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MATERIAL SAFETY DATA SHEET - Reckitt Benckiser

MATERIAL SAFETY DATA SHEET - Reckitt Benckiser

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Date: 17 th December 2008<br />

<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

Product Name: Clearasil Rapid Action Treatment Cream<br />

1. PRODUCT AND COMPANY IDENTIFICATION<br />

Product Name:<br />

CLEARASIL ULTRA RAPID ACTION TREATMENT CREAM<br />

Product Description:<br />

Acne treatment Cream<br />

Product Identifier: 10069001<br />

UPC Number: 8-39977-00249-2<br />

Validation Date: 17th December 2008<br />

Synonyms:<br />

CLEARASIL ULTRA RAPID ACTION TREATMENT CREAM -NON-<br />

TINTED ( SALICYLIC ACID BASE)<br />

Clearasil Ultra Rapid Action Treatment Cream Clear - ROW (2%<br />

SALICYLIC ACID)<br />

Chemical Characterization:<br />

White soft smooth glossy cream<br />

Manufacturer:<br />

Almirall Hermal GmbH<br />

Scholtzstraße 3<br />

D-21465 Reinbek<br />

Emergency Telephone Number: 1-800-228-4722 (US)<br />

Transportation Emergencies:<br />

1-800-424-9300 (U.S. & Canada) CHEMTREC<br />

Outside the U.S. and Canada (North America) Chemtrec call:703-<br />

527-3887<br />

Distributor/Importer:<br />

<strong>Reckitt</strong> <strong>Benckiser</strong> Inc. (United States)<br />

Morris Corporate Center IV<br />

399 Interpace Parkway (P.O. Box 225)<br />

Parsippany, NJ 07054-0225<br />

2. COMPOSITION / INFORMATION ON INGREDIENTS<br />

Exposure Limits:<br />

Components: CAS No.: Weight %: ACGIH: OSHA:<br />

Water 7732-18-5 >50% N/A N/A<br />

Salicylic Acid 69-72-7 1-5% N/A N/A<br />

Steareth-2 9005-00-9 1-5% N/A N/A<br />

Sepigel 38193-60-1, 1-5% N/A<br />

N/A<br />

64742-47-8,<br />

N/A<br />

N/A<br />

3055-97-8<br />

N/A<br />

N/A<br />

Menthol 1490-04-6


Date: 17 th December 2008<br />

<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

Product Name: Clearasil Rapid Action Treatment Cream<br />

Inhalation:<br />

Skin Contact:<br />

Ingestion:<br />

Eye Contact:<br />

Notes to Physician:<br />

Aggravated Medical Conditions:<br />

Remove to fresh air if inhalation causes eye watering, headaches,<br />

dizziness, or other discomfort.<br />

If irritation occurs wash thoroughly with soap and water. Remove<br />

contaminated clothing and consult a physician.<br />

If swallowed in quantity DO NOT INDUCE VOMITING. Rinse mouth<br />

thoroughly and seek medical attention.<br />

Remove contact lenses if present. Flush immediately with large<br />

amounts of water, especially under lids for at least 15 minutes. If<br />

irritation or other effects persist, obtain medical treatment.<br />

5. FIRE-FIGHTING MEASURES<br />

Suitable Extinguishing Media:<br />

Extinguishing Media which must not<br />

be used for safety reasons:<br />

Specific Hazards:<br />

Fire can be extinguished using: water spray, foam, dry chemicals,<br />

sand, dolomite etc.<br />

Not applicable<br />

Avoid breathing fire vapours. Keep run-off water out of sewers and<br />

water sources. Dike for water control.<br />

Unusual Hazards:<br />

N/A<br />

Special Protective Equipment for Appropriate self-contained breathing apparatus may be required as<br />

Firefighters:<br />

the product contains organic substances that will produce smoke and<br />

fumes if in contact with a fire.<br />

Specific Methods:<br />

N/A<br />

Flash Point:<br />

N/A<br />

Auto Ignition Temperature:<br />

N/A<br />

Flammability Limits in Air:<br />

N/A<br />

- Lower N/A<br />

- Upper N/A<br />

NFPA Health:1 Flammability:0 Instability:0<br />

HMIS Health:1 Flammability:0 Physical Hazard:0<br />

6. ACCIDENTAL RELEASE MEASURES<br />

Personal Precautions:<br />

Environmental Precautions:<br />

Methods for Cleaning Up:<br />

Exclude non-essential personnel. Floors may become slippery.<br />

Clean-up personnel should use respiratory protection.<br />

The material is not classified as harmful to the environment.<br />

However, care should be taken not to allow large spills entry into<br />

drains or watercourses.<br />

Exclude non-essential personnel. Floors may become slippery. It is<br />

preferable to contain and collect large spillages with non-combustible<br />

absorbent materials, e.g., sand, earth, vermiculite or diatomaceous<br />

earth and place in a clearly labelled suitable container for disposal in<br />

accordance with local waste control laws.<br />

7. HANDLING AND STORAGE<br />

Handling:<br />

Storage:<br />

In case of accidental discharge avoid eye and skin contact. Good<br />

housekeeping standards and regular safe removal of waste materials<br />

are recommended.<br />

Keep in cool, dry, ventilated storage. Keep in original container.


