424 Author index van Emmerik, P.T., 118 Van Kerpel, R., 257 Van Natta, F.J., 330 Van Puijenbroek, R.R., 232 Vandenberg, E.J., 331 Vander Eynde, S., 228 Vanderberg, E.J., 328, 331 VanderHart, D.L., 230, 231 Vansheidt, A.A., 328 Varma-Nair, M., 331, 332 Vasanthakumari, R., 273 Vasilev, V.A., 330 Vasudevon, P., 7 Veberreiter, K., 329 Vega, A.J., 263, 316, 327, 334 Vehida, S., 232 Venditto, V., 229 (2), 329 (2), 335 Veregin, R.P., 230 Veurink, J., 232 Via, G.H., 408 Viers, B.D., 68, 139, 229 Vile, J., 229 Vilgis, T., 234 Villarico, E.A., 410 Villers, D., 331 Viney, C., 234 Vinogradova, S.V., 330 Vinte, V., 272, 329 Vitagliano, V.M., 335 Vittoria, V., 120, 121 (2), 336, 409 Vogelsong, D.C., 335 Voigt-Martin, I.G., 23, 68, 229, 230 (2) Volkenstein, M.V., 23, 334 Volkova, L.A., 228 Volungis, R.J., 408 von Gyldenfeldt, F., 233 Von Hippel, P.H., 120 Vonk, C.G., 229, 230 (3) Vrij, A., 37, 38 (2), 39, 39, 40 (2), 41 (2), 42 (2), 44, 47, 58, 67, 118, 138, 255, 327 Vygodsky, Y.S., 330 Wada, A., 119 (2) Wagner, H.L., 7, 228 Wahrmund D.C., 138 Waite, J.H., 234 Wakelyn, N.T., 330 Walker, E.E., 329 Walker, N., 140 Wall, L.A., 232 Walsh, D.J., 138 (2) Walter, A.T., 228 Walter, E.R., 230 (2) Walters, D.H., 410 Walton, A.G., 234 Wang, F., 273 Wang, G., 235 Wang, J.C., 233 Wang, T.T., 123, 124, 139 Warakomski, I.M., 231 Ward, I.M., 335 (2) Warhmund, D.C., 139 Waring, J.R.S., 69, 234 Warner, F.P., 139 Warner, M., 120 Warner, R.C., 119 Warwicher, J.O., 233 Wasserman, A., 408, 410 Wasserman, Z.R., 232 Watnabe, W.H., 228 Watson, J.D., 13, 23 Watson, W.F., 228 (2) Waymouth, R.M., 228, 232 Weber, A., 408 (2) Weber, P., 302, 303, 332 (2) Webster, D.C., 233 Weder, C., 328, 330 Wee, E.L., 120 Weeks, J.J., 328 Wegner, G., 41 (2), 42, 50, 58, 67, 68, 69 (2), 191, 231 (5), 273 (2), 333 (2) Weimann, P.A., 213, 214, 215, 232 Weir, C.E., 331 Weiss, V., 233 Welch, G.J., 258 Wellingh<strong>of</strong>f, S.J., 235 Wendling, J., 154, 191, 227 Wessling, R.A., 256, 329 Wesson, J.P., 331, 332 West, J.G., 233 West, R., 332 (3) Wethington, J.A., 231 Whewell, C.S., 400, 409 Whiting, M.C., 67 Whitmore, M.D., 232, 234 Wiederhorn, N.M., 409 Wiegand, W.B., 404, 410 Wiemers, N., 273 Wignall, G.D., 23 (2), 140, 333 (3) Wilding, M.A., 335 Wiley, E.R., 409 Wilhoit, R.C., 333 Wilis, H.A., 229 Wilkes, C.E., 256, 329 Wilkes, G.L., 231 (2), 233 (2), 273, 329, 330 Wilkes, J.B., 328 Wilkins, M.H.F., 13, 23, 118 Williams, A.D., 7, 23, 334 (2) Williams, H.L., 329 Williams, J.L., 228 (2) Williams, T.C., 332 Willis, H.A., 229, 410 Wilski, H., 255, 331 Wilson, E.B., Jr, 23 Wilson, F.C., 232 Wilson, H.R., 23, 118 Windle, A.H., 120, 189, 230, 231 Wineman, P.L., 258 Winter, W., 139 Wissbrun, K.F., 256 Wittbecker, E.L., 330 Wittmann, J.C., 118 (3)
