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mass transfer in multiphase systems - Greenleaf University

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MASS TRANSFER IN MULTIPHASE SYSTEMS: VOLATILE ORGANIC COMPOUND<br />

REMOVAL IN THREE-PHASE SYSTEMS<br />

S<strong>in</strong>ce the <strong>mass</strong> stays the same while the volume changes or could change, all of the derivatives of the<br />

<strong>mass</strong> are zero w :<br />

Dm<br />

<br />

Dt<br />

D<br />

dV<br />

0<br />

Dt<br />

(101)<br />

V<br />

Case III Fixed Inf<strong>in</strong>itesimally Small Element<br />

j<br />

y<br />

v <br />

v<br />

<br />

dydxdz<br />

y<br />

<br />

w <br />

w<br />

<br />

dzdxdy<br />

z<br />

<br />

k<br />

i<br />

x<br />

z<br />

<br />

udydz<br />

u <br />

u<br />

<br />

dxdydz<br />

x<br />

<br />

<br />

wdxdy<br />

<br />

vdxdz<br />

Figure 17. Inf<strong>in</strong>itesimally small unit cube.<br />

From the left face and us<strong>in</strong>g u as the x velocity, the <strong>mass</strong> balance is:<br />

u<br />

( u<br />

dx)<br />

dydz udydz net decrease<br />

x<br />

(102)<br />

This is true because:<br />

df<br />

f<br />

dx<br />

(103)<br />

x<br />

These are similar for y and z directions<br />

The time rate of <strong>mass</strong> <strong>in</strong>crease is (dV =dxdydz)<br />

w It is customary to state that this only applies for stable, non-radioactive elements.<br />

54

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