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Olivo, G.R., Chang, F., and Kyser, T.K., 2006. Formation of the ...

Olivo, G.R., Chang, F., and Kyser, T.K., 2006. Formation of the ...

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608 OLIVO ET AL.<br />

Kirkl<strong>and</strong> Lake, Dome, Kerr Addison, Sigma-Lamaque, <strong>and</strong><br />

Pamour mines (Jenkins et al., 1997). These deposits formed<br />

through complex <strong>and</strong> multistage processes, allowing for concentration<br />

<strong>of</strong> gold at average grades typically around 10 g/t<br />

<strong>and</strong> locally attaining more than 100 g/t.<br />

Most studies <strong>of</strong> <strong>the</strong> processes related to <strong>the</strong> gold concentration<br />

in <strong>the</strong>se world-class deposits have focused on <strong>the</strong> ore<br />

zones with less attention on <strong>the</strong> related veins <strong>and</strong> alteration<br />

systems that are barren. The youngest vein system in <strong>the</strong><br />

Sigma deposit in <strong>the</strong> Abitibi greenstone belt, <strong>the</strong> North Dipper<br />

system (Gaboury et al., 2001), provides an opportunity to<br />

evaluate <strong>the</strong> processes related to ore formation because this<br />

system is relatively young <strong>and</strong> less deformed than early systems,<br />

<strong>and</strong> auriferous <strong>and</strong> barren veins are well exposed in <strong>the</strong><br />

Sigma pit <strong>and</strong> in <strong>the</strong> North zone, respectively, allowing for detailed<br />

mapping <strong>and</strong> sampling.<br />

In this study, detailed field observations reveal that <strong>the</strong><br />

geometry <strong>of</strong> <strong>the</strong> plumbing system <strong>and</strong> its position relative to<br />

<strong>the</strong> major fluid conduit are fundamental for formation <strong>of</strong> <strong>the</strong><br />

auriferous zones. Petrographic descriptions, micro<strong>the</strong>rmometry,<br />

crush-leach chemical analyses, <strong>and</strong> time-<strong>of</strong>-flight laser ablation<br />

induced coupled plasma-mass spectrometry (TOF-LA-<br />

ICPMS) <strong>of</strong> fluid inclusions, <strong>and</strong> stable isotope data also show<br />

that <strong>the</strong> mechanisms for gold precipitation in <strong>the</strong> North Dipper<br />

<strong>and</strong> related veins changed during <strong>the</strong> evolution <strong>of</strong> <strong>the</strong> system.<br />

Comparisons <strong>of</strong> <strong>the</strong> elements enriched in <strong>the</strong> auriferous<br />

fluids versus <strong>the</strong> barren fluids suggest various sources for <strong>the</strong><br />

metals associated with <strong>the</strong> gold, <strong>and</strong> <strong>the</strong> isotopic composition<br />

<strong>of</strong> <strong>the</strong> fluids that carried <strong>the</strong> gold indicates low fluid/rock<br />

ratios.<br />

Regional Geologic <strong>and</strong> Tectonic Setting<br />

The Val d’Or district is located in <strong>the</strong> eastern segment <strong>of</strong><br />

<strong>the</strong> sou<strong>the</strong>rn Volcanic zone (Daigneault et al., 2002) <strong>of</strong> <strong>the</strong><br />

Archean Abitibi subprovince at <strong>the</strong> boundary with <strong>the</strong> Pontiac<br />

subprovince (Fig. 1). This boundary is characterized by<br />

an extensive deformation zone, referred to as <strong>the</strong> Larder<br />

Lake-Cadillac break, which is interpreted as a suture zone between<br />

<strong>the</strong>se two subprovinces (Robert et al., 1995). The<br />

Larder Lake-Cadillac break major fault zone dips to <strong>the</strong> north<br />

<strong>and</strong> is spatially associated with numerous gold deposits <strong>and</strong><br />

occurrences (Robert, 1989, 1994). The geology <strong>of</strong> <strong>the</strong> Val<br />

d’Or district has been described by Gunning <strong>and</strong> Ambrose<br />

(1940), Norman 1947), Latulippe (1966), Dimroth et al.<br />

(1982, 1983a, b), Imreh (1984), Desrochers et al. (1993),<br />

Desrochers <strong>and</strong> Hubert (1996), <strong>and</strong> recently reviewed by Pilote<br />

et al. (1997, 1998, 1999, 2000) <strong>and</strong> Scott et al. (2002). Information<br />

from <strong>the</strong>se sources, as well as from specific studies<br />

in <strong>the</strong> area, is briefly summarized below.<br />

The Val d’Or district comprises a complex sequence <strong>of</strong> volcanic-sedimentary<br />

<strong>and</strong> intrusive rocks that evolved from<br />

2714 to 2611 Ma. The volcanic-sedimentary sequences are<br />

part <strong>of</strong> <strong>the</strong> Malartic Group (i.e., La Motte-Vasson, Dubuisson,<br />

Lac Caste, <strong>and</strong> Jacola <strong>Formation</strong>s) <strong>and</strong> <strong>the</strong> Louvicourt<br />

Group (Val d’Or <strong>and</strong> Héva <strong>Formation</strong>s: Scott et al., 2002).<br />

The Malartic Group comprises mainly ocean floor komatiite<br />

<strong>and</strong> tholeiitic basalt flows <strong>and</strong> sills, with minor sedimentary<br />

rocks, which are interpreted to be formed in an extensional<br />

environment related to mantle plumes. The Louvicourt<br />

Group is composed mainly <strong>of</strong> mafic to felsic volcanic rocks<br />

that formed in a subduction-related deep marine volcanic<br />

arc. The studied barren <strong>and</strong> auriferous veins are hosted in <strong>the</strong><br />

transition zone between <strong>the</strong> Jacola <strong>and</strong> Val d’Or <strong>Formation</strong>s,<br />

which are described below.<br />

The Jacola <strong>Formation</strong> extends for more than 5 km <strong>and</strong> consists<br />