Author index 425 Wittner, H., 232 Wlochowicz, A., 257 Wo, E.M., 254 Wolfe, J.R., Jr, 233 Wolkowicz, M.D., 253, 272, 328 Wong, K.Y., 120 Woo, E.M., 335 (2) Wood, B.A., 230 Wood, G.M., 329 Wood, L.A., 31, 33, 67, 331 Wooden, D.C., 256, 336 Woods, H.J., 334, 400, 409 Worthington, C.R., 23 (2) Wrasidlo, W., 273 (2) Wright, B.A., 409 Wrigley, A.N., 328 Wu, C.C., 7, 120 Wu, Z.Q., 273 Wunder, S.L., 335 Wunderlich, B., 68, 231 (2), 263, 273 (2), 327, 328, 331, 332 (3), 334 Wunderlich, W., 7 Wyman, D.P., 7 Xenopoules, A., 330 Xu, F., 232 Xu, J., 229 Xue, Gi., 235 Yam, W.Y., 139 Yamadera, R., 335 Yamaguchi, H., 355 Yamamoto, S., 234 Yamamoto, T., 335 (2) Yamashita, Y., 257 Yamashuto, Y., 233 Yan, D., 7 Yang, J.T., 119 (2) Yang, M., 330 Yang, Y.W., 234, 235 Yasuniwa, M., 335 Yeates, S.G., 50, 68 Yeh, G.S.Y., 125, 139, 332 Yin, J., 139 Yntema, K., 331 Yoda, N., 330 (2) Yokoyama, M., 121 Yoo, H.Y., 230, 231 (2) Yoon, D.Y., 7 (4), 234 (2), 334 Yoshida, T., 68, 328 Yoshie, N., 140, 230, 231 Yoshimizu, H., 120 Yoshioka, T., 235 Young, C.H., 329 Young, R.S., 356 Yu, A.J., 230 (2) Yuan, Q., 235 Yuan, X.F., 232 Yukinari, T., 336 Yusiniwa, M., 335 Yuzuriha, K., 234 Zachmann, H.G., 140, 273 Zahn, H., 50, 68 Zahurak, S.M., 120 Zaides, A.L., 118 Zambelli, A., 335, 336 Zamboni, V., 255 Zazzetta, A., 409 Zeigler, R., 272 Zhang, A., 228 Zhang, H., 140 Zhang, J., 235, 255 Zhao, A.Z., 232 Zhdanov, A.A., 332 (4) Zhou, Z., 7 Zhukov, V.P., 332 Zimm, B.H., 98, 102, 119 (4) Zimmerman, H.J., 331 Zindy, B., 273 Zoller, P., 263 (6), 316 (4), 327, 334 (2) Zolotukhin, M.G., 331 Zotteri, L., 258, 316, 330, 331 Zuniga, I., 234 Zwich, H., 410 Zwijnenburg, A., 409
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CRYSTALLIZATION OF POLYMERS SECOND
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To Berdie, my wife, and to my grand
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viii Contents 4.3 Two chemically id
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x Preface to second edition of both
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xii Preface to first edition of the
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1 Introduction 1.1 Background Polym
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1.2 Structure of disordered chains
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1.2 Structure of disordered chains
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1.2 Structure of disordered chains
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1.3 The ordered polymer chain 9 Tab
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1.3 The ordered polymer chain 11 Fi
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1.3 The ordered polymer chain 13 Fi
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1.4 Morphological features 15 Fig.
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1.4 Morphological features 17 (a) (
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1.4 Morphological features 19 Fig.
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1.4 Morphological features 21 Fig.
