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mass transfer in multiphase systems - Greenleaf University

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MASS TRANSFER IN MULTIPHASE SYSTEMS: VOLATILE ORGANIC COMPOUND<br />

REMOVAL IN THREE-PHASE SYSTEMS<br />

Actual VOC vs. Time<br />

1000<br />

Gas Concentration, ppm<br />

100<br />

10<br />

1<br />

0 50 100 150 200 250<br />

Time, hr<br />

Figure 15. Data from pulsed operation for TK-V9.<br />

5.0 Interpretations, Conclusions, and Recommendations<br />

In any further work <strong>in</strong> this area, a number of recommendations are quite evident <strong>in</strong> this<br />

dissertation. It is imperative to determ<strong>in</strong>e the equilibrium data, e.g., Henry’s Law constant and<br />

the solid-liquid partition coefficient if no laboratory test<strong>in</strong>g is conducted. Even with laboratory<br />

test<strong>in</strong>g, the apparatus should be similar <strong>in</strong> geometry to the actual system. The author does not<br />

believe the Henry’s constant is go<strong>in</strong>g to vary based on water much around ± 10-15% and<br />

therefore not as critical as the partition coefficient. The partition coefficients used <strong>in</strong> this work<br />

were soil averages. Actual partition coefficients can vary widely. The common assumptions of<br />

the first term of Eq. 15 may need to be exam<strong>in</strong>ed for applicability. Most authors ignore (by<br />

assum<strong>in</strong>g k s is very large compared to k sL and k L ) it and a better rational should be developed.<br />

37

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