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Food Packaging: Strategies for Rapid Phthalate ... - IonSense

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Major Regulated <strong>Phthalate</strong>s of Interest<br />

Compound<br />

Elemental<br />

composition<br />

Precursor<br />

[M+H]+<br />

Selection of characteristic<br />

fragments nominal m/z<br />

Regulation<br />

Di-n-butyl phthalate (DBP) C 16 H 22 O 4 279.1591 205.1 CA Prop 65/ EU<br />

Diisobutyl phthalate (DiBP) C 16 H 22 O 4 279.1591 205.1; 223.1, 57.1 EU<br />

Benzyl butyl phthalate<br />

(BBP)<br />

Bis(2-ethylhexyl)phthalate<br />

(DEHP)<br />

Di-n-octyl phthalate<br />

(DnOP)<br />

Dioctyltere phthalate<br />

(DOTP)<br />

Diisononyl phthalate<br />

(DiNP)<br />

Diisodecyl phthalate<br />

(DiDP)<br />

C 19 H 20 O 4 313.1434 205.1; 239.1; 91.1 CA Prop 65/ EU<br />

C 24 H 38 O 4 391.2843 279.2; 261.1; 167.0; 113.1 CA Prop 65/ EU<br />

C 24 H 38 O 4 391.2843 261.1; 167.0 CA Prop 65/ EU<br />

C 24 H 38 O 4 391.2843 262.1; 167.0; 111.1; 280.1 Not Regulated<br />

C 26 H 42 O 4 419.3156 275.2; 127.1; 293.2 CA Prop 65/ EU<br />

C 28 H 46 O 4 447.3469 289.2; 141.2; 307.2; 99.1 CA Prop 65/ EU<br />

Isomeric phthalates are shown in blue and yellow.<br />

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