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References 23 5. Wilson, E. B., Jr.
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2.1 Introduction 25 Fig. 2.1 Fusion
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2.2 Nature of the fusion process 27
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2.2 Nature of the fusion process 29
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2.2 Nature of the fusion process 31
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2.2 Nature of the fusion process 33
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2.3 Fusion of the n-alkanes and oth
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2.3 Fusion of the n-alkanes and oth
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2.3 Fusion of the n-alkanes and oth
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2.3 Fusion of the n-alkanes and oth
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2.3 Fusion of the n-alkanes and oth
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2.3 Fusion of the n-alkanes and oth
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2.3 Fusion of the n-alkanes and oth
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2.4 Polymer equilibrium 49 Fig. 2.1
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2.4 Polymer equilibrium 51 Fig. 2.8
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2.4 Polymer equilibrium 53 defined
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with ζ e being defined as 2σ eq =
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2.4 Polymer equilibrium 57 is thus
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2.4 Polymer equilibrium 59 The data
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2.4 Polymer equilibrium 61 crystall
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2.4 Polymer equilibrium 63 Fig. 2.2
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2.5 Nonequilibrium states 65 Fig. 2
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References 67 as do low molecular w
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References 69 56. Beech, D. R., C.
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3.2 Melting temperature 71 and ζ =
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3.2 Melting temperature 73 1.05 1.0
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3.2 Melting temperature 75 140 135
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3.2 Melting temperature 77 Fig. 3.4
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3.2 Melting temperature 79 Table 3.
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3.2 Melting temperature 81 crystall
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3.2 Melting temperature 83 Fig. 3.9
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3.2 Melting temperature 85 Fig. 3.1
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3.3 Crystallization from dilute sol
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3.3 Crystallization from dilute sol
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3.3 Crystallization from dilute sol
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3.3 Crystallization from dilute sol
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3.3 Crystallization from dilute sol
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3.4 Helix-coil transition 97 primar
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3.4 Helix-coil transition 99 transi
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3.4 Helix-coil transition 101 If wi
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3.5 Transformations without change
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3.5 Transformations without change
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3.5 Transformations without change
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3.5 Transformations without change
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3.6 Chemical reactions: melting and
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3.6 Chemical reactions: melting and
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3.6 Chemical reactions: melting and
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References 117 Fig. 3.28 Phase diag
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References 119 45. Sanchez, I. C. a
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References 121 121. Paternostre, L.
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4.2 Homogeneous melt: background 12
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4.2 Homogeneous melt: background 12
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4.2 Homogeneous melt: background 12
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4.2 Homogeneous melt: background 12
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4.2 Homogeneous melt: background 13
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4.3 Two chemically identical polyme
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4.4 Crystallization from a heteroge
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4.4 Crystallization from a heteroge
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References 139 20. Flory, P. J., Di
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5 Fusion of copolymers 5.1 Introduc
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5.2 Equilibrium theory 143 distribu
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5.2 Equilibrium theory 145 Here G
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5.2 Equilibrium theory 147 Fig. 5.1
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Therefore 5.2 Equilibrium theory 14
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5.2 Equilibrium theory 151 effect o
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5.2 Equilibrium theory 153 would be
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5.3 Nonequilibrium considerations 1
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5.4 Experimental results: random ty
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5.4 Experimental results: random ty
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5.4 Experimental results: random ty
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5.4 Experimental results: random ty
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5.4 Experimental results: random ty
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5.4 Experimental results: random ty
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5.4 Experimental results: random ty
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5.4 Experimental results: random ty
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5.4 Experimental results: random ty
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5.4 Experimental results: random ty
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5.4 Experimental results: random ty
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5.4 Experimental results: random ty
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5.4 Experimental results: random ty
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5.4 Experimental results: random ty
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5.4 Experimental results: random ty
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5.4 Experimental results: random ty
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5.4 Experimental results: random ty
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5.4 Experimental results: random ty
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5.5 Branching 193 with 1,3-dioxolan
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5.6 Alternating copolymers 195 Mult
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5.6 Alternating copolymers 197 Fig.
