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Food Packaging: Strategies for Rapid Phthalate ... - IonSense

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Optimized MS/MS Method: EPA Mix 506<br />

100<br />

50<br />

162.98<br />

DMP<br />

NL: 2.58E5<br />

EPA506_<strong>Phthalate</strong>Mix_AllOpt_20121004#371<br />

RT: 1.24 AV: 1 SB: 10 0.43-0.78 F: ITMS + c<br />

NSI Full ms2 195.00<br />

0<br />

100<br />

50<br />

177.02<br />

DEP<br />

NL: 2.20E6<br />

EPA506_<strong>Phthalate</strong>Mix_AllOpt_20121004#350-<br />

393 RT: 1.19-1.30 AV: 5 SB: 10 0.43-0.78 F:<br />

ITMS + c NSI Full ms2 223.00<br />

Relative Abundance<br />

0<br />

100<br />

50<br />

0<br />

100<br />

50<br />

0<br />

100<br />

50<br />

0<br />

148.95<br />

166.89<br />

205.01<br />

205.01<br />

148.95<br />

91.06 238.95<br />

113.10<br />

148.95<br />

166.96<br />

261.06<br />

279.11<br />

279.12<br />

DBP<br />

BBP<br />

DEHP/DnOP<br />

Mix<br />

391.28<br />

50 100 150 200 250 300 350 400<br />

m/z<br />

NL: 7.84E5<br />

EPA506_<strong>Phthalate</strong>Mix_AllOpt_20121004#359-<br />

409 RT: 1.21-1.35 AV: 6 SB: 11 0.43-0.78 F:<br />

ITMS + c NSI Full ms2 279.00<br />

NL: 4.52E6<br />

EPA506_<strong>Phthalate</strong>Mix_AllOpt_20121004#365-<br />

474 RT: 1.23-1.52 AV: 11 SB: 10 0.43-0.78 F:<br />

ITMS + c NSI Full ms2 313.10<br />

NL: 1.18E7<br />

EPA506_<strong>Phthalate</strong>Mix_AllOpt_20121004#365-<br />

474 RT: 1.23-1.52 AV: 11 SB: 10 0.43-0.78 F:<br />

ITMS + c NSI Full ms2 391.10<br />

13

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