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Food Packaging: Strategies for Rapid Phthalate ... - IonSense

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Key DART Source Parameters<br />

• Source Parameters:<br />

• Ionization gasses<br />

• N 2 (Standby)<br />

• He (Run Mode)<br />

• Temperature of ionization gas<br />

• Sample introduction speed<br />

• Ions typically observed in<br />

DART–MS mass spectra:<br />

• [M+H] + , [M–H] –<br />

• M +·, M –· (ionic compounds)<br />

• Use of dopants to promote<br />

ionization:<br />

• [M+NH4] + (ammonia)<br />

• [M+Cl] – (e.g. CH 2 Cl 2 )<br />

• [M+CF 3 COO] – (trifluoroacetic<br />

acid)<br />

Figure courtesy of Prof. Jana Hajšlová<br />

ICT Prague, Czech Republic<br />

3

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