MATERIAL SAFETY DATA SHEET - Reckitt Benckiser
MATERIAL SAFETY DATA SHEET - Reckitt Benckiser
MATERIAL SAFETY DATA SHEET - Reckitt Benckiser
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Date: 17 th December 2008<br />
<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />
Product Name: Clearasil Rapid Action Treatment Cream<br />
1. PRODUCT AND COMPANY IDENTIFICATION<br />
Product Name:<br />
CLEARASIL ULTRA RAPID ACTION TREATMENT CREAM<br />
Product Description:<br />
Acne treatment Cream<br />
Product Identifier: 10069001<br />
UPC Number: 8-39977-00249-2<br />
Validation Date: 17th December 2008<br />
Synonyms:<br />
CLEARASIL ULTRA RAPID ACTION TREATMENT CREAM -NON-<br />
TINTED ( SALICYLIC ACID BASE)<br />
Clearasil Ultra Rapid Action Treatment Cream Clear - ROW (2%<br />
SALICYLIC ACID)<br />
Chemical Characterization:<br />
White soft smooth glossy cream<br />
Manufacturer:<br />
Almirall Hermal GmbH<br />
Scholtzstraße 3<br />
D-21465 Reinbek<br />
Emergency Telephone Number: 1-800-228-4722 (US)<br />
Transportation Emergencies:<br />
1-800-424-9300 (U.S. & Canada) CHEMTREC<br />
Outside the U.S. and Canada (North America) Chemtrec call:703-<br />
527-3887<br />
Distributor/Importer:<br />
<strong>Reckitt</strong> <strong>Benckiser</strong> Inc. (United States)<br />
Morris Corporate Center IV<br />
399 Interpace Parkway (P.O. Box 225)<br />
Parsippany, NJ 07054-0225<br />
2. COMPOSITION / INFORMATION ON INGREDIENTS<br />
Exposure Limits:<br />
Components: CAS No.: Weight %: ACGIH: OSHA:<br />
Water 7732-18-5 >50% N/A N/A<br />
Salicylic Acid 69-72-7 1-5% N/A N/A<br />
Steareth-2 9005-00-9 1-5% N/A N/A<br />
Sepigel 38193-60-1, 1-5% N/A<br />
N/A<br />
64742-47-8,<br />
N/A<br />
N/A<br />
3055-97-8<br />
N/A<br />
N/A<br />
Menthol 1490-04-6
Date: 17 th December 2008<br />
<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />
Product Name: Clearasil Rapid Action Treatment Cream<br />
Inhalation:<br />
Skin Contact:<br />
Ingestion:<br />
Eye Contact:<br />
Notes to Physician:<br />
Aggravated Medical Conditions:<br />
Remove to fresh air if inhalation causes eye watering, headaches,<br />
dizziness, or other discomfort.<br />
If irritation occurs wash thoroughly with soap and water. Remove<br />
contaminated clothing and consult a physician.<br />
If swallowed in quantity DO NOT INDUCE VOMITING. Rinse mouth<br />
thoroughly and seek medical attention.<br />
Remove contact lenses if present. Flush immediately with large<br />
amounts of water, especially under lids for at least 15 minutes. If<br />
irritation or other effects persist, obtain medical treatment.<br />
5. FIRE-FIGHTING MEASURES<br />
Suitable Extinguishing Media:<br />
Extinguishing Media which must not<br />
be used for safety reasons:<br />
Specific Hazards:<br />
Fire can be extinguished using: water spray, foam, dry chemicals,<br />
sand, dolomite etc.<br />
Not applicable<br />
Avoid breathing fire vapours. Keep run-off water out of sewers and<br />
water sources. Dike for water control.<br />
Unusual Hazards:<br />
N/A<br />
Special Protective Equipment for Appropriate self-contained breathing apparatus may be required as<br />
Firefighters:<br />
the product contains organic substances that will produce smoke and<br />
fumes if in contact with a fire.<br />
Specific Methods:<br />
N/A<br />
Flash Point:<br />
N/A<br />
Auto Ignition Temperature:<br />
N/A<br />
Flammability Limits in Air:<br />
N/A<br />
- Lower N/A<br />
- Upper N/A<br />
NFPA Health:1 Flammability:0 Instability:0<br />
HMIS Health:1 Flammability:0 Physical Hazard:0<br />
6. ACCIDENTAL RELEASE MEASURES<br />
Personal Precautions:<br />
Environmental Precautions:<br />
Methods for Cleaning Up:<br />
Exclude non-essential personnel. Floors may become slippery.<br />
Clean-up personnel should use respiratory protection.<br />
The material is not classified as harmful to the environment.<br />
However, care should be taken not to allow large spills entry into<br />
drains or watercourses.<br />
Exclude non-essential personnel. Floors may become slippery. It is<br />
preferable to contain and collect large spillages with non-combustible<br />
absorbent materials, e.g., sand, earth, vermiculite or diatomaceous<br />
earth and place in a clearly labelled suitable container for disposal in<br />
accordance with local waste control laws.<br />
7. HANDLING AND STORAGE<br />
Handling:<br />
Storage:<br />
In case of accidental discharge avoid eye and skin contact. Good<br />
housekeeping standards and regular safe removal of waste materials<br />
are recommended.<br />
Keep in cool, dry, ventilated storage. Keep in original container.
