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Oral 18<br />
Abstract<br />
Water dynamics at the liquid-solid interface of biochar systems<br />
Pellegrino C<strong>on</strong>te, Giuseppe Al<strong>on</strong>zo<br />
Dipartimento di Scienze Agrarie e Forestali, Università degli Studi di Palermo, v.le delle Scienze<br />
ed. 4 90128 Palermo (Italy)<br />
Biochar is a carb<strong>on</strong>aceous material obtained by pyrolysis of biomass feedstocks. It is applied to<br />
soils in order to improve fertility <str<strong>on</strong>g>and</str<strong>on</strong>g> mitigate greenhouse-gases emissi<strong>on</strong>s. In fact, from the <strong>on</strong>e<br />
h<str<strong>on</strong>g>and</str<strong>on</strong>g>, biochar changes physical-chemical soil properties, thereby affecting soil fertility. From the<br />
other h<str<strong>on</strong>g>and</str<strong>on</strong>g>, biochar is resistant to chemical <str<strong>on</strong>g>and</str<strong>on</strong>g> biochemical degradati<strong>on</strong>. For this reas<strong>on</strong>, its use<br />
allows carb<strong>on</strong> sequestrati<strong>on</strong> in soils <str<strong>on</strong>g>and</str<strong>on</strong>g> c<strong>on</strong>sequent reducti<strong>on</strong> of carb<strong>on</strong> dioxide to the atmosphere.<br />
Here, dynamics of water at the liquid-solid interface of water saturated biochars is discussed.<br />
Results revealed that water dynamics is affected by the nature of biochar parent biomasses.<br />
Moreover, water undergoes to an inner-sphere interacti<strong>on</strong> mechanism with biochar surface through<br />
formati<strong>on</strong> of weak unc<strong>on</strong>venti<strong>on</strong>al hydrogen b<strong>on</strong>ds.<br />
Recogniti<strong>on</strong> of the interacti<strong>on</strong> mechanisms between water <str<strong>on</strong>g>and</str<strong>on</strong>g> biochar is of paramount importance<br />
in order to underst<str<strong>on</strong>g>and</str<strong>on</strong>g> why biochar soil amendments improve soil fertility <str<strong>on</strong>g>and</str<strong>on</strong>g> crop producti<strong>on</strong>.<br />
<str<strong>on</strong>g>8th</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> Fast Field Cycling NMR Relaxometry, Turin 23-25 May 2013