Date: 17 th December 2008<br />

<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

Product Name: Clearasil Rapid Action Treatment Cream<br />

Keep from freezing.<br />

8. EXPOSURE CONTROLS/PERSONAL PROTECTION<br />

Components<br />

Sepigel<br />

64742-47-8<br />

Canada – British<br />

Columbia – 8hr.<br />

Exposure Limits<br />

200 mg/m3 TWA<br />

Canada – Ontario –<br />

OHSA – Designated<br />

Substances<br />

Canada – Ontario –<br />

OHSA TWAEVs<br />

Canada – Quebec -<br />

TWA<br />

Engineering measures to reduce exposure:<br />

Personal Protective Equipment:<br />

Respiratory Protection:<br />

Hand Protection:<br />

Skin & Body Protection:<br />

Eye Protection:<br />

Hygiene Measures;<br />

Unlikely to be a concern. However, where prolonged skin exposure<br />

may occur, suitable gloves such as nitrile rubber, chloroprene rubber<br />

or PVC may be worn.<br />

Unlikely to be required. Normal cotton/polyester type overalls are<br />

suitable.<br />

Eye protection designed to protect against liquid splashes should be<br />

worn when handling large quantities (e.g. safety goggles or face visor<br />

or safety glasses with side shields).<br />

Wash at the end of each work shift and before eating, smoking. Wash<br />

promptly with soap & water if skin becomes irritated if in prolonged<br />

contact with the product and promptly remove any contaminated<br />

clothing.<br />

9. PHYSICAL AND CHEMICAL PROPERTIES<br />

Physical State:<br />

White homogeneous cream<br />

Appearance:<br />

White cream<br />

Colour:<br />

White<br />

Odour:<br />

Slight characteristic<br />

pH: 3.8 - 4.2<br />

Auto Ignition Temperature:<br />

Not applicable/Not tested product contains no flammable<br />

ingredients<br />

Specific Gravity:<br />

No information available.<br />

Density: 0.980-1.040<br />

Bulk Density:<br />

No information available.<br />

Vapor Density:<br />

No information available.<br />

Vapor Pressure:<br />

No information available.<br />

Solubility:<br />

Soluble/Miscible in water<br />

VOC Content %:<br />

No information available.<br />

Explosion Limits:<br />

Upper:<br />

N/A<br />

Lower:<br />

N/A<br />

10. STABILITY AND REACTIVITY<br />

Stability:<br />

Polymerization:<br />

Stable product.<br />

None known.


Date: 17 th December 2008<br />

<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

Product Name: Clearasil Rapid Action Treatment Cream<br />

Hazardous Decomposition Products:<br />

Materials to avoid:<br />

Conditions to avoid:<br />

Fire could create: Toxic gases/vapours/fumes of: Carbon monoxide<br />

(CO). Carbon dioxide.<br />

Avoid contact with oxidisers or reducing agents.<br />

None identified<br />

11. TOXICOLOGICAL INFORMATION<br />

Acute Toxicity:<br />

Component Information: This product possesses no known toxicological hazards when used as directed and<br />

all precautions followed. This product has been assessed in line with the relevant regulations applicable to<br />

cosmetic products for safety and toxicology.<br />

Product Information: For external use only. Don't get this treatment cream in your eyes or mouth. If you do,<br />

rinse it out immediately with lots of water . Stop using if skin irritation occurs. If irritation persists, please<br />

consult a doctor.<br />

Keep out of the reach of children.<br />

LC50/Inhalation/4h/rat:<br />

0.9mg/L/1H – salicylic acid<br />

5.2 mg/L – Sepigel cas # 64742-47-8<br />

LD50/dermal/rabbit:<br />

200 mg/kg– salicylic acid<br />

2000 mg/kg - Sepigel cas # 64742-47-8<br />

LD50/oral/rat:<br />

891 mg/kg– salicylic acid<br />

2900 mg/kg – steareth-2<br />

5000 mg/kg - Sepigel cas # 64742-47-8<br />

3180 mg/kg – Menthol<br />

Local Effects:<br />

Skin irritation:<br />

Stop using if skin irritation occurs<br />

Eye Irritation:<br />

Rinse it out immediately with lots of water<br />

Inhalation:<br />

No information available.<br />

Ingestion:<br />

Rinse it out immediately with lots of water<br />

Sensitization:<br />

No information available.<br />

Chronic Toxicity:<br />

No information available.<br />

Specific Effects:<br />

Carcinogenic effects:<br />

No information available.<br />

Mutagenic effects:<br />

No information available.<br />

Reproductive Toxicity:<br />

No information available.<br />

Target Organ Effects:<br />

No information available.<br />

Information is based on data on the components and the toxicology of similar products.<br />

