Food Packaging: Strategies for Rapid Phthalate ... - IonSense

Yellow Plastic Handle
A96-1_A_YellowHandlePiece_20120412_PO... 4/12/2012 10:50:56 AM 3+D; Background BEG&END
He; 200C; 1.0 mm/s;1e6 AGC Fill
RT: 0.00 - 1.57
80
60
40
20
0
100
Relative Abundance100
80
60
40
0.08
0.15
0.22 0.29
0.36
0.44
0.48
0.56 0.60 1.43
0.74
1.40
0.66 0.76 1.36
1.46
0.80 1.32
1.50
0.84
1.27
1.02
0.56 0.63
1.43
0.73
0.76 1.36 1.38 1.46
1.32
1.48
0.80
1.27
1.50
20
1.10
0.08 0.17 0.22 0.29 0.33 0.39 0.44
0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1.4 1.5
Time (min)
A96-1_A_YellowHandlePiece_20120412_POS_He_Run71 #47-77 RT: 0.56-0.80 AV: 31 SB: 19 0.05-0.27 NL: 2.04E6
T: FTMS {1,1} + p NSI Full ms [100.00-1000.00]
391.28312
100
Relative Abundance
90
80
70
60
50
40
30
20
Major Ortho
Phthalate Fragment
XIC m/z 149
DEHP, DnOP and DOP
XIC m/z 391
Major Thermal
Fragment
149.02301
1.00
DEHP, DnOP and DOP
1.02
NL: 7.46E5
m/z=
149.02254-
149.02403 MS
A96-
1_A_YellowHandlePi
ece_20120412_POS_
He_Run71
NL: 2.51E6
m/z=
391.28217-
391.28608 MS
A96-
1_A_YellowHandlePi
ece_20120412_POS_
He_Run71
798.58545
10
167.03355 239.14834 279.15841
0
408.30952 841.59119
100 150 200 250 300 350 400 450 500 550 600 650 700 750 800 850
m/z
7