MATERIAL SAFETY DATA SHEET 1. Product ... - Reckitt Benckiser

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MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
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Product Name
CLEARASIL ULTRA® Rapid Action Treatment Cream - Vanishing
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UPC CODES Refer to Section 16
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CAS #
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Product Use
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Distributed by
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LEGEND
HMIS/NFPA
Severe
Serious
4
3
Moderate 2
Slight 1
Minimal 0
Mixture
Topical Skin Preparation
Reckitt Benckiser (Canada) Inc.
1680 Tech Avenue Unit #2
Mississauga, ON L4W 5S9
In Case of Emergency: 1-800-338-6167
Transportation Emergencies: 24 Hour Number:
North America: CHEMTREC: 1-800-424-9300
Outside North America: 1-703-527-3887
Health / 1
Flammability 0
Physical Hazard 0
Personal Protection
0
1 0
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Emergency Overview
2. Hazards Identification
This product is regulated by Health Canada as a Natural Health Product. Extensive
testing has been completed to show that it is safe and effective when used as directed.
Warnings: For external use only.
DO NOT use with other acne medications except on the advice of a doctor.
If excessive skin irritation develops or increases, discontinue use: if irritation persists
consult a doctor.
Avoid contact with the eyes.
If contact occurs, rinse thoroughly with water.
In case of accidental ingestion, get medical help or contact a Poison Control Center
immediately.
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Potential short term health effects
Routes of exposure
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Eyes
Skin
Inhalation
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Ingestion
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Target organs
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Chronic effects
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Signs and symptoms
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Potential environmental effects
Keep out of reach of children.
Eye, Skin contact, Inhalation, Ingestion.
Avoid contact with eyes.
May cause eye irritation upon direct contact with the eyes.
Prolonged exposure may cause skin irritation.
Not expected to be a skin sensitizer.
There are no hazards associated with this product in normal use.
Ingestion may cause gastrointestinal irritation.
Eyes. Skin.
The finished product is not expected to have chronic health effects.
Symptoms may include redness, oedema, drying, defatting and cracking of the skin.
Components of this product have been identified as having potential
environmental concerns.
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3. Composition/Information on Ingredients
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Ingredient(s)
Attapulgite
Alcohols, C18- 22
Salicylic acid
Cetyl Alcohol
1-Dodecanol, 2-octyl-
Poly(oxy-1,2-ethanediyl), a-octadecyl-w-hydroxy
D-Gluconic acid, monosodium salt
1,2-Propylene glycol
CAS #
12174-11-7
97552-91-5
69-72-7
36653-82-4
5333-42-6
9005-00-9
527-07-1
57-55-6
Percent
0.1 - 1
0.5 - 1.5
1 - 5
1 - 5
1 - 5
3 - 7
3 - 7
3 - 7
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First aid procedures
Eye contact
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Skin contact
Inhalation
Ingestion
Notes to physician
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General advice
4. First Aid Measures
Remove contact lenses if present. Flush immediately with large amounts of water,
especially under lids for at least 15 minutes. If irritation or other effects persist, obtain
medical treatment.
If excessive skin irritation develops or increases, discontinue use: if irritation persists
consult a doctor.
Remove to fresh air if inhalation causes eye watering, headaches, dizziness or other
discomfort.
In case of accidental ingestion, get medical help or contact a Poison Control Center
immediately.
Treat patient symptomatically.
If you feel unwell, seek medical advice (show the label where possible). Ensure that
medical personnel are aware of the material(s) involved, and take precautions to protect
themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with
eyes. Keep out of reach of children.
5. Fire-fighting Measures
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Flammable properties
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Extinguishing media
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Suitable extinguishing media
Unsuitable extinguishing media Not available
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Protection of firefighters
Specific hazards arising from Not available
the chemical
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Protective equipment for
firefighers
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Hazardous combustion products
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Explosion data
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Sensitivity to mechanical impact Not available
Sensitivity to static discharge
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Personal precautions
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Environmental precautions
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Methods for containment
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Methods for cleaning up
Not flammable by WHMIS criteria.
Water spray. Foam. Dry chemical. Sand.
Firefighters should wear full protective clothing including self contained breathing
apparatus.
May include and are not limited to: Oxides of carbon.
Not available
6. Accidental Release Measures
Do not touch or walk through spilled material. Do not touch damaged containers or
spilled material unless wearing appropriate protective clothing.