<strong>of</strong> a 1- to 2-km-thick sequence <strong>of</strong> pillowed, brecciated,<br />

<strong>and</strong> massive tholeiitic basalts, intercalated with komatiite <strong>and</strong><br />

massive to pillowed komatiite flows (100–200 m thick). Discontinuous<br />

interflow volcaniclastic deposits occur locally <strong>and</strong><br />

have been dated at 2703.08 ± 1.3 Ma (Pilote et al., 1999). This<br />

sequence is interpreted to represent fissure-style eruptions<br />

formed in a proto-arc environment. The contact between <strong>the</strong><br />

Jacola <strong>and</strong> Val d’Or <strong>Formation</strong>s to <strong>the</strong> south is gradational <strong>and</strong><br />

interefingers laterally (Dimroth et al., 1982), being characterized<br />

by a significant increase in <strong>the</strong> volume <strong>of</strong> volcaniclastic<br />

deposits <strong>and</strong> a change to intermediate <strong>and</strong> felsic composition<br />

at <strong>the</strong> base <strong>of</strong> <strong>the</strong> Val d’Or <strong>Formation</strong> (Scott et al., 2002).<br />

The overlying Val d’Or <strong>Formation</strong> is composed <strong>of</strong> a 3- to 5-<br />

km-thick sequence <strong>of</strong> discontinuous, interstratified, massive to<br />

pillowed lavas <strong>and</strong> volcaniclastic deposits <strong>of</strong> <strong>and</strong>esite (50%),<br />

dacite (30%), <strong>and</strong> rhyolite (20%). The lower units are tholeiitic<br />

to intermediate, <strong>and</strong> <strong>the</strong> upper units are intermediate to<br />

calc-alkaline in composition. The dacitic <strong>and</strong> rhyolitic units<br />

have an age <strong>of</strong> 2704 ± 2 Ma (Wong et al., 1991; Machado et al.,<br />

1992; Pilote et al., 1998). The distribution <strong>and</strong> composition <strong>of</strong><br />

<strong>the</strong> Val d’Or <strong>Formation</strong> rocks suggest that <strong>the</strong>y formed as numerous<br />

small volcanic vents analogous to a modern arc setting<br />

(Scott et al., 2002). Primary volcanic features in both formations<br />

indicate younging directions toward <strong>the</strong> south.<br />

These volcanic <strong>and</strong> sedimentary sequences are intruded by<br />

felsic to mafic bodies that have been grouped into three<br />

classes (Pilote et al., 2000): (1) 2700 Ma synvolcanic (Wong et<br />

al., 1991) stocks <strong>and</strong> batholiths, (2) 2680 Ma syn- to late-tectonic<br />

intrusions (Jemielita et al., 1990; Pilote et al., 1998), <strong>and</strong><br />

(3) late- to post-tectonic, undeformed <strong>and</strong> unmetamorphosed<br />

stocks <strong>and</strong> dikes intruded between 2675 <strong>and</strong> 2611 Ma (Feng<br />

<strong>and</strong> Kerrich, 1991; Ducharme et al., 1997).<br />

All <strong>the</strong>se units, with <strong>the</strong> exception <strong>of</strong> <strong>the</strong> late stocks <strong>and</strong><br />

dikes, have been metamorphosed to greenschist facies <strong>and</strong><br />

multiply deformed in three major phases (Robert, 1990a, b;<br />

Desrochers <strong>and</strong> Hubert, 1996). The first phase <strong>of</strong> deformation<br />

(D 1 ) is recognized only locally; <strong>the</strong> second phase (D 2 ) is<br />

<strong>the</strong> dominant structural trend in <strong>the</strong> area <strong>and</strong> is characterized<br />

by tight <strong>and</strong> isoclinal folds, a regionally penetrative subvertical<br />

east-west foliation, faults, <strong>and</strong> shear zones. Gold deposits<br />

in <strong>the</strong> Val d’Or disctrict are hosted or spatially associated with<br />

<strong>the</strong>se faults <strong>and</strong> shear zones. The D 2 deformation event is estimated<br />

to have occurred after 2672 Ma, <strong>the</strong> age <strong>of</strong> <strong>the</strong> detrital<br />

zircons in sedimentary units folded by D 2 (Robert, 2001,<br />

<strong>and</strong> references <strong>the</strong>rein). The D 3 phase <strong>of</strong> deformation is characterized<br />

by steep, open folds <strong>and</strong> associated east-nor<strong>the</strong>ast<br />

crenulation cleavage <strong>and</strong> also involved <strong>the</strong> reactivation <strong>of</strong> <strong>the</strong><br />

D 1 <strong>and</strong> D 2 faults <strong>and</strong> shear zones.<br />

Sigma Mine Geology: Host Rocks <strong>and</strong> Vein Systems<br />

The geology <strong>and</strong> auriferous vein systems <strong>of</strong> <strong>the</strong> Sigma mine<br />

have been described by Robert (1983), Robert <strong>and</strong> Brown<br />

(1986a, b), Robert et al. (1995), Gar<strong>of</strong>alo (2000), <strong>and</strong> Gaboury<br />

et al. (2001). The relevant features observed by <strong>the</strong> authors,<br />

integrated with previous studies, are presented below.<br />

0361-0128/98/000/000-00 $6.00 608

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