Date: 17 th December 2008<br />
<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />
Product Name: Clearasil Rapid Action Treatment Cream<br />
Keep from freezing.<br />
8. EXPOSURE CONTROLS/PERSONAL PROTECTION<br />
Components<br />
Sepigel<br />
64742-47-8<br />
Canada – British<br />
Columbia – 8hr.<br />
Exposure Limits<br />
200 mg/m3 TWA<br />
Canada – Ontario –<br />
OHSA – Designated<br />
Substances<br />
Canada – Ontario –<br />
OHSA TWAEVs<br />
Canada – Quebec -<br />
TWA<br />
Engineering measures to reduce exposure:<br />
Personal Protective Equipment:<br />
Respiratory Protection:<br />
Hand Protection:<br />
Skin & Body Protection:<br />
Eye Protection:<br />
Hygiene Measures;<br />
Unlikely to be a concern. However, where prolonged skin exposure<br />
may occur, suitable gloves such as nitrile rubber, chloroprene rubber<br />
or PVC may be worn.<br />
Unlikely to be required. Normal cotton/polyester type overalls are<br />
suitable.<br />
Eye protection designed to protect against liquid splashes should be<br />
worn when handling large quantities (e.g. safety goggles or face visor<br />
or safety glasses with side shields).<br />
Wash at the end of each work shift and before eating, smoking. Wash<br />
promptly with soap & water if skin becomes irritated if in prolonged<br />
contact with the product and promptly remove any contaminated<br />
clothing.<br />
9. PHYSICAL AND CHEMICAL PROPERTIES<br />
Physical State:<br />
White homogeneous cream<br />
Appearance:<br />
White cream<br />
Colour:<br />
White<br />
Odour:<br />
Slight characteristic<br />
pH: 3.8 - 4.2<br />
Auto Ignition Temperature:<br />
Not applicable/Not tested product contains no flammable<br />
ingredients<br />
Specific Gravity:<br />
No information available.<br />
Density: 0.980-1.040<br />
Bulk Density:<br />
No information available.<br />
Vapor Density:<br />
No information available.<br />
Vapor Pressure:<br />
No information available.<br />
Solubility:<br />
Soluble/Miscible in water<br />
VOC Content %:<br />
No information available.<br />
Explosion Limits:<br />
Upper:<br />
N/A<br />
Lower:<br />
N/A<br />
10. STABILITY AND REACTIVITY<br />
Stability:<br />
Polymerization:<br />
Stable product.<br />
None known.
Date: 17 th December 2008<br />
<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />
Product Name: Clearasil Rapid Action Treatment Cream<br />
Hazardous Decomposition Products:<br />
Materials to avoid:<br />
Conditions to avoid:<br />
Fire could create: Toxic gases/vapours/fumes of: Carbon monoxide<br />
(CO). Carbon dioxide.<br />
Avoid contact with oxidisers or reducing agents.<br />
None identified<br />
11. TOXICOLOGICAL INFORMATION<br />
Acute Toxicity:<br />
Component Information: This product possesses no known toxicological hazards when used as directed and<br />
all precautions followed. This product has been assessed in line with the relevant regulations applicable to<br />
cosmetic products for safety and toxicology.<br />
Product Information: For external use only. Don't get this treatment cream in your eyes or mouth. If you do,<br />
rinse it out immediately with lots of water . Stop using if skin irritation occurs. If irritation persists, please<br />
consult a doctor.<br />
Keep out of the reach of children.<br />
LC50/Inhalation/4h/rat:<br />
0.9mg/L/1H – salicylic acid<br />
5.2 mg/L – Sepigel cas # 64742-47-8<br />
LD50/dermal/rabbit:<br />
200 mg/kg– salicylic acid<br />
2000 mg/kg - Sepigel cas # 64742-47-8<br />
LD50/oral/rat:<br />
891 mg/kg– salicylic acid<br />
2900 mg/kg – steareth-2<br />
5000 mg/kg - Sepigel cas # 64742-47-8<br />
3180 mg/kg – Menthol<br />
Local Effects:<br />
Skin irritation:<br />
Stop using if skin irritation occurs<br />
Eye Irritation:<br />
Rinse it out immediately with lots of water<br />
Inhalation:<br />
No information available.<br />
Ingestion:<br />
Rinse it out immediately with lots of water<br />
Sensitization:<br />
No information available.<br />
Chronic Toxicity:<br />
No information available.<br />
Specific Effects:<br />
Carcinogenic effects:<br />
No information available.<br />
Mutagenic effects:<br />
No information available.<br />
Reproductive Toxicity:<br />
No information available.<br />
Target Organ Effects:<br />
No information available.<br />
Information is based on data on the components and the toxicology of similar products.<br />
12. ECOLOGICAL INFORMATION<br />
Product Information<br />
Mobility:<br />
Bioaccumulative Potential:<br />
Ecotoxic effects:<br />
Aquatic Toxicity:<br />
Component Information:<br />
The preparation is not classified as harmful to the environment.<br />
Other Information:<br />
Ozone depletion Potential: ODP; (R-11<br />
No information available.<br />
No information available.<br />
No information available.<br />
The product should not be allowed to enter drains, in quantity, or gain<br />
access to watercourses or routes to septic tanks or be deposited<br />
where it can affect ground or surface waters.<br />
No information available.