Do not discharge into lakes, streams, ponds or public waters.
Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements
or confined areas.
Before attempting clean up, refer to hazard data given above. Small spills may be
absorbed with non-reactive absorbent and placed in suitable, covered, labelled
containers. Prevent large spills from entering sewers or waterways. Contact emergency
services and supplier for advice. Never return spills in original containers for re-use.
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Handling
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Storage
7. Handling and Storage
For external use only.
Avoid contact with eyes, lips and mouth.
When using do not eat or drink.
Keep out of reach of children.
Keep in cool, dry, ventilated storage.
Store at room temperature (68-77°F)(20-25°C).
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Exposure limit values
Ingredient(s)
1,2-Propylene glycol
1-Dodecanol, 2-octyl-
Alcohols, C18- 22
Attapulgite
Cetyl Alcohol
60°C - Not permitted.
50°C - Not more than 3 weeks.
40°C - Not more than 8 weeks.
Allowances for excursions below 0°C: Keep from freezing.
8. Exposure Controls / Personal Protection
Exposure limit values
ACGIH-TLV
Not established
ACGIH-TLV
Not established
ACGIH-TLV
Not established
ACGIH-TLV
Not established
ACGIH-TLV
Not established
D-Gluconic acid, monosodium salt
Poly(oxy-1,2-ethanediyl), a-octadecyl-w-hydroxy
ACGIH-TLV
Not established
ACGIH-TLV
Not established
Salicylic acid
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Engineering controls
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Personal protective equipment
Eye/Face protection
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Hand protection
Skin and body protection
Respiratory protection
Not normally required.
ACGIH-TLV
Not established
Not normally required under normal use conditions.
When handling in large quantities or responding to emergency situations, the use of
appropriate eye protection is recommended.
Not required.
When handling in large quantities or responding to emergency situations, the use
of appropriate eye protection is recommended.
No special requirements under normal use conditions.
Not normally required under normal use conditions.
General hygiene considerations Avoid contact with eyes.
Handle in accordance with good industrial hygiene and safety practice.
When using do not eat or drink.
9. Physical and Chemical Properties
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Appearance
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Colour
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Form
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Odour
cream
white
Cream
Slight Characteristic
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Odour threshold
Not available
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Physical state
Liquid
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pH 3.8 - 4.2
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Freezing point
Not available
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Boiling point
Not available
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Pour point
Not available
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Evaporation Rate
Not available
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Flash point
Not available
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Auto-ignition temperature
Not available
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Flammability limits in air, lower, % Not available
by volume
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Flammability Limits in Air, Upper, % Not available
by Volume
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Vapour pressure
Not available
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Vapour density
Not available
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Specific gravity 0.980 - 1.040
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Octanol/water coefficient
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Solubility (H2O)
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VOC (Weight %)
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Percent volatile
Not available
Soluble
Not available
Not available
10. Stability and Reactivity
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Reactivity
This product may react with strong acids.
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Possibility of hazardous reactions Hazardous polymerisation does not occur.
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Chemical stability
Stable under recommended storage conditions.
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Conditions to avoid
Do not mix with other chemicals.
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Incompatible materials
Acids. Oxidizers.
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Hazardous decomposition products May include and are not limited to: Oxides of carbon.
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Component analysis - LC50
Ingredient(s)
11. Toxicological Information
LC50
1,2-Propylene glycol
1-Dodecanol, 2-octyl-
Alcohols, C18- 22
Attapulgite
Cetyl Alcohol
D-Gluconic acid, monosodium salt
Poly(oxy-1,2-ethanediyl), a-octadecyl-w-hydroxy
Salicylic acid
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Component analysis - Oral LD50
Ingredient(s)
Not available
Not available
Not available
Not available
Not available
Not available
Not available
0.225 mg/l/4h rat
LD50
1,2-Propylene glycol
14800 mg/kg rabbit; 20000 mg/kg rat
1-Dodecanol, 2-octyl-
Not available
Alcohols, C18- 22
Not available
Attapulgite
Not available
Cetyl Alcohol
3200 mg/kg mouse; 5000 mg/kg rat
D-Gluconic acid, monosodium salt
2000 mg/kg rat
Poly(oxy-1,2-ethanediyl), a-octadecyl-w-hydroxy
25000 mg/kg rat
Salicylic acid
891 mg/kg rat; 400 mg/kg cat; 480 mg/kg mouse
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Effects of acute exposure
Eye
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Skin
Inhalation
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Ingestion
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Sensitisation
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Chronic effects
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Carcinogenicity
Avoid contact with eyes.
