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mass transfer in multiphase systems - Greenleaf University

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MASS TRANSFER IN MULTIPHASE SYSTEMS: VOLATILE ORGANIC COMPOUND<br />

REMOVAL IN THREE-PHASE SYSTEMS<br />

35000<br />

30000<br />

System 1 Solid VOC Concentration vs Time<br />

Models<br />

X, ppb<br />

25000<br />

20000<br />

15000<br />

10000<br />

5000<br />

X data<br />

ln(X) vs t1/2<br />

X vs ln(t)<br />

Model ln(X) vs 1/t1/2<br />

Model ln(t)<br />

0<br />

0 20 40 60 80<br />

Time, hr<br />

Figure 12. Laboratory data with two models.<br />

The scale-up was based on the ln(X) vs. t -1/2 curve although the X vs. ln(t) curve would<br />

also be acceptable. Once hav<strong>in</strong>g a good model that represents the data, the scale-up is performed<br />

to determ<strong>in</strong>e either 1) the time required to operate based on a specified flow rate or 2) the flow<br />

rate required for a time requirement. Based on this, the change <strong>in</strong> the <strong>mass</strong> concentration is:<br />

dX<br />

dt<br />

Ko<br />

kD<br />

K<br />

X 1 <br />

t H t<br />

'<br />

o<br />

X<br />

(38)<br />

The plan is to f<strong>in</strong>d the K o from the laboratory and scale it up to an operat<strong>in</strong>g system us<strong>in</strong>g the<br />

Sherwood number (Sh) for the system that had laboratory test<strong>in</strong>g (Treybal 1987).<br />

31

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