Millathane® CM MSDS - TSE Industries, Inc.

Approval Date: 07-25-08
Supersedes Date: 08-04-05
MATERIAL SAFETY DATA SHEET
Section 1. Chemical Product and Company Identification
Product Name: MILLATHANE CM
(formerly called ADIPRENE ® CM)
Chemical Name: Synthetic Urethane Rubber
Chemical Family: Polyurethane
Manufacturer:
TSE Industries, Inc.
5260 113 th Avenue North
Clearwater, FL 33760
Tel: (727) 573-7676
Fax: (727) 572-0415
Emergency Telephone INFOTRAC: Domestic: 1-800-535-5053
Numbers: International: +1-352-323-3500
Section 2. Composition/Information on Ingredients
Name CASRN Percent Exposure Limits Carcinogen Skin
(By Weight) OSHA ACGIH
PEL TLV
TWA/ TWA/ IARC/NTP
STEL STEL /OSHA
Polyurethane 56619-85-3 100 NE NE No No
Section 3. Hazards Identification
Emergency Overview
Orange solid with slight characteristic odor. Burns, but difficult to ignite. Does not present a
significant health or environmental hazard as shipped. Minimize vapor exposure during hot
processing. Protect against inhalation of combustion products if involved in a fire.
The following ratings are subjective. They are provided as a quick hazard guide only. Read the
entire MSDS before using the product.
Hazard Rating System:
Health Flammability Reactivity Incompatibility PPE
NFPA: 0 0 1 ---- --
HMIS: 0 0 1 ---- B
0 = minimal, 1 = slight, 2 = moderate, 3 = serious, 4 = severe, * = chronic health hazard
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Potential Health Effects, Signs, and Symptoms of Exposure:
Inhalation: None except at elevated processing temperatures – see sections 7 and 8.
Eye Contact: Mechanical irritant only.
Skin Contact: Not anticipated to cause irritation with prolonged exposure.
Skin Absorption: None.
Swallowing: Not a likely route of entry, but very low toxicity if ingested.
Section 4. First Aid Measures
Eyes: Flush with water to relieve irritation, see physician if irritation persists.
Skin: Wash thoroughly with soap and water.
Inhalation: Remove to fresh air if difficulty breathing and seek medical attention.
Ingestion: NA
Medical Conditions Generally Aggravated by Exposure: None known.
Section 5. Fire Fighting Measures
Flash Point: NA
Auto-Ignition Temperature: ND
UEL/LEL: NA
Extinguishing Media: Water spray, dry chemical, foam are compatible if material is ignited
by a primary fire.
Special Fire Fighting Procedures: Protect against inhalation of combustion products. Wear
SCBA and prevent skin contact with liquids produced in a fire.
Section 6. Accidental Release Measures
Spill or Release Procedures: NA
Section 7. Handling and Storage
Handling: Wear appropriate PPE, based upon Section 3 and Section 8. As supplied, no special
handling procedures are required.
Storage: Keep in the original package and store in a cool, dry area. Keep away from sources
of direct heat and high humidity.
Section 8. Exposure Controls/Personal Protection
Exposure Controls: Work in well-ventilated areas.
Personal Protective Equipment:
General: Wear gloves when handling.
Eye/Face: Wear eye protection when processing to prevent impact or dust entry if grinding.
Skin: Standard work clothing is adequate.
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Respiratory: Wear appropriate PPE when milling, curing, or grinding. May generate dust or
fumes. Work in well-ventilated area.
Section 9. Physical and Chemical Properties
Odor: Slight characteristic odor.
Appearance: Orange solid.
Boiling Point: NA
Decomposition Temperature: ND
Evaporation Rate: NIL
Freezing Point: NA
pH: NA
Specific Gravity: 1.06 (water=1)
Vapor Density: NA
Vapor Pressure: NA
Volatility: Negligible
Solubility in Water: Insoluble; soluble in THF, DMF or methylene chloride.
Section 10. Stability and Reactivity
Chemical Stability: Stable
Incompatibility with Other Materials: None identified.
Hazardous Polymerization: Will not occur.
Hazardous Decomposition Products: Thermal decomposition and burning may produce
carbon monoxide, carbon dioxide, and other toxic compounds including cyanates and small
quantities of HCN.
Section 11. Toxicological Information
There is no toxicology data on this material, however, like similar high molecular weight
polymers, it is expected to exhibit no significant toxicity.
Section 12. Ecological Information
Chemical Fate Information: ND
Biodegradability: ND
Section 13. Disposal Considerations
As shipped, this material is not regulated. However, it is the responsibility of the generator to
make a determination at the time of disposal whether the material meets any of the listing or
characteristic properties of a hazardous waste. Dispose of in accordance with applicable local,
state and federal laws.
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Section 14. Transport Information
This material is not regulated.
Section 15. Regulatory Information
SARA 302 Components: None.
Section 311/312 Hazard Class: None.
Section 313 Components: None.
US Toxic Substance Control Act: Listed on the TSCA Inventory.
International Status:
Australia (AICS): Listed on inventory
Canada (DSL): Listed on inventory
EU (EINECS): Listed on inventory
Japan (METI): Listed on inventory
Korea (KECI): Listed on inventory
Section 16. Other Information
Abbreviations:
ACGIH – American Conference of Governmental Industrial Hygienists
CASRN – Chemical Abstracts Service Registry Number
IARC – International Agency for Research on Cancer
NA – Not Applicable
ND – Not Determined
NE – Not Established
NTP – National Toxicology Program
OSHA – Occupational Safety & Health Administration
PEL – Permissible Exposure Limit
PPE – Personal Protective Equipment
STEL – Short Term (15 minute) Exposure Limit
TLV – Threshold Limit Value
TWA – Time Weighted Average (8 hr.)
TSE Industries, Inc. makes no representations or warranties with respect to the
information in this Material Safety Data Sheet. The information is, however, correct and
up to date to the best of TSE’s knowledge. This list of information is not intended to be all
inclusive. Actual conditions of use and handling may require considerations of information
other than, or in addition to, that which is provided herein.
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