12. ECOLOGICAL INFORMATION<br />

Product Information<br />

Mobility:<br />

Bioaccumulative Potential:<br />

Ecotoxic effects:<br />

Aquatic Toxicity:<br />

Component Information:<br />

The preparation is not classified as harmful to the environment.<br />

Other Information:<br />

Ozone depletion Potential: ODP; (R-11<br />

No information available.<br />

No information available.<br />

No information available.<br />

The product should not be allowed to enter drains, in quantity, or gain<br />

access to watercourses or routes to septic tanks or be deposited<br />

where it can affect ground or surface waters.<br />

No information available.


Date: 17 th December 2008<br />

<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

Product Name: Clearasil Rapid Action Treatment Cream<br />

= 1):<br />

Global Warming Potential (GWP):<br />

Additional Ecological Information:<br />

No information available.<br />

No information available.<br />

13. DISPOSAL CONSIDERATIONS<br />

Waste from residues/unused product:<br />

Contaminated packaging:<br />

No information available.<br />

No information available.<br />

14. TRANSPORT INFORMATION<br />

UN/ID No.<br />

DOT:<br />

Classification<br />

Proper Shipping Name<br />

U.S. DOT Hazard Class:<br />

Subsidiary Risk:<br />

Packing Group:<br />

DOT RQ (lbs):<br />

ERG No:<br />

TDG (Canada):<br />

Classification:<br />

Proper Shipping Name<br />

Status:<br />

Packing Group:<br />

IMDG/IMO<br />

Classification<br />

Proper Shipping Name<br />

Class:<br />

Subsidiary Risk:<br />

Packing Group:<br />

IMDG Page:<br />

Marine Pollutant:<br />

EmS:<br />

MFAG:<br />

Maximum Quantity:<br />

ADR/RID<br />

Classification<br />

Proper Shipping Name<br />

Class:<br />

Subsidiary Risk:<br />

Packing Group:<br />

ADR/RID – Labels:<br />

HIN:<br />

CEFIC Tremcard No.<br />

ICAO/IATA:<br />

Classification<br />

Proper Shipping Name<br />

Class:<br />

Subsidiary Risk:<br />

Not regulated<br />

N/A<br />

N/A<br />

N/A<br />

N/A<br />

N/A<br />

N/A<br />

Not regulated<br />

N/A<br />

N/A<br />

N/A<br />

Not regulated<br />

N/A<br />

N/A<br />

N/A<br />

N/A<br />

N/A<br />

N/A<br />

N/A<br />

N/A<br />

N/A<br />

N/A<br />

Not regulated, Not a dangerous good.<br />

N/A<br />

N/A<br />

N/A<br />

N/A<br />

N/A<br />

N/A<br />

N/A<br />

Not regulated, Not a dangerous good.<br />

N/A<br />

N/A<br />

N/A


Date: 17 th December 2008<br />

<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

Product Name: Clearasil Rapid Action Treatment Cream<br />

Packing Group:<br />

Maximum Quantity<br />

N/A<br />

N/A


Date: 17 th December 2008<br />

15. REGULATORY INFORMATION<br />

<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

Product Name: Clearasil Rapid Action Treatment Cream<br />

Components: TSCA: DSL: NDSL: China: AICS: EINECS No.:<br />

WATER<br />

Y Y Y Y<br />

7732-18-5<br />

231-791-2<br />

SALICYLIC ACID<br />

Y Y Y Y<br />

69-72-7<br />

201-919-1<br />

STEARETH-2<br />

9005-00-9<br />

Y Y Y Y<br />

SEPIGEL<br />

38193-60-1,<br />

Y Y<br />

Y Y -------------<br />

64742-47-8,<br />

Y Y<br />

Y Y 265-149-8<br />

3055-97-8<br />

Y<br />

Y Y Y 221-283-9<br />

MENTHOL<br />

1490-04-6 Y Y Y Y 216-074-4<br />

16. OTHER INFORMATION<br />

National Fire Protection Association (U.S.A):<br />

HMIS (U.S.A):<br />

Health Hazard: 1<br />

Fire Hazard: 0<br />

Reactivity: 0<br />

Personal Protection: 0<br />

Reason for Revision:<br />

Additional Advice:<br />

Prepared by:<br />

New Document<br />

Consult your supplier if the material is to be used in special applications such<br />

as in the food industry or for hygiene, medical or surgical end use<br />

Global RSE<br />

To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier<br />

nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information<br />

contained herein. Final determination of suitability of any materials is the sole responsibility of the user. All materials may<br />

present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot<br />

guarantee that these are the only hazards that exist.

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