire
: Wear suitable protective clothing Self-contained breathing apparatus.
Makhteshim Chemical Works Ltd.
PO Box 60 Beer Sheva 84100 Israel.
Fax : +972-8-6296848

U
MATERIAL SAFETY DATA SHEET
Page : 2 of 4
Revised edition no : 1
Date : 9/2/2006
Supersedes : 0/0/0
ALPHA FENPROPIDIN 750 EC R-18958
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Environmental precautions
After spillage and/or leakage
: Use appropriate protection (see section 8). Avoid contact with skin and eyes. Do
not breathe fumes .
: Dispose of this material and its container at hazardous or special waste collection
point, In accordance with national and regional regulations . If the product has
contaminated surface water, inform the appropriate authorities. Contaminated soil
layers have to be dug out.
: In the event of minor spillage: Absorb in sand or other inert material . Use
appropriate container to avoid environmental contamination.
In the event of major spillage: Collect and contain as much free liquid as possible.
Dike spills using absorbent or impervious materials such as sand or clay for later
disposal. Do not discharge into the environment . Do not empty into drains .
7. HANDLING AND STORAGE
Handling
Storage
: Do not breathe fumes . Use only in well ventilated areas. . Avoid contact with skin
and eyes. When using, do not eat, drink or smoke. Wash hands thoroughly after
handling.
: Keep locked up . Keep container tightly closed. Keep container dry. Keep only in
the original container in a cool, well ventilated place. Avoid : strong oxidizing agents
, direct sunlight . Storage temperature : 0 - 35 °C
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Industrial hygiene
: Facilities storing or utilizing this material should be equipped with an eyewash
facility and safety shower . Wash hands thoroughly after handling. Wash clothing
before re-using.
Occupational Exposure Limits
- Respiratory protection : During spraying wear suitable respiratory equipment. (Filter A2P2)
- Skin protection : Wear suitable protective clothing Chemical resistant boots.
- Hand protection : Use neoprene gloves.
- Eye protection : Goggles.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state
: Liquid
Colour
: Light brown
Odour
: characteristic
pH value in distilled water :1%: 7.6
Molecular weight : Fenpropidin : 273.5
Density
: 0.931 g/ml
Viscosity
: 63 mPas (100.01 s-1)
Solubility in water
: Emulsifiable
Flash point [°C] : > 110
Log P octanol : Fenpropidin : 2.59
10. STABILITY AND REACTIVITY
Physico-chemical stability
: Stable under normal conditions.
Hazardous decomposition products : Thermal decomposition may generate : carbon monoxide , carbon dioxide ,
nitrogen oxides , NH3.
Hazardous reactions : Avoid contact with : oxidizing agents .
Makhteshim Chemical Works Ltd.
PO Box 60 Beer Sheva 84100 Israel.
Fax : +972-8-6296848

U
MATERIAL SAFETY DATA SHEET
Page : 3 of 4
Revised edition no : 1
Date : 9/2/2006
Supersedes : 0/0/0
ALPHA FENPROPIDIN 750 EC R-18958
10. STABILITY AND REACTIVITY (continued)
Hazardous Polymerization
Conditions to avoid
: Will not occur.
: Protect from (sun)light , open flame , sources of heat , Freezing.
11. TOXICOLOGICAL INFORMATION
Rat oral LD50 [mg/kg] : 300 -2000
Rabbit dermal LD50 [mg/kg] : ~ 775
Rat inhalation LC50 [mg/l/4h] : ~ 1.28
Dermal irritation (rabbit)
: Not irritating
Eyes irritation (rabbit)
: Risk of serious damage to eyes.
Sensitization
: Guinea pig maximization test: Non sensitizer
Carcinogenicity
: Fenpropidin : Not carcinogenic
Mutagenicity
: Fenpropidin : Not mutagenic
Reproductive toxicity
: Fenpropidin : Not teratogenic in animal experiments
12. ECOLOGICAL INFORMATION
Ecological effects information : No ecological information is known on the product. For Fenpropidin:
96 H-LC50 - Bluegill sunfish [mg/l] :1.9
96 H-LC50 - Rainbow trout [mg/l] :2.6
48 H-LC50 - Daphnia magna [mg/l] :0.5
96 H-EbC50 - Algae [mg/l] : 0.0057
LD50 Birds [mg/kg] : Mallard duck : 1900
Bees LD50 [µg/Bee] : oral : > 10
Contact : 46
13. DISPOSAL CONSIDERATIONS
Disposal
: Dispose in a safe manner in accordance with local/national regulations.
14. TRANSPORT INFORMATION
- UN No. : 2902
- Proper shipping name : PESTICIDE, LIQUID, TOXIC, N.O.S. (750 g/l Fenpropidin)
- Packing group : III
- Class :6.1
- H.I. nr : :60
- IMDG-Marine pollution :Yes
15. REGULATORY INFORMATION
EU Classification
Symbol(s)
: This product is provisionally labelled by the supplier in accordance to the EU
regulations; :
: Xn: Harmful.
N: Dangerous for the environment.
Makhteshim Chemical Works Ltd.
PO Box 60 Beer Sheva 84100 Israel.
Fax : +972-8-6296848

U
MATERIAL SAFETY DATA SHEET
Page : 4 of 4
Revised edition no : 1
Date : 9/2/2006
Supersedes : 0/0/0
ALPHA FENPROPIDIN 750 EC R-18958
15. REGULATORY INFORMATION (continued)
R Phrase(s)
S Phrase(s)
Labelling
: R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R41 - Risk of serious damage to eyes.
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
: S02 - Keep out of the reach of children.
S23 - Do not breathe gas/fumes/vapour/spray.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S29/35 - Do not empty into drains ; dispose of this material and its container in a
safe way.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S46 - If swallowed seek medical advice immediately and show this container or
label.
S57 - Use appropriate container to avoid environmental contamination.
: May cause allergic reaction(s)
16. OTHER INFORMATION
Recommended uses and restrictions
Text of R-phrases in heading 2
: Fungicide
: R20/22 - Harmful by inhalation and if swallowed.
R22 - Harmful if swallowed.
R36/38 - Irritating to eyes and skin.
R38 - Irritating to skin.
R41 - Risk of serious damage to eyes.
R43 - May cause sensitization by skin contact.
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R65 - Harmful : may cause lung damage if swallowed.
Print date : 9/2/2006
DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However,
the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of
handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and
other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in
any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used
only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
End of document
Makhteshim Chemical Works Ltd.
PO Box 60 Beer Sheva 84100 Israel.
Fax : +972-8-6296848