May cause eye irritation upon direct contact with the eyes.
Prolonged exposure may cause skin irritation.
Not expected to be a skin sensitizer.
There are no hazards associated with this product in normal use.
Ingestion may cause gastrointestinal irritation.
The finished product is not expected to have chronic health effects.
The finished product is not expected to have chronic health effects.
The finished product is not expected to have chronic health effects.
IARC - Group 2B (Possibly Carcinogenic to Humans)
Attapulgite 12174-11-7 Monograph 68 [1997] (long fibres >5 µm); Supplement 7 [1987]
IARC - Group 3 (Not Classifiable)
Attapulgite 12174-11-7 Monograph 68 [1997] (short fibres 10000 mg/L
Salicylic acid 69-72-7 48 Hr LC50 Leuciscus idus: 90 mg/L [static]
Ecotoxicity - Water Flea - Acute Toxicity Data
1,2-Propylene glycol 57-55-6 24 Hr EC50 Daphnia magna: >10000 mg/L; 48 Hr EC50 Daphnia magna: >1000 mg/L
[Static]
Salicylic acid 69-72-7 24 Hr EC50 Daphnia magna: 105 mg/L; 48 Hr EC50 Daphnia magna: 870 mg/L
[Static]
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Persistence and degradability Not available
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Bioaccumulation/accumulation Not available
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Mobility in environmental media Not available
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Environmental effects
Not available
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Aquatic toxicity
Not available
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Partition coefficient
Not available
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Chemical fate information
Not available
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Other adverse effects
Not available
13. Disposal Considerations
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Disposal instructions
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Waste from residues / unused
products
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Contaminated packaging
Review federal, provincial, and local government requirements prior to disposal.
Not available
Not available
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14. Transport Information
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UN/ID N.o.
Not applicable
U.S. Department of Transportation (DOT): Classification: Not regulated
Proper shipping name Not applicable
U.S. DOT Hazard Class
Subsidiary Risk
Packing group
DOT RQ (lbs)
ERG NO
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Transportation of Dangerous Goods (TDG - Canada): Classification: Not regulated
Proper shipping name Not applicable
Status
Not applicable
Packing group Not applicable
IMDG (Marine Transport): Classification: Not regulated
Proper shipping name Not applicable
Class
Not applicable
Subsidiary Risk
Not applicable
Packing group
Not applicable
IMDG Page
Not applicable
Marine pollutant
EMS
MFAG
Maximum Quantity
Not applicable
Not applicable
Not applicable
Not applicable
IATA/ICAO (Air): Classification: Not regulated
Proper shipping name Not applicable
Class
Not applicable
Subsidiary Risk:
Not applicable
Packing group
Not applicable
Maximum Quantity
Not applicable
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Canadian federal regulations
15. Regulatory Information
This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations and the MSDS contains all the information required by the
Controlled Products Regulations.
Product Registration: Registered NHP Product
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Canada - WHMIS - Ingredient Disclosure List
1,2-Propylene glycol 57-55-6 1 %
Salicylic acid 69-72-7 0.1 %
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WHMIS classification Exempt - Registered product - (NHP 80008630)
Inventory Status
Country(s) or region
Canada
Canada
Inventory Name
Domestic Substances List (DSL)
Non-Domestic Substances List (NDSL)
On Inventory (Yes/No)*
Yes
No
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing
country(s)
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Disclaimer
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Further information
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16. Other Information
This product should only be used as directed on the label and for the purpose intended.
To the best of our knowledge, the information contained herein is accurate. However,
neither the above named supplier nor any of its subsidiaries assumes any liability
whatsoever for the accuracy or completeness of the information contained herein. Final
determination of suitability of any material is the sole responsibility of the user. All
materials may present unknown hazards and should be used with caution. Although
certain hazards are described herein, we cannot guarantee that these are the only
hazards that exist.
39977-00909 - 15 mL - Clearasil® ULTRA Rapid Action Treatment Cream - Vanishing
- 10069001
10-Aug-2011
Issue date
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Effective Date
15-Aug-2011
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Expiry Date
15-Aug-2014
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Prepared by Reckitt Benckiser Regulatory Department 800-333-3899
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Other Information
For an updated MSDS, please contact the supplier/manufacturer listed on the first
page of the document.
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