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5.6 Alternating copolymers 199 Pair
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5.7 Block or ordered copolymers 201
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5.7 Block or ordered copolymers 203
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5.7 Block or ordered copolymers 205
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5.7 Block or ordered copolymers 207
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5.7 Block or ordered copolymers 209
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5.7 Block or ordered copolymers 211
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5.7 Block or ordered copolymers 213
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5.7 Block or ordered copolymers 215
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5.7 Block or ordered copolymers 217
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5.7 Block or ordered copolymers 219
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5.7 Block or ordered copolymers 221
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5.7 Block or ordered copolymers 223
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5.8 Copolymer-diluent mixtures 225
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References 227 are interconnected b
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References 229 57. Etlis, V. S., K.
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References 231 125. Montaudo, G., G
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References 233 193. Hamley, I. W.,
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References 235 267. Inoue, T., H. K
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6.2 Melting temperatures, heats and
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Table 6.1. Thermodynamic quantities
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acrylonitrile 593.2 5 021 94.7 8.5
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trans-octenamer 5 350.2 23 765 215.
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3-ethyl 3-methyl oxetane 334.2 6 27
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decamethylene adipate 352.7 42 677
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β-propiolactone 357 8 577 119.1 24
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caprolactam γ 7 502.2 17 949 158.8
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tetramethyl-p-silphenylene siloxane
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11 The value of H u was determined
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uu. Rijke, A. M. and S. McCoy, J. P
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Table 6.2. Thermodynamic quantities
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ethylene suberate 336.2 24 451 131.
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1 Adapted with permission from L. M
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Table 6.3. Unique values of thermod
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3,3 ′ -dimethyl thietane 286.2 5
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undecane amide 514.2 35 982 196.6 7
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new-TPI 12 >679.2 63 800 116 93.9 D
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i. Wrasidlo, W., J. Polym. Sci.: Po
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6.2 Melting temperatures, heats and
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6.2 Melting temperatures, heats and
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6.2 Melting temperatures, heats and
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6.2 Melting temperatures, heats and
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6.2 Melting temperatures, heats and
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6.2 Melting temperatures, heats and
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6.2 Melting temperatures, heats and
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6.2 Melting temperatures, heats and
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6.2 Melting temperatures, heats and
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6.2 Melting temperatures, heats and
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6.2 Melting temperatures, heats and
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6.2 Melting temperatures, heats and
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6.2 Melting temperatures, heats and
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6.2 Melting temperatures, heats and
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6.2 Melting temperatures, heats and
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6.2 Melting temperatures, heats and
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6.2 Melting temperatures, heats and
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6.2 Melting temperatures, heats and
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6.3 Entropy of fusion 311 regularit
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6.3 Entropy of fusion 313 Fig. 6.12
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6.3 Entropy of fusion 315 Table 6.5
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6.3 Entropy of fusion 317 disordere
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6.4 Polymorphism 319 of chains.(219
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6.4 Polymorphism 321 different crys
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6.4 Polymorphism 323 at 5 kbar. The
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6.4 Polymorphism 325 the conversion
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References 327 Fig. 6.16 Schematic
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References 329 43. Miller, R. G. J.
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References 331 114. Allen, G., C. B
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References 333 182. Russell, T. P.,
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References 335 256. Vogelsong, D. C
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7 Fusion of cross-linked polymers 7
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7.2 Theory of the melting of isotro
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7.2 Theory of the melting of isotro
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7.3 Melting temperature for random
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7.3 Melting temperature for random
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7.4 Melting temperature for axially
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7.5 Melting temperature for randoml
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7.6 Melting of network-diluent mixt
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7.6 Melting of network-diluent mixt
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References 355 if the cross-linkage
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8 Oriented crystallization and cont
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8.1 Introduction 359 disordered cha
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8.2 One-component system subject to
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8.2 One-component system subject to
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8.2 One-component system subject to
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8.2 One-component system subject to
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8.2 One-component system subject to
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8.2 One-component system subject to
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