Date: 17 th December 2008<br />
<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />
Product Name: Clearasil Rapid Action Treatment Cream<br />
= 1):<br />
Global Warming Potential (GWP):<br />
Additional Ecological Information:<br />
No information available.<br />
No information available.<br />
13. DISPOSAL CONSIDERATIONS<br />
Waste from residues/unused product:<br />
Contaminated packaging:<br />
No information available.<br />
No information available.<br />
14. TRANSPORT INFORMATION<br />
UN/ID No.<br />
DOT:<br />
Classification<br />
Proper Shipping Name<br />
U.S. DOT Hazard Class:<br />
Subsidiary Risk:<br />
Packing Group:<br />
DOT RQ (lbs):<br />
ERG No:<br />
TDG (Canada):<br />
Classification:<br />
Proper Shipping Name<br />
Status:<br />
Packing Group:<br />
IMDG/IMO<br />
Classification<br />
Proper Shipping Name<br />
Class:<br />
Subsidiary Risk:<br />
Packing Group:<br />
IMDG Page:<br />
Marine Pollutant:<br />
EmS:<br />
MFAG:<br />
Maximum Quantity:<br />
ADR/RID<br />
Classification<br />
Proper Shipping Name<br />
Class:<br />
Subsidiary Risk:<br />
Packing Group:<br />
ADR/RID – Labels:<br />
HIN:<br />
CEFIC Tremcard No.<br />
ICAO/IATA:<br />
Classification<br />
Proper Shipping Name<br />
Class:<br />
Subsidiary Risk:<br />
Not regulated<br />
N/A<br />
N/A<br />
N/A<br />
N/A<br />
N/A<br />
N/A<br />
Not regulated<br />
N/A<br />
N/A<br />
N/A<br />
Not regulated<br />
N/A<br />
N/A<br />
N/A<br />
N/A<br />
N/A<br />
N/A<br />
N/A<br />
N/A<br />
N/A<br />
N/A<br />
Not regulated, Not a dangerous good.<br />
N/A<br />
N/A<br />
N/A<br />
N/A<br />
N/A<br />
N/A<br />
N/A<br />
Not regulated, Not a dangerous good.<br />
N/A<br />
N/A<br />
N/A
Date: 17 th December 2008<br />
<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />
Product Name: Clearasil Rapid Action Treatment Cream<br />
Packing Group:<br />
Maximum Quantity<br />
N/A<br />
N/A
Date: 17 th December 2008<br />
15. REGULATORY INFORMATION<br />
<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />
Product Name: Clearasil Rapid Action Treatment Cream<br />
Components: TSCA: DSL: NDSL: China: AICS: EINECS No.:<br />
WATER<br />
Y Y Y Y<br />
7732-18-5<br />
231-791-2<br />
SALICYLIC ACID<br />
Y Y Y Y<br />
69-72-7<br />
201-919-1<br />
STEARETH-2<br />
9005-00-9<br />
Y Y Y Y<br />
SEPIGEL<br />
38193-60-1,<br />
Y Y<br />
Y Y -------------<br />
64742-47-8,<br />
Y Y<br />
Y Y 265-149-8<br />
3055-97-8<br />
Y<br />
Y Y Y 221-283-9<br />
MENTHOL<br />
1490-04-6 Y Y Y Y 216-074-4<br />
16. OTHER INFORMATION<br />
National Fire Protection Association (U.S.A):<br />
HMIS (U.S.A):<br />
Health Hazard: 1<br />
Fire Hazard: 0<br />
Reactivity: 0<br />
Personal Protection: 0<br />
Reason for Revision:<br />
Additional Advice:<br />
Prepared by:<br />
New Document<br />
Consult your supplier if the material is to be used in special applications such<br />
as in the food industry or for hygiene, medical or surgical end use<br />
Global RSE<br />
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier<br />
nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information<br />
contained herein. Final determination of suitability of any materials is the sole responsibility of the user. All materials may<br />
present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot<br />
guarantee that these are the only hazards that exist.