ECHA - Guidance of the application of CLP criteria [November 2012]

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Guidance on the Application of the CLP Criteria Version 3.0 - November 20122.13 OXIDISING LIQUIDS AND OXIDISING SOLIDS .......................................................................1642.13.1 Introduction ..........................................................................................................................1642.13.2 Definitions and general considerations for the classification of oxidising liquids andoxidising solids.....................................................................................................................1652.13.3 Classification of substances and mixtures as oxidising liquids and oxidising solids ...........1662.13.3.1 Identification of hazard information .....................................................................1662.13.3.1.1 Non-testing data ..................................................................................1662.13.3.2 Classification criteria.............................................................................................1672.13.3.2.1 General ................................................................................................1672.13.3.2.2 Oxidising liquids .................................................................................1672.13.3.2.3 Oxidising solids...................................................................................1682.13.3.3 Testing and evaluation of hazard information.......................................................1682.13.3.4 Decision logic........................................................................................................1692.13.3.4.1 Decision logic 2.13 for oxidising liquids ............................................1702.13.3.4.2 Decision logic 2.14 for oxidising solids..............................................171Hazard communication for oxidising liquids and oxidising solids .......................171Hazard communication for oxidising liquids and oxidising solids .......................1722.13.3.5 Pictograms, signal words, hazard statements and precautionary statements.........1722.13.4 Re-classification of substances and mixtures classified as oxidising liquids andoxidising solids according to DSD or already classified for transport .................................1722.13.4.1 Re-classification of substances and mixtures classified in accordance withDSD.......................................................................................................................1722.13.4.1.1 Liquids.................................................................................................1722.13.4.1.2 Solids...................................................................................................1732.13.4.2 Relation to transport classification........................................................................1732.13.5 Examples of classification for oxidising liquids and oxidising solids..................................1732.13.5.1 Examples of substances and mixtures fulfilling the classification criteria............1732.13.5.1.1 Liquids.................................................................................................1732.13.5.1.2 Solids...................................................................................................1732.13.5.2 Examples of substances and mixtures not fulfilling the classification criteriafor 1742.13.5.2.1 Liquids.................................................................................................1742.13.5.2.2 Solids...................................................................................................1742.13.6 Reference..............................................................................................................................1742.14 ORGANIC PEROXIDES..................................................................................................................1742.14.1 Introduction ..........................................................................................................................1742.14.2 Definitions and general considerations for the classification of organic peroxides .............1742.14.3 Relation to other physical hazards........................................................................................1752.14.4 Classification of substances and mixtures as organic peroxides ..........................................1752.14.4.1 Identification of hazard information .....................................................................1752.14.4.2 Classification criteria.............................................................................................1752.14.4.3 Testing and evaluation of hazard information.......................................................1772.14.4.3.1 Thermal stability tests and temperature control ..................................1772.14.4.3.2 Additional testing ................................................................................1782.14.4.3.3 Additional classification considerations..............................................1782.14.4.4 Decision logic........................................................................................................1782.14.5 Hazard communication for organic peroxides......................................................................1802.14.5.1 Pictograms, signal words, hazard statements and precautionary statements.........1802.14.5.2 Additional labelling provisions for organic peroxides ..........................................1812.14.6 Re-classification of substances and mixtures classified as organic peroxides accordingto DSD or already classified according to transport.............................................................1812.14.6.1 Re-classification of substances and mixtures classified in accordance withDSD.......................................................................................................................1812.14.6.2 Relation to transport classification........................................................................1812.14.7 Examples of classification for organic peroxides.................................................................18112
Guidance on the Application of the CLP Criteria Version 3.0 - November 20122.14.7.1 Examples of substances and mixtures fulfilling the classification criteria............1812.14.8 Additional remarks ...............................................................................................................183Explosive properties ..........................................................................................................................1832.15 CORROSIVE TO METALS .............................................................................................................1842.15.1 Introduction ..........................................................................................................................1842.15.2 Definitions and general considerations for the classification of substances andmixtures corrosive to metals.................................................................................................1852.15.3 Classification of substances and mixtures as corrosive to metals.........................................1852.15.3.1 Identification of hazard information .....................................................................1852.15.3.2 Screening procedures and waiving of testing........................................................1862.15.3.3 Classification criteria.............................................................................................1872.15.3.4 Testing and evaluation of hazard information.......................................................1872.15.3.4.1 General considerations ........................................................................1872.15.3.4.2 Additional notes on best practice for testing .......................................1882.15.4 Hazard communication for substances and mixtures corrosive to metals ............................1902.15.4.1 Pictograms, signal words, hazard statements and precautionary statements.........1902.15.5 Re-classification of substances and mixtures classified as corrosive to metalsaccording to DSD .................................................................................................................1912.15.5.1 Re-classification of substances and mixtures classified in accordance withDSD.......................................................................................................................1912.15.5.2 Relation to transport classification........................................................................1912.15.6 Examples of classification for substances and mixtures corrosive to metals .......................1912.15.6.1 Example of metal specimen plates after exposure to a corrosive mixture ............1922.15.7 References ............................................................................................................................1923 HEALTH HAZARDS .......................................................................................................................1933.1 ACUTE TOXICITY..........................................................................................................................1933.1.1 Definitions and general considerations for acute toxicity ....................................................1933.1.2 Classification of substances for acute toxicity......................................................................1943.1.2.1 Identification of hazard information .....................................................................1943.1.2.1.1 Identification of human data ...............................................................1943.1.2.1.2 Identification of non-human data ........................................................1943.1.2.2 Classification criteria.............................................................................................1953.1.2.3 Evaluation of hazard information..........................................................................1973.1.2.3.1 Evaluation of human data....................................................................1973.1.2.3.2 Evaluation of non-human data ............................................................1973.1.2.3.3 Weight of evidence..............................................................................2003.1.2.4 Decision on classification......................................................................................2003.1.2.5 Setting of specific concentration limits.................................................................2003.1.2.6 Decision logic........................................................................................................2003.1.3 Classification of mixtures for acute toxicity.........................................................................2023.1.3.1 General considerations for classification ..............................................................2023.1.3.2 Identification of hazard information .....................................................................2023.1.3.3 Classification criteria.............................................................................................2023.1.3.3.1 When data are available for the complete mixture..............................2023.1.3.3.2 When data are not available for the complete mixture: bridgingprinciples .............................................................................................2033.1.3.3.3 When data are available for all components or only for somecomponents .........................................................................................2033.1.3.3.4 When data are not available for all components .................................2053.1.3.3.5 Components that should be taken into account for the purpose ofclassification........................................................................................2083.1.3.4 Generic concentration limits for substances triggering classification ofmixtures.................................................................................................................20813
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ECHA - Guidance of the application of CLP criteria [November 2012]

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